Ti3C2 MXene助催化剂组装的介孔TiO2用以增强光催化甲基橙降解和产氢活性

doi:10.1016/S1872-2067(21)63915-3

催化学报 ›› 2022, Vol. 43 ›› Issue (2): 461-471.DOI: 10.1016/S1872-2067(21)63915-3

Ti₃C₂ MXene助催化剂组装的介孔TiO₂用以增强光催化甲基橙降解和产氢活性

李华鹏, 孙彬^*(), 高婷婷, 李欢, 任永强, 周国伟^#()

齐鲁工业大学(山东省科学院)化学与化工学院, 济南市多尺度功能材料工程实验室, 山东省高校轻工精细化学品重点实验室, 山东济南 250353

收稿日期:2021-05-01 接受日期:2021-05-01 出版日期:2022-02-18 发布日期:2022-02-18
通讯作者: 孙彬,周国伟
基金资助:
国家自然科学基金(51972180);国家自然科学基金(51572134);山东省自然科学基金(ZR2019BB030);山东省重点研发计划(2019GGX102070);济南市高校院所创新团队(2018GXRC006)

Ti₃C₂ MXene co-catalyst assembled with mesoporous TiO₂ for boosting photocatalytic activity of methyl orange degradation and hydrogen production

Huapeng Li, Bin Sun^*(), Tingting Gao, Huan Li, Yongqiang Ren, Guowei Zhou^#()

Key Laboratory of Fine Chemicals in Universities of Shandong, Jinan Engineering Laboratory for Multi-scale Functional Materials, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, Shandong, China

Received:2021-05-01 Accepted:2021-05-01 Online:2022-02-18 Published:2022-02-18
Contact: Bin Sun, Guowei Zhou
Supported by:
This work was supported by the National Natural Science Foundation of China(51972180);This work was supported by the National Natural Science Foundation of China(51572134);Natural Science Foundation of Shandong Province(ZR2019BB030);Key Research & Development Project of Shandong Province(2019GGX102070);the Program for Scientific Research Innovation Team in Colleges and Universities of Jinan(2018GXRC006)

摘要/Abstract

摘要：

利用太阳能驱动半导体光催化剂进行光催化降解污染物和产氢被认为是解决环境问题和能源危机最有效的方法之一. 在众多的半导体光催化剂中, TiO₂因其优异的化学稳定性、环境友好和成本低等优点, 在光催化领域具有不可或缺的作用. 介孔TiO₂由于具有独特的介孔结构, 更有利于光催化过程中反应物的吸附和传输. 然而, 单一TiO₂具有较高的光生载流子重组效率和低的光利用率等缺点, 导致其光催化活性低. 通过负载助催化剂可以增强光吸收、促进光生载流子的分离以及提供更多活性位点, 是提高光催化活性的一种有效策略. 目前, 常用的高效助催化剂主要为贵金属, 如Pt, Pd和Au等, 但昂贵的价格及稀缺性限制了其在未来的广泛应用. 因此, 寻找新型的非贵金属助催化剂来提高光催化剂的活性具有重要意义. MXene作为一种新型的二维过渡金属碳化物和/或氮化物, 具有丰富的表面亲水性官能团、良好的金属导电性和较高的载流子迁移率等特性, 适合用于光催化中作为助催化剂来提高光催化性能. 受此启发, 本文利用静电自组装策略将介孔TiO₂纳米颗粒均匀地固定在Ti₃C₂ MXene助催化剂上, 构建了紧密的介孔TiO₂/Ti₃C₂复合材料, 并研究其光催化降解甲基橙(MO)和产氢性能.
Zeta电位测试结果表明, 带有相反表面电荷的介孔TiO₂和Ti₃C₂可以通过静电作用构筑稳定的复合材料. X-射线粉末衍射、拉曼光谱、X-射线光电子能谱(XPS)、透射电子显微镜和高分辨透射电子显微镜等表征也进一步表明, 成功制备了介孔TiO₂/Ti₃C₂复合材料. XPS也证明在复合材料中光生电子从TiO₂转移到Ti₃C₂助催化剂上, 表明两者之间具有强相互作用. BET测试结果表明, 相比单一的介孔TiO₂, 复合材料具有更大的比表面积和孔体积, 可提供更多的活性位点, 有利于提高光催化活性. 紫外-可见漫反射光谱表明, Ti₃C₂助催化剂的引入提高了材料的光吸收能力. 荧光光谱、时间分辨荧光光谱、光电流密度和电化学阻抗等测试结果表明, 复合材料具有优异的光生载流子分离和转移能力.
在光催化性能测试中, 最佳Ti₃C₂含量(3 wt%)的介孔TiO₂/Ti₃C₂复合材料在40 min内对MO的光催化降解效率可达99.6%, 并利用自由基捕获实验和电子自旋共振表征证实了活性物种·O₂ ^-和·OH在光催化降解过程中起主要作用. 此外, 该复合材料也表现出了较好的产氢性能(218.85 μmol g ^-1 h ^-1), 约为单一介孔TiO₂的5.6倍, 且三次循环后仍保持稳定的产氢效率. 综上, MXene族材料可以作为一种高效的非贵金属助催化剂应用于光催化领域.

关键词: 介孔TiO₂, 静电自组装, Ti₃C₂ MXene, 助催化剂, 光催化降解, 光催化产氢

Abstract:

Photocatalytic degradation and hydrogen production using solar energy through semiconductor photocatalysts are deemed to be a powerful approach for solving environmental and energy crisis. However, the biggest challenge in photocatalysis is the efficient separation of photo-induced carriers. To this end, we report that the mesoporous TiO₂ nanoparticles are anchored on highly conductive Ti₃C₂ MXene co-catalyst by electrostatic self-assembly strategy. The constructed mesoporous TiO₂/Ti₃C₂ composites display that the mesoporous TiO₂ nanoparticles are uniformly distributed on the surface of layer structured Ti₃C₂ nanosheets. More importantly, the as-obtained mesoporous TiO₂/Ti₃C₂ composites reveal the significantly enhanced light absorption performance, photo-induced carriers separation and transfer ability, thus boosting the photocatalytic activity. The photocatalytic methyl orange degradation efficiency of mesoporous TiO₂/Ti₃C₂ composite with an optimized Ti₃C₂ content (3 wt%) can reach 99.6% within 40 min. The capture experiments of active species confirm that the ·O₂ ^- and ·OH play major role in photocatalytic degradation process. Furthermore, the optimized mesoporous TiO₂/Ti₃C₂ composite also shows an excellent photocatalytic H₂ production rate of 218.85 μmol g ^-1 h ^-1, resulting in a 5.6 times activity as compared with the pristine mesoporous TiO₂ nanoparticles. This study demonstrates that the MXene family materials can be applied as highly efficient noble-metal-free co-catalysts in the field of photocatalysis.

Key words: Mesoporous TiO₂, Electrostatic self-assembly, Ti₃C₂ MXene, Co-catalyst, Photocatalytic degradation, Photocatalytic hydrogen production

李华鹏, 孙彬, 高婷婷, 李欢, 任永强, 周国伟. Ti₃C₂ MXene助催化剂组装的介孔TiO₂用以增强光催化甲基橙降解和产氢活性[J]. 催化学报, 2022, 43(2): 461-471.

Huapeng Li, Bin Sun, Tingting Gao, Huan Li, Yongqiang Ren, Guowei Zhou. Ti₃C₂ MXene co-catalyst assembled with mesoporous TiO₂ for boosting photocatalytic activity of methyl orange degradation and hydrogen production[J]. Chinese Journal of Catalysis, 2022, 43(2): 461-471.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(21)63915-3

https://www.cjcatal.com/CN/Y2022/V43/I2/461

图/表 10

Fig. 1. (a) Schematic illustration for the synthesis process of mesoporous TiO2/Ti3C2 composites; (b) Zeta potential of Ti3C2 MXene and mesoporous TiO2 nanoparticles; (c) Digital photographs of mesoporous TiO2 nanoparticles, Ti3C2 MXene, and T/M-3% in the aqueous solution.

Fig. 2. (a) XRD patterns of Ti3AlC2 and Ti3C2; (b) XRD patterns of TiO2 and composites with different Ti3C2 contents; (c) Raman spectra of Ti3AlC2, Ti3C2, TiO2, and T/M-3%; (d) The enlarged curves in the range of 100-700 cm-1 in (c).

Fig. 3. N2 adsorption-desorption isotherms and corresponding pore size distribution curves (inset) of TiO2 (a), Ti3C2 (b), T/M-1% (c), T/M-3% (d), T/M-5% (e), and T/M-7% (f).

Fig. 4. TEM images of TiO2 (a), Ti3C2 (b), and T/M-3% (c); (d) HRTEM image of T/M-3%.

Fig. 5. (a) XPS survey spectra of TiO2, Ti3C2, and T/M-3%; high-resolution XPS spectra of Ti 2p (b), C 1s (c), O 1s (d) for Ti3C2 and T/M-3%.

Fig. 6. UV-vis diffuse reflectance spectra (a), band gap plots (b), PL spectra (c), TRPL spectra (d), transient photocurrent (e), and EIS Nyquist plots (f) of the as-prepared samples.

Fig. 7. (a) Photocatalytic degradation of MO; (b) Kinetic linear simulation curves for the photocatalytic degradation of MO; (c) Rate constant of as-synthesized photocatalysts; (d) UV-vis spectra and the solution color (inset) of MO at different photocatalytic degradation time intervals, cycling stability (e), and photocatalytic degradation (f) of MO in the presence of different scavengers over T/M-3%.

Fig. 8. ESR spectra of T/M-3% before and after UV light illumination for DMPO-·O2- (a) and DMPO-·OH (b).

Fig. 9. Photocatalytic H2 production (a) and H2 production rate (b) of as-synthesized photocatalysts.

Fig. 10. Schematic photocatalytic mechanism for photocatalytic MO degradation and H2 production over mesoporous TiO2/Ti3C2 composites.

参考文献

[1]	C. C. Dong, J. Lu, B. C. Qiu, B. Shen, M. Y. Xing, J. L. Zhang , Appl. Catal. B, 2018,222, 146-156.
[2]	F. Y. Xu, K. Meng, B. Cheng, S. Y. Wang, J. S. Xu, J. G. Yu , Nat. Commun., 2020,11, 4613.
[3]	D. B. Zeng, C. L. Yu, Q. Z. Fan, J. L. Zeng, L. F. Wei, Z. S. Li, K. Yang, H. B. Ji , Chem. Eng. J., 2020,391, 123607.
[4]	Z. Z. Liang, R. C. Shen, Y. H. Ng, P. Zhang, Q. J. Xiang, X. Li , J. Mater. Sci. Technol., 2020,56, 89-121.
[5]	D. D. Ren, R. C. Shen, Z. M. Jiang, X. Y. Lu, X. Li , Chin. J. Catal., 2020,41, 31-40.
[6]	C. B. Bie, H. G. Yu, B. Cheng, W. K. Ho, J. J. Fan, J. G. Yu , Adv. Mater., 2021,33, 2003521.
[7]	Z. L. Wang, J. J. Fan, B. Cheng, J. G. Yu, J. S. Xu , Mater. Today Phys., 2020,15, 100279.
[8]	X. T. Liu, S. N. Gu, Y. J. Zhao, G. W. Zhou, W. J. Li , J. Mater. Sci. Technol., 2020,56, 45-68.
[9]	W. Zhang, H. L. He, Y. Tian, K. Lan, Q. Liu, C. Y. Wang, Y. Liu, A. Elzatahry, R. C. Che, W. Li, D. Y. Zhao , Chem. Sci., 2019,10, 1664-1670.
[10]	G. C. Huang, X. Y. Liu, S. R. Shi, S. T. Li, Z. T. Xiao, W. Q. Zhen, S. W. Liu, P. K. Wong , Chin. J. Catal., 2020,41, 50-61.
[11]	F. Y. Chen, C. L. Yu, L. F. Wei, Q. Z. Fan, F. Ma, J. L. Zeng, J. H. Yi, K. Yang, H. B. Ji , Sci. Total Environ., 2020,706, 136026.
[12]	X. H. Zhang, Z. W. Chen, Y. Luo, X. L. Han, Q. Q. Jiang, T. F. Zhou, H. J. Yang, J. C. Hu , J. Hazard. Mater., 2021,405, 124128.
[13]	T. M. Di, L. Y. Zhang, B. Cheng, J. G. Yu, J. J. Fan , J. Mater. Sci. Technol., 2020,56, 170-178.
[14]	Y. Li, D. N. Zhang, J. J. Fan, Q. J. Xiang , Chin. J. Catal., 2021,42, 627-636.
[15]	C. B. Bie, B. Cheng, J. J. Fan, W. K. Ho, J. G. Yu , Energy Chem., 2021,3, 100051.
[16]	K. Lan, L. Liu, W. Zhang, Y. Liu, A. Elzatahry, R. C. Wang, Y. Y. Xia, D. A. Dhayan, N. F. Zheng, D. Y. Zhao , J. Am. Chem. Soc., 2018,140, 4135-4143.
[17]	M. Miodyńska, A. Mikolajczyka, B. Bajorowicz, J. Zwara, T. Klimczuk, W. Lisowski, G. Trykowski, H. P. Pinto, A. Z. Medynsk , Appl. Catal. B, 2020,272, 118962.
[18]	Q. Q. Liu, J. X. Huang, H. Tang, X. H. Yu, J. Shen , J. Mater. Sci. Technol., 2020,56, 196-205.
[19]	Q. Guo, C. Y. Zhou, Z. B. Ma, X. M. Yang , Adv. Mater., 2019,31, 1901997.
[20]	Y. Chen, G. B. Mao, Y. W. Tang, H. Wu, G. Wang, L. Zhang, Q. Liu , Chin. J. Catal., 2021,42, 225-234.
[21]	M. Xiao, L. Zhang, B. Luo, M. Q. Lyu, Z. L. Wang, H. M. Huang, S. C. Wang, A. J. Du, L. Z. Wang , Angew. Chem. Int. Ed., 2020,59, 7230-7234.
[22]	X. Li, J. G. Yu, M. Jaroniec, X. B. Chen , Chem. Rev., 2019,119, 3962-4179.
[23]	J. Liu, G. Hodes, J. Q. Yan, S. Z. Liu , Chin. J. Catal., 2021,42, 205-216.
[24]	F. He, B. C. Zhu, B. Cheng, J. G. Yu, W. K. Ho, W. Macyk , Appl. Catal. B, 2020,272, 119006.
[25]	S. Q. Wu, X. J. Tan, J. Y. Lei, H. J. Chen, L. Z. Wang, J. L. Zhang , J. Am. Chem. Soc., 2019,141, 6592-6600.
[26]	Z. Cao, C. Liu, D. W. Chen, J. Q. Liu , Sci. Total. Environ., 2019,692, 572-581.
[27]	L. Y. Lu, G. H. Wang, Z. W. Xiong, Z. F. Hu, Y. W. Liao, J. Wang, J. Li , Ceram. Int., 2020,46, 10667-10677.
[28]	T. Wojciechowski, A. R. Wojciechowska, G. Matyszczak, M. Wrzecionek, A. Olszyna, A. Peter, A. M. Cozmuta, C. Nicula, L. M. Cozmuta, S. Podsiadło, D. Basiak, W. Ziemkowska, A. Jastrzębska , Inorg. Chem., 2019,58, 7602-7614.
[29]	M. Naguib, M. Kurtoglu, V. Presser, J. Lu, J. Niu, M. Heon, L. Hultman, Y. Gogotsi, M. W. Barsoum , Adv. Mater., 2011,23, 4248-4253.
[30]	M. Naguib, V. N. Mochalin, M. W. Barsoum, Y. Gogotsi , Adv. Mater., 2014,26, 992-1005.
[31]	R. Z. Zhao, M. Q. Wang, D. Y. Zhao, H. Li, C. X. Wang, L. W. Yin , ACS Energy Lett., 2018,3, 132-140.
[32]	P. Y. Kuang, M. He, B. C. Zhu, J. G. Yu, K. Fan, M. Jaroniec , J. Catal., 2019,375, 8-20.
[33]	S. J. Kim, H. J. Koh, C. E. Ren, O. Kwon, K. Maleski, S. Y. Cho, B. Anasori, C. K. Kim, Y. K. Choi, J. H. Kim, Y. Gogotsi, H. T. Jung , ACS Nano, 2018,12, 986-993.
[34]	X. F. Feng, Z. X. Yu, R. X. Long, X. H. Li, L. Y. Shao, H. J. Zeng, G. Y. Zeng, Y. H. Zuo , Sep. Purif. Technol., 2020,253, 117525.
[35]	C. Cai, R. Wang, S. F. Liu, X. Y. Yan, L. X. Zhang, M. L. Wang, Q. Tong, T. F. Jiao , Colloids Surf. A, 2020,589, 124468.
[36]	T. Cai, L. L. Wang, Y. T. Liu, S. Q. Zhang, W. Y. Dong, H. Chen, X. Y. Yi, J. L. Yuan, X. N. Xia, C. B. Liu, S. L. Luo , Appl. Catal. B, 2018,239, 545-554.
[37]	K. N. Li, S. S. Zhang, Y. H. Li, J. J. Fan, K. L. Lv , Chin. J. Catal., 2021,42, 3-14.
[38]	P. Y. Kuang, J. X. Low, B. Cheng, J. G. Yu, J. J. Fan , J. Mater. Sci. Technol., 2020,56, 18-44.
[39]	C. Peng, X. F. Yang, Y. H. Li, H. Yu, H. J. Wang, F. Peng , ACS Appl. Mater. Interfaces, 2016,8, 6051-6060.
[40]	J. X. Low, L. Y. Zhang, T. Tong, B. J. Shen, J. G. Yu , J. Catal., 2018,361, 255-266.
[41]	H. Wang, R. Peng, Z. D. Hood, M. Naguib, S. P. Adhikari, Z. L. Wu , Chem Sus Chem, 2016,9, 1490-1497.
[42]	Y. T. Liu, P. Zhang, N. Sun, B. Anasori, Q. Z. Zhu, H. Liu, Y. Gogotsi, B. Xu , Adv. Mater., 2018,30, 1707334.
[43]	S. Chen, Y. F. Xiang, W. J. Xu, C. Peng , Inorg. Chem. Front., 2019,6, 199-208.
[44]	H. Wang, Y. Wu, T. Xiao, X. Z. Yuan, G. M. Zeng, W. G. Tu, S. Y. Wu, H. Y. Lee, Y. Z. Tan, J. W. Chew , Appl. Catal. B, 2018,233, 213-225.
[45]	S. Y. Lu, G. Meng, C. Wang, H. Chen , Chem. Eng. J., 2021,404, 126526.
[46]	Y. Xie, M. M. Rahman, S. Kareem, H. Dong, F. Qiao, W. Xiong, X. Q. Liu, N. Li, X. J. Zhao , Cryst Eng Comm, 2020,22, 2060-2066.
[47]	N. My Tran, Q. Thanh Hoai Ta, J. S. Noh , Appl. Surf. Sci., 2021,538, 148023.
[48]	Y. F. Dong, Z. S. Wu, S. H. Zheng, X. Wang, J. Qin, S. Wang, X. Shi, X. Bao , ACS Nano, 2017,11, 4792-4800.
[49]	Z. H. Liu, Y. J. Zheng, T. T. Gao, J. Zhang, X. F. Sun, G. W. Zhou , Int. J. Hydrogen Energy, 2017,42, 21775-21785.
[50]	R. Z. Zhao, H. X. Di, X. B. Hui, D. Y. Zhao, R. T. Wang, C. X. Wang, L. W. Yin , Energy Environ. Sci., 2020,13, 246-257.
[51]	S. W. Cao, B. J. Shen, T. Tong, J. W. Fu, J. G. Yu , Adv. Funct. Mater., 2018,28, 1800136.
[52]	H. C. Dai, Y. J. Sun, P. J. Ni, W. D. Lu, S. Jiang, Y. L. Wang, Z. Li, Z. Li, , Sens. Actuators. B, 2017,242, 260-268.
[53]	Y. Q. Sheng, Z. Wei, H. Miao, W. Q. Yao, H. Q. Li, Y. F. Zhu , Chem. Eng. J., 2019,370, 287-294.
[54]	H. H. Wang, H. Z. Cui, X. J. Song, R. Q. Xu, N. Wei, J. Tian, H. S. Niu , J. Colloid Interface Sci., 2020,561, 46-57.
[55]	Y. A. Zhu, Z. Y. Zhang, N. Lu, R. N. Hua, B. Dong , Chin. J. Catal., 2019,40, 413-423.
[56]	B. Sun, F. R. Tao, Z. X. Huang, W. Yan, Y. X. Zhang, X. S. Dong, Y. Wu, G. W. Zhou , Appl. Surf. Sci., 2021,535, 147354.
[57]	C. Wang, X. D. Zhu, Y. C. Mao, F. Wang, X. T. Gao, S. Y. Qiu, S. R. Le, K. N. Sun , Chem. Commun., 2019,55, 1237-1240.
[58]	H. Q. Wang, Q. H. Gong, H. Huang, T. T. Gao, Z. W. Yuan, G. W. Zhou , Mater. Res. Bull., 2018,107, 397-406.
[59]	W. Zheng, P. Zhang, J. Chen, W. B. Tian, Y. M. Zhang, Z. M. Sun , J. Mater. Chem. A, 2018,6, 3543-3551.
[60]	Y. Zhuang, Y. F. Liu, X. F. Meng , Appl. Surf. Sci., 2019,496, 143647.
[61]	F. Y. Xu, K. Meng, B. Zhu, H. B. Liu, J. S. Xu, J. G. Yu , Adv. Funct. Mater., 2019,29, 1904256.
[62]	Z. M. Jiang, Q. Chen, Q. Q. Zheng, R. C. Shen, P. Zhang, X. Li , Acta Phys.-Chim. Sin., 2021,37, 2010059.
[63]	W. Z. Liu, M. X. Sun, Z. P. Ding, B. W. Gao, W. Ding , J. Alloys Compd., 2021,877, 160223.
[64]	C. Sun, Z. Q. Chen, J. Cui, K. Li, H. X. Qu, H. F. Xie, Q. Zhong , Catal. Sci. Technol., 2021,11, 1027-1038.
[65]	J. Y. Shen, J. Shen, W. J. Zhang, X. H. Yu, H. Tang, M. Y. Zhang, Zulfiqar, Q. Q. Liu , Ceram. Int., 2019,45, 24146-24153.
[66]	Y. J. Li, Z. H. Yin, G. R. Ji, Z. Q. Liang, Y. J. Xue, Y. C. Guo, J. Tian, X. Z. Wang, H. Z. Cui , Appl. Catal. B, 2019,246, 12-20.
[67]	B. Sun, G. W. Zhou, T. T. Gao, H. J. Zhang, H. H. Yu , Appl. Surf. Sci., 2016,364, 322-331.
[68]	J. Ren, T. T. Hu, Q. H. Gong, Q. Wang, B. Sun, T. T. Gao, P. Cao, G. W. Zhou , Nanomaterials, 2020,10, 1813.
[69]	J. R. Ran, G. P. Gao, F. T. Li, T. Y. Ma, A. J. Du, S. Z. Qiao , Nat. Commun., 2017,8, 13907.
[70]	Y. J. Li, L. Ding, S. J. Yin, Z. Q. Liang, Y. J. Xue, X. Z. Wang, H. Z. Cui, J. Tian , Nano-Micro Lett., 2020,12, 6.
[71]	S. Q. Wu, H. Y. Hu, Y. Lin, J. L. Zhang, Y. H. Hu , Chem. Eng. J., 2020,382, 122842.

Ti₃C₂ MXene助催化剂组装的介孔TiO₂用以增强光催化甲基橙降解和产氢活性

Ti₃C₂ MXene co-catalyst assembled with mesoporous TiO₂ for boosting photocatalytic activity of methyl orange degradation and hydrogen production

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 10

参考文献

相关文章 15

编辑推荐

Metrics

[1]	刘博文, 蔡家杰, 张建军, 谭海燕, 程蓓, 许景三. MOF/CdS梯型光催化剂同时进行苯甲醇氧化和析氢反应及其机理研究[J]. 催化学报, 2023, 51(8): 204-215.
[2]	李晓娟, 祁明雨, 李婧宇, 谭昌龙, 唐紫蓉, 徐艺军. PdS修饰的ZnIn₂S₄复合材料用于可见光催化硫醇偶联制备二硫化物同时产氢[J]. 催化学报, 2023, 51(8): 55-65.
[3]	刘德法, 孙彬, 白硕杰, 高婷婷, 周国伟. 双助催化剂Ag/Ti₃C₂/TiO₂分层花状微球用于增强光催化产氢活性[J]. 催化学报, 2023, 50(7): 273-283.
[4]	李宁, 高雪云, 苏俊珲, 高旸钦, 戈磊. 类金属WO₂/g-C₃N₄复合光催化剂的构造及其优异的光催化性能[J]. 催化学报, 2023, 47(4): 161-170.
[5]	解志鹏, 杨修贝, 张沛, 柯夏婷, 袁昕, 翟黎鹏, 王文滨, 秦娜, 崔乘幸, 屈凌波, 陈雄. 具有可控载流子动力学的烯烃连接的共价有机框架用于高效太阳能光催化制氢[J]. 催化学报, 2023, 47(4): 171-180.
[6]	王珂然, 罗磊, 王超, 唐军旺. 双反应位点共修饰WO₃光催化活化甲烷[J]. 催化学报, 2023, 46(3): 103-112.
[7]	伍超, 吕康乐, 李鑫, 李覃. 光催化产氢双助催化剂: 类别、合成和设计策略[J]. 催化学报, 2023, 54(11): 137-160.
[8]	钟蕤羽, 梁玉洁, 黄菲, 梁诗诺, 刘升卫. 一维g-C₃N₄/二维Ti₃C₂T_x界面调制促进光催化CO₂还原活性与选择性[J]. 催化学报, 2023, 53(10): 109-122.
[9]	王可, 程淼, 王楠, 张千一, 刘懿, 梁俊威, 管杰, 刘茂昌, 周建成, 李乃旭. 2D/2D超薄La₂Ti₂O₇/Ti₃C₂ Mxene肖特基异质结用于高效光催化CO₂还原[J]. 催化学报, 2023, 44(1): 146-159.
[10]	胡海均, 张开来, 闫格, 史丽童, 贾宝华, 黄洪伟, 张宇, 孙晓东, 马天翼. 通过孔道功能化策略将CdS精准修饰到Zr-MOFs表面构筑高效光解水催化剂[J]. 催化学报, 2022, 43(9): 2332-2341.
[11]	张宪文, 李政, 刘太丰, 李名润, 曾超斌, 松本弘昭, 韩洪宪. Pt/SrTiO₃光催化全分解水过程中水氧化活性位点的研究[J]. 催化学报, 2022, 43(8): 2223-2230.
[12]	张美玉, 秦朝朝, 孙万军, 董聪朝, 钟俊, 吴凯丰, 丁勇. 双助催化剂负载CdS的能量捕集和电荷分离增强产H₂[J]. 催化学报, 2022, 43(7): 1818-1829.
[13]	赵辉, 茅沁怡, 蹇亮, 董玉明, 朱永法. 光催化水分解中地球储量丰富助催化剂的光沉积方法、功能与机理[J]. 催化学报, 2022, 43(7): 1774-1804.
[14]	钟威, 许家超, 王苹, 朱必成, 范佳杰, 余火根. 新型核壳Ag@AgSe_x纳米粒子析氢助剂: 原位表面硒化以提升TiO₂的光催化产氢活性[J]. 催化学报, 2022, 43(4): 1074-1083.
[15]	张亚萍, 徐继香, 周洁, 王磊. 金属-有机框架衍生的多功能光催化剂[J]. 催化学报, 2022, 43(4): 971-1000.