表面应力介导的碳基Pt纳米催化剂用于硝基芳烃的高选择性加氢

doi:10.1016/S1872-2067(23)64424-9

催化学报 ›› 2023, Vol. 48: 195-204.DOI: 10.1016/S1872-2067(23)64424-9

表面应力介导的碳基Pt纳米催化剂用于硝基芳烃的高选择性加氢

张锋伟^a^,^*^,¹(), 郭河芳^a^,¹, 刘萌萌^a, 赵阳^d, 洪峰^b, 李静静^a, 董正平^c^,^*(), 乔波涛^b^,^*()

^a山西大学晶态材料研究所, 分子科学研究所, 山西太原030006
^b中国科学院大连化学物理研究所, 中国科学院应用催化科学与技术重点实验室, 辽宁大连116023
^c兰州大学化学化工学院, 甘肃兰州730000
^d中国科学院大连化学物理研究所, 洁净能源国家实验室(筹), 辽宁大连116023

收稿日期:2022-12-07 接受日期:2023-03-01 出版日期:2023-05-18 发布日期:2023-04-20
通讯作者: * 电子信箱: fwzhang@sxu.edu.cn (张锋伟), dongzhp@lzu.edu.cn (董正平),bqiao@dicp.ac.cn (乔波涛).
作者简介:第一联系人：
¹共同第一作者
基金资助:
国家自然科学基金(22272095);国家自然科学基金(22172067);山西省省筹资金资助回国留学人员科研项目(2022-003);山西省自然科学研究基金(20210302123434);甘肃省自然科学基金(21YF5GA101)

Enhancing the chemoselective hydrogenation of nitroarenes: Designing a novel surface-strained carbon-based Pt nanocatalyst

Fengwei Zhang^a^,^*^,¹(), Hefang Guo^a^,¹, Mengmeng Liu^a, Yang Zhao^d, Feng Hong^b, Jingjing Li^a, Zhengping Dong^c^,^*(), Botao Qiao^b^,^*()

^aInstitute of Crystalline Materials, Institute of Molecular Science, Shanxi University, Taiyuan 030006, Shanxi, China
^bCAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
^cCollege of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, Gansu, China
^dDalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Received:2022-12-07 Accepted:2023-03-01 Online:2023-05-18 Published:2023-04-20
Contact: * E-mail: fwzhang@sxu.edu.cn (F. Zhang), dongzhp@lzu.edu.cn (Z. Dong), bqiao@dicp.ac.cn (B. Qiao).
About author:First author contact:
¹Contributed equally to this work.
Supported by:
National Natural Science Foundation of China(22272095);National Natural Science Foundation of China(22172067);Shanxi Scholarship Council of China(2022-003);Natural Science Research Foundation of Shanxi Province(20210302123434);Natural Science Foundation of Gansu(21YF5GA101)

摘要/Abstract

摘要：

苯胺衍生物是合成药物、杀虫剂、颜料和染料等化工原料的重要中间体, 其主要由硝基芳烃选择加氢制得. 该反应通常在较高的温度和压力下进行, 尤其是底物中含有其他官能团(如卤素、醛、酮和酯等)会因脱卤和过度加氢造成产物的选择性下降, 其原因可能是-C-X和-C=C双键比-NO₂基团具有更高反应活性以及它们在催化剂表面的不同吸附强度和构型. 因此, 含竞争官能团的硝基芳烃定向转化从根本上取决于高选择性加氢催化剂的合理设计与制备. 为实现含有可还原性基团的硝基芳烃高选择性加氢, 研究人员开发了多种方法来构建Pd、Pt基非均相催化剂, 如有机分子修饰金属表面、产生载体氧空位、降低金属颗粒组装体尺寸、构筑核壳结构复合材料以及与第二种金属形成合金/金属间化合物.
本文采用一种简便可放大的热还原策略合成具有高选择性和稳定的表面应变铂基纳米催化剂(Pt NPs). 通过溶剂热法制备Pt/OCNTs预催化剂, 然后在H₂气氛下对其进行高温处理获得目标催化剂. 在该过程中, Pt NPs尺寸稍微增加且被迁移的碳原子覆盖, 碳原子源自CNTs载体. Pt NPs外围保护性碳层可有效抑制其聚集和浸出, 有望提高催化剂的选择性和稳定性. 结合球差校正透射电子显微镜、X-射线吸收精细结构谱和X-射线光电子能谱分析, 在退火过程中发现Pt NPs和CNTs载体之间存在较强的金属-载体相互作用(SMSI), 进一步升温后Pt NPs表面的部分碳涂层被蚀刻成碳原子, 并在Pt NPs表面诱导产生压缩应变. 因此, Pt/OCNTs催化剂的热还原处理成功地诱导了Pt NPs和CNTs载体之间的SMSI效应以及Pt NPs的压缩应变. 将制备的催化剂用于硝基芳烃底物的选择性加氢, 结果表明, 表面应变的Pt/CNTs-800H(在氢气气氛中, 800 ^oC热处理)催化剂对苯乙烯和硝基苯混合物及4-硝基苯乙烯加氢的化学选择性几乎完全反转, 说明CNTs惰性载体在将Pt NPs从非选择性催化剂转化为对4-硝基苯乙烯高选择性加氢催化剂中起到关键作用. 硝基芳烃加氢反应结果表明, 经高温H₂处理后的Pt/CNTs-800H催化剂的加氢选择性显著提高且对4-溴硝基苯加氢具有较好的循环稳定性. 同时, 该策略也适用于5 wt% Pt/C和Pt/rGO催化剂, 证明本文处理方法在碳基催化材料中的良好普适性. 综上, 本文不仅发现Pt NPs和CNTs之间存在SMSI效应, 而且为制备具有压缩应变的Pt NPs提供了一种新途径, 为解决Pt基非均相催化剂选择性差和稳定性低等问题提供一定参考.

关键词: 铂基纳米催化剂, 热还原处理, 金属载体强相互作用, 压缩应变, 选择性加氢

Abstract:

Supported Pt nanoparticles (NPs) are highly active catalysts for heterogeneous catalytic hydrogenation reactions; however, controlling their selectivity remains the biggest challenge toward their applicability. Herein, we propose the formation of a highly selective and stable, surface-strained Pt-based nanocatalyst via a facile and scalable thermal reduction treatment. Spherical-aberration-corrected transmission electron microscopy (SACTEM) and various spectral analytic techniques reveal a strong metal-support interaction between the Pt NPs and carbon nanotubes (CNTs) support during the annealing process. Thereafter, a fraction of carbon atoms is etched from the carbon-coated Pt NPs, inducing a compressive strain on the surface of the Pt NPs. Notably, the chemoselectivity of the surface-strained Pt/CNTs-800H catalyst (where 800 represents the heat-treatment temperature; H represents a hydrogen atmosphere) is almost completely different compared to that of its pristine counterpart. This catalyst is used for the hydrogenation reactions of a styrene and nitrobenzene mixture as well as 4-nitrostyrene. Interestingly, similar findings were observed with 5 wt% Pt/C and Pt/rGO catalysts, confirming that this treatment could be generalized. Hence, it has great potential in the design and synthesis of carbon-based catalytic materials.

Key words: Pt-based nanocatalyst, Thermal reduction treatment, Strong metal-support interaction, Compressive strain, Selective hydrogenation

张锋伟, 郭河芳, 刘萌萌, 赵阳, 洪峰, 李静静, 董正平, 乔波涛. 表面应力介导的碳基Pt纳米催化剂用于硝基芳烃的高选择性加氢[J]. 催化学报, 2023, 48: 195-204.

Fengwei Zhang, Hefang Guo, Mengmeng Liu, Yang Zhao, Feng Hong, Jingjing Li, Zhengping Dong, Botao Qiao. Enhancing the chemoselective hydrogenation of nitroarenes: Designing a novel surface-strained carbon-based Pt nanocatalyst[J]. Chinese Journal of Catalysis, 2023, 48: 195-204.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(23)64424-9

https://www.cjcatal.com/CN/Y2023/V48/I5/195

图/表 7

Scheme 1. Schematic diagram of the preparation of a compressive-strained Pt/CNTs-800H catalyst.

Fig. 1. TEM and HRTEM images of Pt/OCNTs (a,b) and Pt/CNTs-800H (c,d). (e) HAADF-STEM and the corresponding elemental mapping images. (f) SACTEM image of the Pt/CNTs-800H catalyst.

Fig. 2. XRD patterns (a) and XANES spectra (b) at the Pt K-edge of the Pt foil, Pt/C, and Pt/CNTs-800H. (c) Fourier-transform (FT) k3-weighted χ (k)-function of the EXAFS spectra for the Pt K-edge. Raman spectra (d) and N2 adsorption-desorption isotherms (e) of Pt-based catalysts prepared at different heat treatment temperatures. (f) In-situ DRIFT spectra of CO adsorption on Pt/OCNTs and Pt/CNTs-800H obtained at room temperature.

Fig. 3. HRTEM images (a-d) and high-resolution XPS analysis (e-h) in the Pt 4f region of the as-prepared Pt/CNTs-TH (from left to right: T = 200, 400, 600, and 800 °C, respectively).

Fig. 4. Reaction kinetics for the hydrogenation of the nitrobenzene and styrene mixture in the presence of Pt/CNTs-TH (T = 200 °C (a), 400 °C (b), 600 °C (c), and 800 °C (d)). Reaction conditions: 0.25 mmol styrene, 0.25 mmol nitrobenzene, 10 mg Pt-based catalyst, 40 °C, 0.1-0.3 MPa H2, and 5 mL EtOH.

Table 1 Selective hydrogenation of 4-nitrostyrene with different catalysts. a

Entry	Catalyst	P (MPa)	t (h)	Conv.^b (%)	Sel.^b (%)
1	Pt/OCNTs	0.1	1	>99	12.1
2	Pt/CNTs-200H	0.1	1	>99	27.3
3	Pt/CNTs-400H	0.1	1.5	>99	55.7
4	Pt/CNTs-600H	0.1	4	>99	60.8
5	Pt/CNTs-800H	0.3	8	91.4	89.2
6^c	Pt/CNTs-800H	0.1	7	94.8	81.1
7^d	Pt/CNTs-800Ar	0.3	24	76.5	69.5
8	5 wt% Pt/C	0.1	0.5	>99	—
9	5 wt% Pt/C-800H	0.1	1	>99	61.7
10	Pt/rGO	0.1	1	>99	1.5
11	Pt/rGO-800H	0.3	12	97.3	68.2

Table 2 Selective hydrogenation of a variety of nitroarenes with Pt/CNTs-800H. a

Entry	Time (h)	Conv. (%)^a	Sel. (%)^b
1	8	97.1	>99
2	6	98.2	>99
3 ^c	4	>99	>99
4 ^c	4	>99	>99
5	3	>99	>99
6	6	96.3	>99
7	8	92.5	>99
8	12	91.0	>99
9	12	>99	>99
10 ^c	8	91.4	89.2

参考文献

[1]	L. Zhang, M. Zhou, A. Wang, T. Zhang, Chem. Rev., 2020, 120, 683-733.
[2]	K. Liu, R. Qin, N. Zheng, J. Am. Chem. Soc., 2021, 143, 4483-4499.
[3]	Y. Kang, H. Du, B. Jiang, H. Li, Y. Guo, M. A. Amin, Y. Sugahara, T. Asahi, H. Li, Y. Yamauchi, J. Mater. Chem. A, 2022, 10, 6560-6568.
[4]	D. Zhou, L. Zhang, W. Liu, G. Xu, J. Yang, Q. Jiang, A. Wang, J. Yin, Chin. J. Catal., 2021, 42, 1617-1624.
[5]	J. Song, Z. F. Huang, L. Pan, K. Li, X. Zhang, L. Wang, J. J. Zou, Appl. Catal. B, 2018, 227, 386-408.
[6]	S. Iihama, S. Furukawa, T. Komatsu, ACS Catal., 2015, 6, 742-746.
[7]	H. Wei, X. Liu, A. Wang, L. Zhang, B. Qiao, X. Yang, Y. Huang, S. Miao, J. Liu, T. Zhang, Nat. Commun., 2014, 5, 5634.
[8]	Y. Peng, Z. Geng, S. Zhao, L. Wang, H. Li, X. Wang, X. Zheng, J. Zhu, Z. Li, R. Si, J. Zeng, Nano Lett., 2018, 18, 3785-3791.
[9]	P. Serna, A. Corma, ACS Catal., 2015, 5, 7114-7121.
[10]	Y. Pei, Z. Qi, T.W. Goh, L. L. Wang, R. V. Maligal-Ganesh, H. L. MacMurdo, S. Zhang, C. Xiao, X. Li, F. Tao, D. D. Johnson, W. Huang, J. Catal., 2017, 356, 307-314.
[11]	Q. Wu, B. Zhang, C. Zhang, X. Meng, X. Su, S. Jiang, R. Shi, Y. Li, W. Lin, M. Arai, H. Cheng, F. Zhao, J. Catal., 2018, 364, 297-307.
[12]	Y. Kang, Y. Tang, L. Zhu, B. Jiang, X. Xu, O. Guselnikova, H. Li, T. Asahi, Y. Yamauchi, ACS Catal., 2022, 12, 14773-14793.
[13]	Y. Wang, R. Qin, Y. Wang, J. Ren, W. Zhou, L. Li, J. Ming, W. Zhang, G. Fu, N. Zheng, Angew. Chem. Int. Ed., 2020, 59, 12736-12740.
[14]	Z. Qi, C. Xiao, C. Liu, T. W. Goh, L. Zhou, R. Maligal-Ganesh, Y. Pei, X. Li, L.A. Curtiss, W. Huang, J. Am. Chem. Soc., 2017, 139, 4762-4768.
[15]	M. Makosch, W. I. Lin, V. Bumbalek, J. Sa, J. W. Medlin, K. Hungerbühler, J. A. V. Bokhoven, ACS Catal., 2012, 2, 2079-2081.
[16]	M. Hu, S. Zhao, S. Liu, C. Chen, W. Chen, W. Zhu, C. Liang, W. C. Cheong, Y. Wang, Y. Yu, Q. Peng, K. Zhou, J. Li, Y. Li, Adv. Mater., 2018, 30, 1801878.
[17]	W. A. Farooq. Y. Bando, T. Asahi, B. Jiang, H. Li, Y. Yamauchi, Small, 2020, 16, 1906707.
[18]	C. Gu, C. Liang, X. Qin, Y.-J. Gu, P. Gao, M. Shao, W.-T. Wong, ACS Appl. Nano Mater., 2020, 3, 7242-7251.
[19]	C. Riley, S. Zhou, D. Kunwar, A. De La Riva, E. Peterson, R. Payne, L. Gao, S. Lin, H. Guo, A. Datye, J. Am. Chem. Soc., 2018, 140, 12964-12973.
[20]	T. W. V. Deelen, C. H. Mejia, K. P. D. Jong, Nat. Catal., 2019, 2, 955-970.
[21]	E. Vignola, S. N. Steinmann, A. Al Farra, B. D. Vandegehuchte, D. Curulla, P. Sautet, ACS Catal., 2018, 8, 1662-1671.
[22]	J. Gu, Z. Zhang, P. Hu, L. Ding, N. Xue, L. Peng, X. Guo, M. Lin, W. Ding, ACS Catal., 2015, 5, 6893-6901.
[23]	S. J. Tauster, S. C. Fung, R. L. Garten, J. Am. Chem. Soc., 1978, 100, 170-175.
[24]	F. Hong, S. Wang, J. Zhang, J. Fu, Q. Jiang, K. Sun, J. Huang, Chin. J. Catal., 2021, 42, 1530-1537.
[25]	J. Humphreys, R. Lan, S. Chen, S. Tao, J. Mater. Chem. A, 2020, 8, 16676-16689.
[26]	A. Corma, P. Serna, P. Concepción, J. J. Calvino, J. Am. Chem. Soc., 2008, 130, 8748-8753.
[27]	L. Liu, A. Corma, Chem. Rev., 2018, 118, 4981-5079.
[28]	J. Dong, Q. Fu, H. Li, J. Xiao, B. Yang, B. Zhang, Y. Bai, T. Song, R. Zhang, L. Gao, J. Cai, H. Zhang, Z. Liu, X. Bao, J. Am. Chem. Soc., 2020, 142, 17167-17174.
[29]	H. Tang, J. Wei, F. Liu, B. Qiao, X. Pan, L. Li, J. Liu, J. Wang, T. Zhang, J. Am. Chem. Soc., 2016, 138, 56-59.
[30]	C. W. A. Chan, A. H. Mahadi, M. M. J. Li, E. C. Corbos, C. Tang, G. Jones, W. C. H. Kuo, J. Cookson, C. M. Brown, P.T. Bishop, S. C. E. Tsang, Nat. Commun., 2014, 5, 5787.
[31]	H. Chen, S. Z. Yang, Z. Yang, W. Lin, H. Xu, Q. Wan, X. Suo, T. Wang, D. E. Jiang, J. Fu, S. Dai, ACS Cent. Sci., 2020, 6, 1617-1627.
[32]	Y. Sun, X. Li, J. Wang, W. Ning, J. Fu, X. Lu, Z. Hou, Appl. Catal. B, 2017, 218, 538-544.
[33]	W. Z. Li, L. Kovarik, D. Mei, J. Liu, Y. Wang, C. H. F. Peden, Nat. Commun., 2013, 4, 2481.
[34]	G. He, Y. Song, K. Liu, A. Walter, S. Chen, S. Chen,, ACS Catal., 2013, 3, 831-838.
[35]	Z. Ye, Y. Wang, S. Liu, D. Xu, W. Wang, X. Ma, J. Am. Chem. Soc., 2021, 143, 15063-15072.
[36]	B. You, M. T. Tang, C. Tsai, F. Abild-Pedersen, X. Zheng, H. Li, Adv. Mater., 2019, 31, 1807001.
[37]	M. Luo, S. Guo, Nat. Rev. Mater., 2017, 2, 17059.
[38]	X. Yang, Y. Wang, X. Tong, N. Yang, Adv. Energy Mater., 2022, 12, 2102261.
[39]	M. Xie, Z. Lyu, R. Chen, M. Shen, Z. Cao, Y. Xia, J. Am. Chem. Soc., 2021, 143, 8509-8518.
[40]	F. Giacalone, V. Campisciano, C. Calabrese, V. La Parola, Z. Syrgiannis, M. Prato, M. Gruttadauria, ACS Nano, 2016, 10, 4627-4636.
[41]	Y. Qian, S. Jiang, Y. Li, Z. Yi, J. Zhou, J. Tian, N. Lin, Y. Qian,, Angew. Chem. Int. Ed., 2019, 58, 18108-18115.
[42]	T. He, W. Wang, F. Shi, X. Yang, X. Li, J. Wu, Y. Yin, M. Jin, Nature, 2021, 598,76-81.
[43]	H. Wang, S. Xu, C. Tsai, Y. Li, C. Liu, J. Zhao, Y. Liu, H. Yuan, F. Abild-Pedersen, F. B. Prinz, J. K. Norskov, Y. Cui, Science, 2016, 354, 1031-1036.
[44]	C. Jackson, G. T. Smith, D. W. Inwood, A. S. Leach, P. S. Whalley, M. Callisti, T. Polcar, A. E. Russell, P. Levecque, D. Kramer, Nat. Commun., 2017, 8, 15802.
[45]	F. Jiang, C. Li, H. Fu, X. Guo, G. Wu, S. Chen, Phys. Chem. Chem. Phys., 2016, 18, 19259-19266.
[46]	J. Wang, Z. Huang, W. Liu, C. Chang, H. Tang, Z. Li, W. Chen, C. Jia, T. Yao, S. Wei, Y. Wu, Y. Li, J. Am. Chem. Soc., 2017, 139, 17281-17284.
[47]	E. Picheau, A. Impellizzeri, D. Rybkovskiy, M. Bayle, J. Y. Mevellec, F. Hof, H. Saadaoui, L. Noe, A. C. Torres Dias, J. L. Duvail, M. Monthioux, B. Humbert, P. Puech, C. P. Ewels, A. Penicaud, ACS Nano, 2021, 15, 596-603.
[48]	L. Shao, B. Zhang, W. Zhang, S. Y. Hong, R. Schlögl, D. S. Su, Angew. Chem. Int. Ed., 2013, 52, 2114-2117.
[49]	Y. Kim, J. H. Jang, J. Min, A. A. Jeffery, S. Lee, S. S. Chougule, M. Kim, N. Jung, S. J. Yoo, J. Mater. Chem. A, 2021, 9, 24480-24487.
[50]	Z. Zhang, Y. Zhu, H. Asakura, B. Zhang, J. Zhang, M. Zhou, Y. Han, T. Tanaka, A. Wang, T. Zhang, N. Yan, Nat. Commun., 2017, 8, 16100.
[51]	J. Zhang, D. Zhu, J. Yan, C. A. Wang, Nat. Commun., 2021, 12, 6665.
[52]	H. Tang, Y. Su, B. Zhang, F. Lee Adam, A. Isaacs Mark, K. Wilson, L. Li, Y. Ren, J. Huang, M. Haruta, B. Qiao, X. Liu, C. Jin, D. Su, J. Wang, T. Zhang, Sci. Adv., 2017, 3, 1700231.
[53]	J. Sun, Y. Nam, N. Lindvall, M. T. Cole, K. B. K. Teo, Y. Woo Park, A. Yurgens, Appl. Phys. Lett., 2014, 104, 152107.
[54]	Y. Zhang, Z. Li, P. Kim, L. Zhang, C. Zhou, ACS Nano, 2012, 6, 126-132.
[55]	G. F. Long, X. H. Li, K. Wan, Z. X. Liang, J. H. Piao, P. Tsiakaras, Appl. Catal. B, 2017, 203, 541-548.
[56]	M. Makosch, W. I. Lin, V. Bumbalek, J. Sa, J. W. Medlin, K. Hungerbühler, J. A. van Bokhoven, ACS Catal., 2012, 2, 2079-2081.

表面应力介导的碳基Pt纳米催化剂用于硝基芳烃的高选择性加氢

Enhancing the chemoselective hydrogenation of nitroarenes: Designing a novel surface-strained carbon-based Pt nanocatalyst

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 7

参考文献

相关文章 15

编辑推荐

Metrics

[1]	刘诗瑶, 巩玉同, 杨晓, 张楠楠, 刘会斌, 梁长海, 陈霄. 具有富电子镍位点的耐酸金属间化合物CaNi₂Si₂催化剂用于不饱和有机酸酐/酸的水相加氢[J]. 催化学报, 2023, 50(7): 260-272.
[2]	聂超, 龙向东, 刘琪, 王嘉, 展飞, 赵泽伦, 李炯, 席永杰, 李福伟. 原子分散Ru-P-Ru催化剂的制备及其在多类加氢中的高效应用[J]. 催化学报, 2023, 45(2): 107-119.
[3]	王梦茹, 王奕, 牟效玲, 林荣和, 丁云杰. 1,3-丁二烯选择性加氢催化剂的设计策略以及构效关系[J]. 催化学报, 2022, 43(4): 1017-1041.
[4]	周丹, 张磊磊, 刘文刚, 徐刚, 杨级, 蒋齐可, 王爱琴, 银建中. 压缩CO₂中Co-N-C催化3-硝基苯乙烯选择性加氢反应动力学及相行为[J]. 催化学报, 2021, 42(9): 1617-1624.
[5]	洪峰, 王升扬, 张军营, 付俊红, 蒋齐可, 孙科举, 黄家辉. 金属载体强相互作用增强Au/TiO₂催化剂在3-硝基苯乙烯选择性加氢反应的活性[J]. 催化学报, 2021, 42(9): 1530-1537.
[6]	胡念, 李小云, 刘思明, 王朝, 何小可, 侯月新, 王宇翔, 邓兆, 陈丽华, 苏宝连. 超高稳定性的等级孔碳负载高分散铜基选择性加氢催化剂[J]. 催化学报, 2020, 41(7): 1081-1090.
[7]	连菊红, 柴玉超, 祁育, 郭向阳, 关乃佳, 李兰冬, 章福祥. 铂负载二氧化钛光催化剂在单波长下苯乙炔高选择性加氢[J]. 催化学报, 2020, 41(4): 598-603.
[8]	魏中哲, 邵方君, 王建国. 氮杂环化合物的多相催化加氢反应及其可逆脱氢反应的最新进展[J]. 催化学报, 2019, 40(7): 980-1002.
[9]	陈宇卓, 王哲, 毛善俊, 王勇. 基于氮掺杂多孔炭的加氢催化剂的理性设计[J]. 催化学报, 2019, 40(7): 971-979.
[10]	陈宇卓, 孔祥千, 毛善俊, 王哲, 巩玉同, 王勇. 碱性钠添加剂在苯酚选择性加氢中的作用[J]. 催化学报, 2019, 40(10): 1516-1524.
[11]	林伟伟, 程海洋, 李小汝, 张弨, 赵凤玉, 荒井正彦. 类水滑石Mg₃Al_1-xFe_x负载Ir催化剂在肉桂醛加氢反应中的应用:Fe的促进作用[J]. 催化学报, 2018, 39(5): 988-996.
[12]	马宏飞, 于铁, 潘秀莲, 包信和. 碳纳米管限域效应对肉桂醛选择加氢产物分布的影响[J]. 催化学报, 2017, 38(8): 1315-1321.
[13]	陈志俊, 王艳华, 李文江, 蒋景阳, 金子林. 温控相转移纳米铑催化邻氯硝基苯选择性加氢反应[J]. 催化学报, 2014, 35(12): 1917-1920.
[14]	王铭浩, 苏宏久, 周谨, 王树东. 用于苯选择加氢的Ru/Al₂O₃-ZrO₂-NiO/堇青石蜂窝整体催化剂[J]. 催化学报, 2013, 34(8): 1543-1550.
[15]	牛明铭, 王艳华, 李文江, 蒋景阳, 金子林. 温控聚乙二醇两相体系中纳米钯催化肉桂醛选择性加氢反应[J]. 催化学报, 2013, 34(4): 674-678.