2D/2D超薄La2Ti2O7/Ti3C2 Mxene肖特基异质结用于高效光催化CO2还原

doi:10.1016/S1872-2067(22)64155-X

催化学报 ›› 2023, Vol. 44: 146-159.DOI: 10.1016/S1872-2067(22)64155-X

2D/2D超薄La₂Ti₂O₇/Ti₃C₂ Mxene肖特基异质结用于高效光催化CO₂还原

王可^a^,¹, 程淼^a^,¹, 王楠^a, 张千一^a, 刘懿^a, 梁俊威^a, 管杰^b^,^*(), 刘茂昌^c^,^*(), 周建成^a^,^d, 李乃旭^a^,^d^,^*()

^a东南大学化学化工学院, 江苏南京 211189
^b东南大学物理学院, 江苏南京 211189
^c西安交通大学动力工程多相流国家重点实验室, 国际可再生能源研究中心, 陕西西安 710049
^d中国林业科学研究院林产化学工业研究所, 江苏省生物质能源与材料重点实验室, 江苏南京 210042

收稿日期:2022-06-14 接受日期:2022-07-18 出版日期:2023-01-18 发布日期:2022-12-08
通讯作者: 管杰,刘茂昌,李乃旭
作者简介:¹共同第一作者.
基金资助:
国家自然科学基金(21576050);国家自然科学基金(21227801);中央高校基本科研业务费项目(3207045403);中央高校基本科研业务费项目(3207042107D);中央高校基本科研业务费项目(3207042108D);江苏省生物质能源与材料重点实验室开放基金资助项目(JSBEM202001);江苏高校优势学科建设工程资助项目(PAPD);东南大学“仲英青年学者”;江苏省研究生科研实践创新计划(SJCX20_0014);江苏省研究生科研实践创新计划(SJCX20_0015)

Inter-plane 2D/2D ultrathin La₂Ti₂O₇/Ti₃C₂ MXene Schottky heterojunctions toward high-efficiency photocatalytic CO₂ reduction

Ke Wang^a^,¹, Miao Cheng^a^,¹, Nan Wang^a, Qianyi Zhang^a, Yi Liu^a, Junwei Liang^a, Jie Guan^b^,^*(), Maochang Liu^c^,^*(), Jiancheng Zhou^a^,^d, Naixu Li^a^,^d^,^*()

^aSchool of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, Jiangsu, China
^bSchool of Physics, Southeast University, Nanjing 211189, Jiangsu, China
^cInternational Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an 710049, Shaanxi, China
^dInstitute of Chemical Industry of Forest Products of the Chinese Academy of Forestry Sciences, Jiangsu Key Laboratory for Biomass Energy and Material, Nanjing 210042, Jiangsu, China

Received:2022-06-14 Accepted:2022-07-18 Online:2023-01-18 Published:2022-12-08
Contact: Jie Guan, Maochang Liu, Naixu Li
About author:¹ Contributed equally to this work.
Supported by:
National Natural Science Foundation of China(21576050);National Natural Science Foundation of China(21227801);Fundamental Research Funds for the Central Universities of China(3207045403);Fundamental Research Funds for the Central Universities of China(3207042107D);Fundamental Research Funds for the Central Universities of China(3207042108D);Foundation of Jiangsu Key Laboratory for Biomass Energy and Material(JSBEM202001);Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD);Zhongying Young Scholars of Southeast University;Postgraduate Research & Practice Innovation Program of Jiangsu Province(SJCX20_0014);Postgraduate Research & Practice Innovation Program of Jiangsu Province(SJCX20_0015)

摘要/Abstract

摘要：

CO₂的过量排放造成了全球生态系统的失衡, 如温室效应、海洋酸化和极端天气频发等. CO₂作为一种储量丰富且可循环利用的碳一资源, 利用光催化技术将其催化转化为包括一氧化碳和甲烷在内的碳氢燃料, 为上述问题提供了一个很有前景的解决方案. 纳米片作为典型的二维材料, 其厚度一般低至100 nm. 此外, 二维材料具有较大的比表面积、可调谐的端基官能团、出色的光学性能以及较好的导电性和柔韧性, 在光催化领域受到了广泛关注. 在半导体材料中, 钛酸镧(La₂Ti₂O₇)具有优良的氧化还原能力和良好的稳定性和耐久性, 但与其他半导体类似, La₂Ti₂O₇的宽带隙性质决定了其只能利用波长较短的光, 这极大地限制了其对太阳光的利用.

为了增强光吸收能力, 降低光生载流子的复合, 本文通过溶剂热法在La₂Ti₂O₇纳米片上负载薄层Ti₃C₂ MXene纳米片, 设计制备了二维/二维(2D/2D) La₂Ti₂O₇/Ti₃C₂ Mxene肖特基异质结复合材料, 并用于增强光催化CO₂还原性能. 研究发现, 当Ti₃C₂ MXene的负载量为3 wt%时, CO和CH₄的产率是物理混合的La₂Ti₂O₇和Ti₃C₂ MXene的4.6倍和11.4倍. 飞秒瞬态吸收光谱和X射线光电子能谱结果表明, La₂Ti₂O₇/Ti₃C₂ Mxene较好的光催化CO₂还原反应性能归因于高效电荷载流子迁移率和两组分接触界面之间形成了肖特基异质结的协同作用. 原位红外漫反射光谱观察到的反应中间产物、紫外光电子能谱计算得到的功函数和原子层级的密度泛函理论计算得到的吉布斯自由能和差分电荷密度揭示了该体系光催化CO₂还原的机理、光催化反应的路径和产物选择性的由来.

相比于单独的La₂Ti₂O₇和物理混合的La₂Ti₂O₇和Ti₃C₂ MXene, 2D/2D La₂Ti₂O₇/Ti₃C₂ Mxene肖特基异质结复合材料表现出增强的光催化CO₂还原性能. 引入Ti₃C₂ MXene形成平面间2D/2D的异质结结构可作为电荷转移通道并促进电荷的快速分离, 形成的肖特基结能够有效地抑制光生电子的回流, 同时降低了光催化CO₂还原的反应势垒, 最终促进了光催化CO₂还原过程. 综上, 本文详细阐述了肖特基异质结构中光催化性能增强的机理机制, 并为设计和制造用于转化和利用二氧化碳的光催化剂及其探究光催化转化机理提供借鉴.

关键词: 钛酸镧, Ti₃C₂ MXene, 光催化CO₂还原, 二维/二维, 肖特基异质结

Abstract:

Ascribing to incremental fossil fuels emissions, the utilization and conversion of CO₂ and development of renewable energy is globally essential and significative. Ultrathin 2D/2D heterojunctions with fast photo-generated electrons transmission channels illustrate a better strategy to improve photocatalytic activity. Herein, combing La₂Ti₂O₇ with metallic few-layered Ti₃C₂ MXene to construct inter-plane 2D/2D heterojunction was in situ self-assembled through solvothermal method. Benefiting from the advantages including stability, conductivity, abundant active sites and formation of Schottky junctions, as expected, the ultrathin 2D/2D La₂Ti₂O₇/Ti₃C₂ MXene nanosheets presented much improved photocatalytic ability for CO₂ reduction to CO and CH₄, which is about 4.6 and 11.4 times higher than that of mechanical mixed La₂Ti₂O₇ and Ti₃C₂ MXene. fs-TAS and XPS provided direct evidence that the prominence of La₂Ti₂O₇/Ti₃C₂ MXene in photocatalytic CO₂ reduction reaction over other opponents should be attributed to the synergetic effect of efficient charge carrier mobility and formed 2D/2D Schottky heterojunction interfacial contact between La₂Ti₂O₇ and Ti₃C₂ MXene. Intermediates revealed by in-situ DRIFTS and corresponding atomic-level DFT calculations confirmed the mechanism, pathways and selectivity for photocatalytic CO₂ conversion. This work expanded promising prospects arouses new impetus for deepening the prehension of the mechanism of photocatalytic CO₂ reduction, designing and fabrication of Schottky heterojunctions for application in conversion and utilization of CO₂.

Key words: La₂Ti₂O₇, Ti₃C₂ MXene, Photocatalytic CO₂ reduction, 2D/2D, Schottky heterojunction

王可, 程淼, 王楠, 张千一, 刘懿, 梁俊威, 管杰, 刘茂昌, 周建成, 李乃旭. 2D/2D超薄La₂Ti₂O₇/Ti₃C₂ Mxene肖特基异质结用于高效光催化CO₂还原[J]. 催化学报, 2023, 44: 146-159.

Ke Wang, Miao Cheng, Nan Wang, Qianyi Zhang, Yi Liu, Junwei Liang, Jie Guan, Maochang Liu, Jiancheng Zhou, Naixu Li. Inter-plane 2D/2D ultrathin La₂Ti₂O₇/Ti₃C₂ MXene Schottky heterojunctions toward high-efficiency photocatalytic CO₂ reduction[J]. Chinese Journal of Catalysis, 2023, 44: 146-159.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(22)64155-X

https://www.cjcatal.com/CN/Y2023/V44/I1/146

图/表 10

Scheme 1. Schematic of the synthetic route of the inter-plane 2D/2D ultrathin La2Ti2O7/Ti3C2 MXene nanosheets.

Fig. 1. FESEM images of La2Ti2O7 nanosheets (a), bulk Ti3C2 (b) and LTM-3 composites (c). AFM images of La2Ti2O7 nanosheets (d), few-layered Ti3C2 MXene (e) and corresponding height cutaway view (f).

Fig. 2. (a) XRD patterns of La2Ti2O7, LTM-3 composite and few-layered Ti3C2 MXene. TEM images of La2Ti2O7 nanosheets (b), few-layered Ti3C2 MXene (c). HRTEM images of LTM-3 composites (d,e) and corresponding lattice spacing of La2Ti2O7 (f) and Ti3C2 MXene (g). (h) HAADF-STEM of LTM-3 and EDX element mapping images of La, Ti, O and C.

Fig. 3. UV-vis spectra (a), and N2 adsorption-desorption isotherms with inset pore size distribution spectra (b).

Fig. 4. XPS spectra of survey spectra (a), and high-resolution XPS spectra of La 3d (b), C 1s (c), O 1s (d), Ti 2p (e), diagram (f) of the bond connection between La2Ti2O7 and Ti3C2 MXene.

Fig. 5. (a) CO, CH4 and H2 products over as-prepared photocatalysts. (b) The CO2 reduction and H4 selectivity. (c) Recycling photocatalytic production experiments over LTM-3. (d) GC-MS spectra of the photocatalytic 13CO2 reduction over LTM-3.

Fig. 6. PL spectra (a), TRPL decay spectra (b), Femtosecond transient absorption spectroscopy (fs-TAS) (c,d), Transient photocurrent response (e) and electrochemical impedance spectroscopy (EIS) Nyquist plots (f) of as-prepared samples.

Fig. 7. In-situ DRIFTS of CO2 reduction reaction on LTO and LTM-3 in the spectral regions of 1000?2000 (a), 2600?3500 (b) and 3400?4000 (c) cm?1. (1)?(5) are black, balance, irradiation of 30, 60 and 90 min, respectively.

Fig. 8. (a) Charge density difference. (b) Planar-averaged charge density difference Δρ(z) LTM. The blue color and yellow color in the plot of charge density difference represent the dissipation and accumulation of the charges. (c) Free energy profiles for CO2 reduction on LTO and LTM. (d) Structures for the intermediates on LTM (see details in the Supporting Information).

Scheme 2. Energy scheme before, after contact and under light irradiation of LTO and Ti3C2 MXene.

参考文献

[1]	P. Friedlingstein, M. O'Sullivan, M. W. Jones, R. M. Andrew, J. Hauck, A. Olsen, G. P. Peters, W. Peters, J. Pongratz, S. Sitch, C. Le Quéré, J. G. Canadell, P. Ciais, R. B. Jackson, S. Alin, LEOC Aragão, A. Arneth, V. Arora, N. R. Bates, M. Becker, A. Benoit-Cattin, H. C. Bittig, L. Bopp, S. Bultan, N. Chandra, F. Chevallier, L. P. Chini, W. Evans, L. Florentie, P. M. Forster, T. Gasser, M. Gehlen, D. Gilfillan, T. Gkritzalis, L. Gregor, N. Gruber, I. Harris, K. Hartung, V. Haverd, R. A. Houghton, T. Ilyina, A. K. Jain, E. Joetzjer, K. Kadono, E. Kato, V. Kitidis, J. I. Korsbakken, P. Landschützer, N. Lefèvre, A. Lenton, S. Lienert, Z. Liu, D. Lombardozzi, G. Marland, N. Metzl, D. R. Munro, JEMS Nabel, S.-I. Nakaoka, Y. Niwa, K. O'Brien, T. Ono, P. I. Palmer, D. Pierrot, B. Poulter, L. Resplandy, E. Robertson, C. Rödenbeck, J. Schwinger, R. Séférian, I. Skjelvan, A. J. P. Smith, A. J. Sutton, T. Tanhua, P. P. Tans, H. Tian, B. Tilbrook, G. van der Werf, N. Vuichard, A. P. Walker, R. Wanninkhof, A. J. Watson, D. Willis, A. J. Wiltshire, W. Yuan, X. Yue, S. Zaehle, Earth Syst. Sci. Data, 2020, 12, 3269-3340.
[2]	M. Lickley, S. Solomon, S. Fletcher, G. J. M. Velders, J. Daniel, M. Rigby, S. A. Montzka, L. J. M. Kuijpers, K. Stone, Nat. Commun., 2020, 11, 1380.
[3]	U. Riebesell, J. P. Gattuso, Nat. Clim. Change, 2014, 5, 12-14.
[4]	S. Wei, G. Han, X. Chu, B. Sun, W. Song, W. He, X. Wang, P. Li, D. Yu, Agr. Forest. Meteorol., 2021, 310, 108655.
[5]	Y. X. Pan, Y. You, S. Xin, Y. Li, G. Fu, Z. Cui, Y. L. Men, F. F. Cao, S. H. Yu, J. B. Goodenough, J. Am. Chem. Soc., 2017, 139, 4123-4129.
[6]	Q. Li, Y. Ouyang, H. Li, L. Wang, J. Zeng, Angew. Chem. Int. Ed., 2022, 61, e202108069.
[7]	Y. Wang, S. Wang, X. W. D. Lou, Angew. Chem. Int. Ed., 2019, 58, 17236-17240.
[8]	Y. Wang, X. Shang, J. Shen, Z. Zhang, D. Wang, J. Lin, J. C. S. Wu, X. Fu, X. Wang, C. Li, Nat. Commun., 2020, 11, 3043.
[9]	C. Bie, B. Zhu, F. Xu, L. Zhang, J. Yu, Adv. Mater., 2019, 31, 1902868.
[10]	E. Gong, S. Ali, C. B. Hiragond, H. S. Kim, N. S. Powar, D. Kim, H. Kim, S. I. In, Energy Environ. Sci., 2022, 15, 880-937.
[11]	J. Ran, W. Guo, H. Wang, B. Zhu, J. Yu, S. Z. Qiao, Adv. Mater., 2018, 30, e1800128.
[12]	Y. Xue, G. Zhao, R. Yang, F. Chu, J. Chen, L. Wang, X. Huang, Nanoscale, 2021, 13, 3911-3936.
[13]	Z. Wang, B. Cheng, L. Zhang, J. Yu, Y. Li, S. Wageh, A. A. Al-Ghamdi, Chin. J. Catal., 2022, 43, 1657-1666.
[14]	D. Zhao, Y. Wang, C. L. Dong, Y. C. Huang, J. Chen, F. Xue, S. Shen, L. Guo, Nat. Energy, 2021, 6, 388-397.
[15]	P. Salles, E. Quain, N. Kurra, A. Sarycheva, Y. Gogotsi, Small, 2018, 14, e1802864.
[16]	K. Maleski, C. E. Ren, M. Q. Zhao, B. Anasori, Y. Gogotsi, ACS Appl. Mater. Interfaces, 2018, 10, 24491-24498.
[17]	P. Zhao, M. Amani, D. H. Lien, G. H. Ahn, D. Kiriya, J. P. Mastandrea, J. W. Ager, 3rd, E. Yablonovitch, D. C. Chrzan, A. Javey, Nano Lett., 2017, 17, 5356-5360.
[18]	Y. J. Yuan, Z. Shen, S. Wu, Y. Su, L. Pei, Z. Ji, M. Ding, W. Bai, Y. Chen, Z. T. Yu, Z. Zou, Appl. Catal. B, 2019, 246, 120-128.
[19]	M. Madi, M. Tahir, S. Tasleem, J. Environ. Chem. Eng., 2021, 9, 106264.
[20]	E. Hua, S. Jin, X. Wang, S. Ni, G. Liu, X. Xu, Appl. Catal. B, 2019, 245, 733-742.
[21]	R. Boppella, C. H. Choi, J. Moon, D. Ha Kim, Appl. Catal. B, 2018, 239, 178-186.
[22]	S. Hu, L. Jia, B. Chi, J. Pu, L. Jian, J. Power Sources, 2014, 266, 304-312.
[23]	X. Hou, L. Cui, H. Du, L. Gu, Z. Li, Y. Yuan, Appl. Catal. B, 2020, 278, 119253.
[24]	Y. Liu, P. Stradins, S. H. Wei, Sci. Adv., 2016, 2, e1600069.
[25]	B. Li, S. Liu, C. Lai, G. Zeng, M. Zhang, M. Zhou, D. Huang, L. Qin, X. Liu, Z. Li, N. An, F. Xu, H. Yi, Y. Zhang, L. Chen, Appl. Catal. B, 2020, 266, 118650.
[26]	S. Li, L. Shao, Z. Yang, S. Cheng, C. Yang, Y. Liu, X. Xia, Green Energy Environ., 2022, 7, 246-256.
[27]	B. Shao, Z. Liu, G. Zeng, Y. Liu, Q. Liang, Q He, T Wu, Y Pan, J Huang, Z Peng, S Luo, C Liang, X Liu, S Tong, J Liang, Appl. Catal. B, 2021, 286, 119867.
[28]	M. Ghidiu, M. R. Lukatskaya, M. Q. Zhao, Y. Gogotsi, M. W. Barsoum, Nature, 2014, 516, 78-81.
[29]	X. Zhan, C. Si, J. Zhou, Z. Sun, Nanoscale Horiz., 2020, 5, 235-258.
[30]	K. Li, S. Zhang, Y. Li, J. Fan, K. Lv, Chin. J. Catal., 2021, 42, 3-14.
[31]	H. Li, B. Sun, T. Gao, H. Li, Y. Ren, G. Zhou, Chin. J. Catal., 2022, 43, 461-471.
[32]	Y. Yang, Z. Zeng, G. Zeng, D. Huang, R. Xiao, C. Zhang, C. Zhou, W. Xiong, W. Wang, M. Cheng, W. Xue, H. Guo, X. Tang, D. He, Appl. Catal. B, 2019, 258, 117956.
[33]	L. Zhu, Y. Lin, K. Liu, E. Cortés, H. Li, J. Hu, A. Yamaguchi, X. Liu, M. Miyauchi, J. Fu, M. Liu, Chin. J. Catal., 2021, 42, 1500-1508.
[34]	B. Yang, K. Liu, H. Li, C. Liu, J. Fu, H. Li, J. E. Huang, P. Ou, T. Alkayyali, C. Cai, Y. Duan, H. Liu, P. An, N. Zhang, W. Li, X. Qiu, C. Jia, J. Hu, L. Chai, Z. Lin, Y. Gao, M. Miyauchi, E. Cortes, S. A. Maier, M. Liu, J. Am. Chem. Soc., 2022, 144, 3039-3049.
[35]	J. Fu, L. Zhu, K. Jiang, K. Liu, Z. Wang, X. Qiu, H. Li, J. Hu, H. Pan, Y. R. Lu, T. S. Chan, M. Liu, Chem. Eng. J., 2021, 415, 128982.
[36]	J. Fu, K. Liu, K. Jiang, H. Li, P. An, W. Li, N. Zhang, H. Li, X. Xu, H. Zhou, D. Tang, X. Wang, X. Qiu, M. Liu, Adv. Sci., 2019, 6, 1900796.
[37]	H. Lin, X. Wang, L. Yu, Y. Chen, J. Shi, Nano Lett., 2017, 17, 384-391.
[38]	H. Xu, R. Xiao, J. Huang, Y. Jiang, C. Zhao, X. Yang, Chin. J. Catal., 2021, 42, 107-114.
[39]	M. Zhu, X. Cai, M. Fujitsuka, J. Zhang, T. Majima, Angew. Chem. Int. Ed., 2017, 56, 2064-2068.
[40]	G. Deysher, C. E. Shuck, K. Hantanasirisakul, N. C. Frey, A. C. Foucher, K. Maleski, A. Sarycheva, V. B. Shenoy, E. A. Stach, B. Anasori, Y. Gogotsi, ACS Nano, 2020, 14, 204-217.
[41]	Y. Qin, H. Li, J. Lu, Y. Feng, F. Meng, C. Ma, Y. Yan, M. Meng, Appl. Catal. B, 2020, 277, 119254.
[42]	D. Zhao, P. Wang, H. Di, P. Zhang, X. Hui, L. Yin, Adv. Funct. Mater., 2021, 31, 2010544.
[43]	M. Ding, W. Ao, H. Xu, W. Chen, L. Tao, Z. Shen, H. Liu, C. Lu, Z. Xie, J. Hazard. Mater., 2021, 420, 126686.
[44]	J. Bai, R. Shen, Z. Jiang, P. Zhang, Y. Li, X. Li, Chin. J. Catal., 2022, 43, 359-369.
[45]	K. S. W. Sing, D. H. Everett, R. A. W. Haul, L. Moscou, R. A. Pierotti, J. Rouquerol, T. Siemieniewska, Pure Appl. Chem., 1985, 57, 603-619.
[46]	R. Swami, R. Bokolia, K. Sreenivas, Ceram. Int., 2020, 46, 26790-26799.
[47]	K. Krishnankutty, K. R. Dayas, Bull. Mater. Sci., 2008, 31, 907-918.
[48]	L. Cheng, Q. Chen, J. Li, H. Liu, Appl. Catal. B, 2020, 267, 118379.
[49]	C. Li, D. Ma, S. Mou, Y. Luo, B. Ma, S. Lu, G. Cui, Q. Li, Q. Liu, X. Sun, J. Energy Chem., 2020, 50, 402-408.
[50]	D. Guo, X. Li, Y. Jiao, H. Yan, A. Wu, G. Yang, Y. Wang, C. Tian, H. Fu, Nano Res., 2021, 15, 238-247.
[51]	J. Low, L. Zhang, T. Tong, B. Shen, J. Yu, J. Catal., 2018, 361, 255-266.
[52]	D. Xu, Y. Ma, J. Wang, W. Chen, Y. Tang, X. Li, L. Li, Chem. Eng. J., 2021, 426, 131246.
[53]	J. Halim, K. M. Cook, M. Naguib, P. Eklund, Y. Gogotsi, J. Rosen, M. W. Barsoum, Appl. Surf. Sci., 2016, 362, 406-417.
[54]	S. Zhao, D. Pan, Q. Liang, M. Zhou, C. Yao, S. Xu, Z. Li, J. Phys. Chem. C, 2021, 125, 10207-10218.
[55]	J. Qin, X. Hu, X. Li, Z. Yin, B. Liu, K.-h. Lam, Nano Energy, 2019, 61, 27-35.
[56]	Z. Pan, F. Cao, X. Hu, X. Ji, J. Mater. Chem. A, 2019, 7, 8984-8992.
[57]	Y. Wu, W. Xu, W. Tang, Z. Wang, Y. Wang, Z. Lv, Y. Zhang, W. Zhong, H. L. Cai, R. Yang, X. S. Wu, Nano Energy, 2021, 90, 106532.
[58]	F. Raziq, L. Sun, Y. Wang, X. Zhang, M. Humayun, S. Ali, L. Bai, Y. Qu, H. Yu, L. Jing, Adv. Energy Mater., 2018, 8, 1701580.
[59]	N. Liu, N. Lu, Y. Su, P. Wang, X. Quan, Sep. Purif. Technol., 2019, 211, 782-789.
[60]	Y. Chen, H. Lian, Y. Wei, X. He, Y. Chen, B. Wang, Q. Zeng, J. Lin, Nanoscale, 2018, 10, 6734-6743.
[61]	R. Tang, D. Gong, Y. Deng, S. Xiong, J. Deng, L. Li, Z. Zhou, J. Zheng, L. Su, L. Yang, Chem. Eng. J., 2022, 427, 131809.
[62]	Z. Huang, Y. Lin, X. Xiang, W. Rodríguez-Córdoba, K. J. McDonald, K. S. Hagen, K. S. Choi, B. S. Brunschwig, D. G Musaev, C. L. Hill, D. Wang, T. Lian, Energy Environ. Sci., 2012, 5, 8923-8926.
[63]	Z. Zhang, B. Wang, H. B. Zhao, J. F. Liao, Z. C. Zhou, T. Liu, B. He, Q. Wei, S. Chen, H. Y. Chen, D. B. Kuang, Y. Li,G Xing, Appl. Catal. B, 2022, 312, 121358.
[64]	Z. Zhang, Y. Li, C. Liang, G. Yu, J. Zhao, S. Luo, Y. Huang, C. Su, G. Xing, Small, 2020, 16, 1905896.
[65]	Z. Yan, W. Wang, L. Du, J. Zhu, D. L. Phillips, J. Xu, Appl. Catal. B, 2020, 275, 119151.
[66]	A. Dabirian, R. van de Krol, Chem. Mater., 2015, 27, 708-715.
[67]	H. Li, H. Zhou, Y. Zhou, J. Hu, M. Miyauchi, J. Fu, M. Liu, Chin. J. Catal., 2022, 43, 519-525.
[68]	W. Luo, Z. Li, X. Jiang, T. Yu, L. Liu, X. Chen, J. Ye, Z. Zou, Phys. Chem. Chem. Phys., 2008, 10, 6717-6723.
[69]	L. Wang, B. Cheng, L. Zhang, J. Yu, Small, 2021, 17, 2103447.
[70]	L. Wang, H. Tan, L. Zhang, B. Cheng, J. Yu, Chem. Eng. J., 2021, 411, 128501.
[71]	Z. Ma, P. Li, L. Ye, Y. Zhou, F. Su, C. Ding, H. Xie, Y. Bai, P. K. Wong, J. Mater. Chem. A, 2017, 5, 24995-25004.
[72]	F. He, B. Zhu, B. Cheng, J. Yu, W. Ho, W. Macyk, Appl. Catal. B, 2020, 272, 119006.
[73]	W. G. Cui, X. Y. Zhuang, Y. T. Li, H. Zhang, J. J. Dai, L. Zhou, Z. Hu, T. L. Hu, Appl. Catal. B, 2021, 287, 119959.
[74]	J. Zhao, Y. Wang, Y. Li, X. Yue, C. Wang, Catal. Sci. Technol., 2016, 6, 7967-7975.
[75]	G. Henkelman, A. Arnaldsson, H. Jónsson, Comput. Mater. Sci., 2006, 36, 354-360.
[76]	Y. Gao, H. Zhuo, Y. Cao, X. Sun, G. Zhuang, S. Deng, X. Zhong, Z. Wei, J. Wang, Chin. J. Catal., 2019, 40, 152-159.
[77]	J. Fu, K. Jiang, X. Qiu, J. Yu, M. Liu, Mater. Today, 2020, 32, 222-243.
[78]	S. Rajput, M. X. Chen, Y. Liu, Y. Y. Li, M. Weinert, L. Li, Nat. Commun., 2013, 4, 2752.

2D/2D超薄La₂Ti₂O₇/Ti₃C₂ Mxene肖特基异质结用于高效光催化CO₂还原

Inter-plane 2D/2D ultrathin La₂Ti₂O₇/Ti₃C₂ MXene Schottky heterojunctions toward high-efficiency photocatalytic CO₂ reduction

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 10

参考文献

相关文章 15

编辑推荐

Metrics

[1]	宋明明, 宋相海, 刘鑫, 周伟强, 霍鹏伟. ZnIn₂S₄/MOF-808微球结构S型异质结光催化剂的制备及其光还原CO₂性能研究[J]. 催化学报, 2023, 51(8): 180-192.
[2]	邵秀丽, 李可, 李静萍, 程强, 王国宏, 王楷. 揭示NiS@Ta₂O₅纳米纤维中梯型电荷转移路径及光催化CO₂转化性能[J]. 催化学报, 2023, 51(8): 193-203.
[3]	李嘉明, 李源, 王小田, 杨直雄, 张高科. TiO₂上原子分散的Fe位点促进光催化CO₂还原: 增强的催化活性、 DFT计算和机制洞察[J]. 催化学报, 2023, 51(8): 145-156.
[4]	夏思源, 李奇远, 张仕楠, 许冬, 林秀, 孙露菡, 许景三, 陈接胜, 李国栋, 李新昊. Pd纳米立方体异质结尺寸依赖的电子界面效应对苯酚加氢反应的促进作用[J]. 催化学报, 2023, 49(6): 180-187.
[5]	何厚伟, 王中辽, 代凯, 李素文, 张金锋. LSPR效应增强碳包覆In₂O₃/W₁₈O₄₉ S型异质结用于高效CO₂光还原[J]. 催化学报, 2023, 48(5): 267-278.
[6]	陈成成, 刘芳庭, 张巧钰, 张正国, 刘琼, 方晓明. 理论设计和实验研究吡啶掺杂聚合氮化碳提升光催化CO₂还原性能[J]. 催化学报, 2023, 46(3): 91-102.
[7]	王中辽, 程蓓, 张留洋, 余家国, 李佑稷, S. Wageh, Ahmed A. Al-Ghamdi. 梯型2D/2D Bi₂MoO₆/BiOI范德华异质结的制备及CO₂光还原性能[J]. 催化学报, 2022, 43(7): 1657-1666.
[8]	赵君泽, 薛敏, 季梦夏, 王彬, 王雨, 李英杰, 陈自然, 李华明, 夏杰祥. “电子集流体”Bi₁₉S₂₇Br₃/BiOBr复合材料的制备及其增强光催化CO₂还原性能[J]. 催化学报, 2022, 43(5): 1324-1330.
[9]	白浚贤, 沈荣晨, 姜志民, 张鹏, 李佑稷, 李鑫. 集成二维层状CdS/WO₃ S型异质结及金属化Ti₃C₂ MXene基欧姆结高效光催化产氢[J]. 催化学报, 2022, 43(2): 359-369.
[10]	李华鹏, 孙彬, 高婷婷, 李欢, 任永强, 周国伟. Ti₃C₂ MXene助催化剂组装的介孔TiO₂用以增强光催化甲基橙降解和产氢活性[J]. 催化学报, 2022, 43(2): 461-471.
[11]	黄悦, 代凯, 张金锋, Graham Dawson. 具有高效电荷转移的W₁₈O₄₉/CdSe-二乙烯三胺光催化CO₂转化: LSPR效应和S型异质结协同效应[J]. 催化学报, 2022, 43(10): 2539-2547.
[12]	王佳琦, 程浩, 魏丁琼, 李朝晖. 超声辅助制备Cs₂AgBiBr₆/Bi₂WO₆ S型异质结用于可见光光催化CO₂还原[J]. 催化学报, 2022, 43(10): 2606-2614.
[13]	赵小雪, 许梦阳, 宋相海, 周伟强, 刘鑫, 霍鹏伟. Fe-MOF/g-C₃N₄嵌入式3D/2D S型异质结的构建及其光还原CO₂性能[J]. 催化学报, 2022, 43(10): 2625-2636.
[14]	王乐乐, 杨涛, 彭李杰, 张琪琪, 佘希林, 唐华, 刘芹芹. 2D/2D/2D三明治结构ZnIn₂S₄/g-C₃N₄/Ti₃C₂ Mxene S型异质结-肖特基结双通道电荷转移路径促进的光催化析氢[J]. 催化学报, 2022, 43(10): 2720-2731.
[15]	王立博, 朱必成, 程蓓, 张建军, 张留洋, 余家国. 原位制备氧化钛/氮掺杂石墨烯空心球光催化剂及其光催化CO₂还原性能研究[J]. 催化学报, 2021, 42(10): 1648-1658.