共价有机框架中不对称的N-Ru-S偶极子增强内建电场以实现高效的CO2光还原

doi:10.1016/S1872-2067(26)65082-6

催化学报 ›› 2026, Vol. 87: 59-69.DOI: 10.1016/S1872-2067(26)65082-6

共价有机框架中不对称的N-Ru-S偶极子增强内建电场以实现高效的CO₂光还原

陈月铃^a^,^b, 林玉玲^b, 陈紫妍^b, 孔祥昱^b, 毕进红^a^,^b^,^*(), 黄国城^b^,^*(), 吴棱^a

^a 福州大学化学学院, 能源与环境光催化国家重点实验室, 福建闽侯 350108
^b 福州大学环境科学与工程系, 福建闽侯 350108

收稿日期:2025-10-27 接受日期:2025-12-03 出版日期:2026-08-18 发布日期:2026-06-24
通讯作者: ^*电子信箱: bijinhong@fzu.edu.cn (毕进红),
huanggch@fzu.edu.cn (黄国城).
基金资助:
国家自然科学基金(22206026);国家自然科学基金(22272028);福建省雏鹰计划青年拔尖人才项目(00387077);福建省科技厅高校产学合作项目(2023H6005)

Asymmetric N-Ru-S dipole within covalent organic framework enhances internal electric field for efficient CO₂ photoreduction

Yueling Chen^a^,^b, Yuling Lin^b, Ziyan Chen^b, Xiangyu Kong^b, Jinhong Bi^a^,^b^,^*(), Guocheng Huang^b^,^*(), Ling Wu^a

^a State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Minhou 350108, Fujian, China
^b Department of Environmental Science and Engineering, Fuzhou University, Minhou 350108, Fujian, China

Received:2025-10-27 Accepted:2025-12-03 Online:2026-08-18 Published:2026-06-24
Supported by:
National Natural Science Foundation of China(22206026);National Natural Science Foundation of China(22272028);Youth Talent Support Program of Fujian Province(00387077);Industry-University Research Collaboration Project of Fujian Province(2023H6005)

摘要/Abstract

摘要：

化石燃料的过度消耗及伴随的过量CO₂排放已成为全球可持续发展面临的两大严峻挑战, 同时引发能源短缺与温室效应加剧. 太阳能驱动的光催化CO₂还原反应(CO₂RR)能够在温和条件下将CO₂转化为高能量密度燃料或高附加值化学品, 被视为助力碳循环并提供绿色能源的变革性途径. 然而, 该技术的实际应用仍受限于以下瓶颈: (1)催化剂表面CO₂活化的高能垒阻碍了*COOH等关键中间体的形成; (2)光生载流子的快速复合显著降低了光生电子的利用效率. 这些因素共同导致现有光催化体系的活性和选择性不足. 因此, 设计高效光催化剂被认为是推动CO₂RR发展的核心课题.

与传统均相及多相催化剂相比, 单原子催化剂因其原子利用率最大化、不饱和配位环境独特及电子结构可调等优势, 在CO₂RR及其他催化反应中展现出优异的活性. 其中, 钌(Ru)单原子在驱动CO₂选择性还原为CO方面表现出显著潜力. 这种高选择性主要源于其适宜的电子构型, 尤其是Ru位点优化的d带中心, 能够精准调控关键反应中间体的吸附强度, 从而促进CO₂活化, 并实现CO产物的高效脱附. 值得注意的是, 单原子d带中心的调控与其局部配位环境密切相关. 构建具有非均匀电荷分布的不对称配位结构, 可有效调节d带中心, 进而优化反应中间体的吸附能, 加速整体反应动力学. 通过引入电负性不同的杂原子(如N, S)调控金属中心的化学微环境, 已成为优化电子结构、提升光催化CO₂还原性能的有效策略. 本文在噻吩功能化的共价有机框架(COFs)中精准构筑了不对称N-Ru-S配位结构(Ru/Py-bTDC), 用于在无牺牲剂、无光敏剂的气固条件下高效光催化还原CO₂. 同步辐射光谱结合高角环形暗场扫描透射电子显微镜证实, Ru物种通过不对称的N-Ru-S配位在Py-bTDC骨架中实现原子级分散. 优化后的Ru₁₀/Py-bTDC催化剂在可见光照射下表现出显著增强的CO生成性能(226.88 μmol·L^-1), CO生成速率较原始Py-bTDC催化剂提升了13倍. 光电化学分析和原位开尔文探针力显微镜证实, Ru₁₀/Py-bTDC催化剂的内建电场(IEF)较原始Py-bTDC催化剂增强了6.15倍, 并且接触电势差从23增至70 mV, 其最大表面光电压达到350 mV, 这直接揭示了N-Ru-S基序作为定向纳米偶极子驱动光生电子向Ru位点移动的作用机制. 随后, 通过原位傅里叶变换红外光谱实时追踪了关键反应中间体的演变过程. 理论计算结果表明, 与原始Py-bTDC催化剂相比, Ru中心的局域电子富集有效激活了CO₂分子, 具体表现为O=C=O键角显著减小40.4°, 同时C=O键长分别从1.17 Å延长至1.21和1.31 Å. 这种电荷再分配将*COOH的形成能垒从2.63降到0.40 eV, 并将速率决定步骤从*CO₂质子化转变为*CO解吸(ΔG = 2.20 eV).

综上, 本工作将原子尺度的对称性破缺与宏观的IEF增强和反应动力学优化联系起来, 提出了COFs中工程不对称配位的设计策略, 同时解决电荷分离和CO₂激活障碍问题, 从而推进太阳能燃料转换系统.

关键词: 不对称电子分布, 共价有机骨架, 单原子催化剂, 内建电场, CO₂光还原

Abstract:

Asymmetric electron distribution at single-atom centers offers a promising pathway to enhance photocatalytic CO₂-to-CO conversion; however, direct visualization of how such symmetry-breaking influences local electric fields and reaction coordinates remains elusive. Herein, an asymmetric N-Ru-S motif was constructed in a thiophene-based covalent organic framework (Ru/Py-bTDC) via post-synthetic metalation. Under visible light in a gas-solid system without sacrificial agents, Ru₁₀/Py-bTDC exhibited a CO production of 226.88 μmol·L^-1, representing a 13-fold increase over pristine Py-bTDC. In-situ Kelvin probe force microscopy revealed that the N-Ru-S unit acts as a directional nanoscale dipole, intensifying the internal electric field (IEF) by 6.15-fold and steering photogenerated electrons toward Ru sites to facilitate charge separation. In-situ Fourier transform infrared spectroscopy and theoretical calculations demonstrated that the enhanced IEF promotes CO₂ activation, lowering the energy barrier for *COOH formation from 2.63 to 0.40 eV and shifting the rate-determining step to *CO desorption. This work establishes a direct spatial correlation between atomic-scale asymmetry, IEF enhancement, and optimized reaction kinetics, offering a design strategy to overcome both charge separation and activation barriers in CO₂ photoreduction through symmetry-breaking coordination.

Key words: Asymmetric electron distribution, Covalent organic framework, Single-atom catalysts, Internal electric field, CO₂ photoreduction

陈月铃, 林玉玲, 陈紫妍, 孔祥昱, 毕进红, 黄国城, 吴棱. 共价有机框架中不对称的N-Ru-S偶极子增强内建电场以实现高效的CO₂光还原[J]. 催化学报, 2026, 87: 59-69.

Yueling Chen, Yuling Lin, Ziyan Chen, Xiangyu Kong, Jinhong Bi, Guocheng Huang, Ling Wu. Asymmetric N-Ru-S dipole within covalent organic framework enhances internal electric field for efficient CO₂ photoreduction[J]. Chinese Journal of Catalysis, 2026, 87: 59-69.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(26)65082-6

https://www.cjcatal.com/CN/Y2026/V87/I8/59

图/表 5

Fig. 1. XRD patterns (a) and FTIR spectra (b) of Py-bTDC and Rux/Py-bTDC samples. SEM (c), TEM (d), HAADF-STEM (e) images and elemental distribution (f) of Ru10/Py-bTDC.

Fig. 2. High resolution N 1s (a) and S 2p (b) XPS spectrum of Py-bTDC and Ru10/Py-bTDC. The XANES spectra (c) and the Fourier transform of the corresponding EXAFS spectra (d) of Ru10/Py-bTDC, Ru-Foil, RuO2, and Ru2O3 on the K-edge of Ru. (e) The EXAFS fitting curve of Ru10/Py-bTDC. Wavelet transform diagrams of Ru-foil (f), Ru2O3 (g) and Ru10/Py-bTDC (h). (i) Schematic model of Ru10/Py-bTDC.

Fig. 3. (a) UV-vis DRS spectra of Py-bTDC and Ru10/Py-bTDC. Transient photocurrent curves (b) and EIS plots (c) of Py-bTDC and Rux/Py-bTDC. TRPL spectra (d) and KPFM images of Ru10/Py-bTDC under dark (e) and light (f). Surface potentials under dark conditions (g), surface charge densities (h), and the intensity of the IEF (i) of Py-bTDC and Ru10/Py-bTDC.

Fig. 4. (a) CO2 adsorption profiles of Ru10/Py-bTDC at 273 and 298 K. (b) CO2-TPD spectra of Ru10/Py-bTDC. (c) LSV curves of Py-bTDC and Ru10/Py-bTDC. (d) CO2 photoreduction performance of Py-bTDC and Rux/Py-bTDC (All experiments were conducted in triplicate). Control experiments (e) and isotope experiment (f) for photocatalytic CO2 reduction over Ru10/Py-bTDC.

Fig. 5. (a) In-situ FTIR spectra of photocatalytic reduction of CO2 on Ru10/Py-bTDC. Adsorption energies (b), charge density difference and bader charge change results (c) for CO2 adsorption on Py-bTDC and Ru10/Py-bTDC. (d) Gibbs free energy changes during CO2 reduction to CO on Py-bTDC and Ru10/Py-bTDC.

参考文献

[1]	A. M. Sadanandan, J. H. Yang, V. Devtade, G. Singh, N. Panangattu Dharmarajan, M. Fawaz, J. Mee Lee, E. Tavakkoli, C. H. Jeon, P. Kumar, A. Vinu, Prog. Mater. Sci., 2024, 142, 101242.
[2]	M. Bonchio, J. Bonin, O. Ishitani, T. B. Lu, T. Morikawa, A. J. Morris, E. Reisner, D. Sarkar, F. M. Toma, M. Robert, Nat. Catal., 2023, 6, 657-665.
[3]	J. Lv, H. Chu, C. Shao, L. Sun, G. Dawson, K. Dai, Chin. J. Catal., 2025, 78, 75-99.
[4]	Y. Liu, C. Chen, G. Dawson, J. Zhang, C. Shao, K. Dai, J. Mater. Sci. Technol., 2025, 233, 10-37.
[5]	R. Bhimpuria, M. Tomar, A. Thapper, M. Ahlquist, K. E. Borbas, Chem, 2025, 11, 102450.
[6]	Z. Zhang, Y. Xia, C. Shao, L. Sun, G. Dawson, K. Dai, J. Mater. Sci. Technol., 2026, 252, 1-33.
[7]	C. Li, J. He, T. Cai, X. Chen, H. Tao, Y. Zhou, M. Zhu, Chin. J. Catal., 2025, 74, 130-143.
[8]	E. Nikoloudakis, I. López-Duarte, G. Charalambidis, K. Ladomenou, M. Ince, A. G. Coutsolelos, Chem. Soc. Rev., 2022, 51, 6965-7045.
[9]	T. Kong, Y. Jiang, Y. Xiong, Chem. Soc. Rev., 2020, 49, 6579-6591.
[10]	X. Wu, M. Sayed, G. Wang, W. Yu, B. Zhu, Adv. Mater., 2026, 38, e11322.
[11]	F. Cao, G. Liu, X. Wang, L. Tan, N. Tsubaki, EnergyChem, 2024, 6, 100141.
[12]	Y. H. Li, Y. Chen, J. Y. Guo, R. Wang, S. N. Zhao, G. Li, S. Q. Zang, Chin. J. Catal., 2025, 74, 155-166.
[13]	S. Wang, X. T. Min, B. Qiao, N. Yan, T. Zhang, Chin. J. Catal., 2023, 52, 1-13.
[14]	Z. Liu, J. Ma, Y. Guo, M. Hong, R. Sun, Appl. Catal. B, 2024, 342, 123429.
[15]	X. Li, M. Wang, R. Wang, Y. Wang, M. Zhu, L. Zhang, J. Shi, ACS Nano, 2024, 18, 5741-5751.
[16]	H. Ma, X. Zheng, H. Zhang, G. Ma, W. Zhang, Z. Jiang, D. Chen, Adv. Sci., 2023, 10, 2205635.
[17]	G. Jia, Y. Zhang, J. C. Yu, Z. Guo, Adv. Mater., 2024, 36, 2403153.
[18]	M. Ahmed, M. Tabish, M. Mubeen, A. Kumar, S. Ajmal, A. Abbas, M. M. Alam, M. Arif, A. G. Al-Sehemi, G. Yasin, Coord. Chem. Rev., 2026, 547, 217105.
[19]	Y. Q. Su, Y. Wang, J. X. Liu, I. A. W. Filot, K. Alexopoulos, L. Zhang, V. Muravev, B. Zijlstra, D. G. Vlachos, E. J. M. Hensen, ACS Catal., 2019, 9, 3289-3297.
[20]	S. Mohata, P. Majumder, R. Banerjee, Chem. Soc. Rev., 2025, 54, 6062-6087.
[21]	Z. Xue, B. Zhang, Q. Guo, Y. Wang, Q. Li, K. Yang, S. Qiao, Adv. Mater., 2025, 37, e10201.
[22]	L. Zhang, H. Zhang, J. Fang, J. Cui, J. Liu, H. Liu, L. Sun, Q. Sun, L. Dong, Y. Zhao, Chin. J. Catal., 2025, 74, 144-154.
[23]	D. Wu, H. Wang, Y. Nie, H. Wan, S. Liu, S. Yang, H. Li, H. Zhang, C. Zhu, T. Ma, Prog. Mater. Sci., 2026, 155, 101538.
[24]	L. Zhou, X. Jia, Y. Wang, K. Xiong, J. Yang, Y. Kong, M. Guo, X. Xu, S. Li, X. Ren, C. Cheng, Mater. Sci. Eng. R Rep., 2026, 167, 101117.
[25]	S. Li, Y. Liu, L. Li, C. Liu, J. Li, S. Ashraf, P. Li, B. Wang, ACS Appl. Mater. Interfaces, 2020, 12, 22910-22916.
[26]	Z. Gu, Z. Shan, Y. Wang, J. Wang, T. Liu, X. Li, Z. Yu, J. Su, G. Zhang, Chin. Chem. Lett., 2024, 35, 108356.
[27]	S. Y. Jiang, Z. B. Zhou, S. X. Gan, Y. Lu, C. Liu, Q. Y. Qi, J. Yao, X. Zhao, Nat. Commun., 2024, 15, 698.
[28]	C. Li, D. Li, W. Zhang, H. Li, G. Yu, Angew. Chem. Int. Ed., 2021, 60, 27135-27143.
[29]	L. Wang, L. Wang, Y. Xu, G. Sun, W. Nie, L. Liu, D. Kong, Y. Pan, Y. Zhang, H. Wang, Y. Huang, Z. Liu, H. Ren, T. Wei, Y. Himeda, Z. Fan, Adv. Mater., 2024, 36, 2309376.
[30]	H. Jia, N. Yao, Y. Jin, L. Wu, J. Zhu, W. Luo, Nat. Commun., 2024, 15, 5419.
[31]	C. Yang, J. Yue, G. Wang, W. Luo, Angew. Chem. Int. Ed., 2024, 63, e202401453.
[32]	H. Xu, G. Xin, W. Hu, Z. Zhang, C. Si, J. Chen, L. Lu, Y. Peng, X. Li, Appl. Catal. B, 2023, 339, 123157.
[33]	J. Qiu, Q. Chen, C. Liu, Y. Chen, J. Wu, K. Jing, J. C. Yu, L. Wu, X. Fu, Appl. Catal. B, 2025, 366, 125034.
[34]	B. Wang, L. Li, T. Zhang, J. Wu, J. Zhang, ACS Catal., 2025, 15, 3085-3095.
[35]	Y. Fan, H. Xu, G. Gao, M. Wang, W. Huang, L. Ma, Y. Yao, Z. Qu, P. Xie, B. Dai, N. Yan, Nat. Commun., 2024, 15, 6035.
[36]	W. Li, X. Zheng, B. B. Xu, Y. Yang, Y. Zhang, L. Cai, Z. J. Wang, Y. F. Yao, B. Nan, L. Li, X. L. Wang, X. Feng, M. Antonietti, Z. Chen, Angew. Chem. Int. Ed., 2024, 63, e202320014.
[37]	E. Gong, S. Ali, C. B. Hiragond, H. S. Kim, N. S. Powar, D. Kim, H. Kim, S. I. In, Energy Environ. Sci., 2022, 15, 880-937.
[38]	K. Wang, T. Yang, G. Dawson, J. Zhang, C. Shao, K. Dai, Chem. Res. Chin. Univ., 2025, 41, 716-725.
[39]	W. Zhong, A. Meng, X. Cai, Y. Gan, J. Wang, Y. Su, Chin. J. Catal., 2025, 76, 108-119.
[40]	J. Chen, L. Lin, P. Lin, L. Xiao, L. Zhang, Y. Lu, W. Su, Chin. J. Struct. Chem., 2023, 42, 100010.
[41]	B. Zhang, H. Li, Y. Kang, K. Yang, H. Liu, Y. Zhao, S. Qiao, Adv. Funct. Mater., 2025, 35, 2416958.
[42]	L. Fang, L. W. Bai, D. Wu, H. T. Che, Y. Jiang, Y. Wang, H. Dong, F. M. Zhang, Chem. Eng. J., 2025, 510, 161820.
[43]	W. Zhong, A. Meng, Y. Su, H. Yu, P. Han, J. Yu, Angew. Chem. Int. Ed., 2025, 64, e202425038.
[44]	Z. Liu, Y. Bian, G. Dawson, J. Zhu, K. Dai, Chin. Chem. Lett., 2025, 36, 111272.
[45]	W. Zhong, J. Wang, A. Meng, B. He, P. Han, Y. Su, Chem. Eng. J., 2025, 519, 164921.
[46]	Y. He, P. Hu, J. Zhang, G. Liang, J. Yu, F. Xu, ACS Catal., 2024, 14, 1951-1961.
[47]	J. Wang, C. S. Cao, Y. Zhang, L. Zhu, Appl. Catal. B, 2023, 336, 122899.
[48]	Y. Chen, T. Liang, Y. Lin, W. Peng, Z. Chen, W. Lin, Y.-T. Sham, M. Pan, Q. Chen, G. Huang, J. Bi, J. Colloid Interface Sci., 2026, 701, 138770.
[49]	M. Yu, W. Chen, Q. Lin, L. Li, Z. Liu, J. Bi, Y. Yu, Angew. Chem. Int. Ed., 2024, 64, e202418422.
[50]	X. Zhou, E. Song, Z. Kuang, Z. Gao, H. Zhao, J. Liu, S. Sun, C.-Y. Mou, H. Chen, Chem. Eng. J., 2022, 430, 133035.
[51]	B. Su, Y. Kong, S. Wang, S. Zuo, W. Lin, Y. Fang, Y. Hou, G. Zhang, H. Zhang, X. Wang, J. Am. Chem. Soc., 2023, 145, 27415-27423.
[52]	H. Han, L. Tang, K. Wei, S. Zhang, X. Ma, C. Ma, S. Feng, Sep. Purif. Technol., 2025, 356, 129800.
[53]	Y. Wang, J. Hu, T. Ge, F. Chen, Y. Lu, R. Chen, H. Zhang, B. Ye, S. Wang, Y. Zhang, T. Ma, H. Huang, Adv. Mater., 2023, 35, 2302538.
[54]	J. Ning, J. Huang, Y. Liu, Y. Chen, Q. Niu, Q. Lin, Y. He, Z. Liu, Y. Yu, L. Li, Chin. J. Struct. Chem., 2024, 43, 100453.
[55]	H. Dong, L. Fang, K. X. Chen, J. X. Wei, J. X. Li, X. Qiao, Y. Wang, F. M. Zhang, Y. Q. Lan, Angew. Chem. Int. Ed., 2025, 64, e202414287.
[56]	H. Fu, J. Tian, Q. Zhang, Z. Zheng, H. Cheng, Y. Liu, B. Huang, P. Wang, Chin. J. Catal., 2024, 64, 143-151.
[57]	Y. Bian, H. He, G. Dawson, J. Zhang, K. Dai, Sci. China Mater., 2024, 67, 514-523.
[58]	A. Meng, P. Yang, D. Fu, W. Peng, W. Zhong, Y. Su, J. Colloid Interface Sci., 2025, 684, 148-157.
[59]	J. Liang, H. Zhang, Q. Song, Z. Liu, J. Xia, B. Yan, X. Meng, Z. Jiang, X. W. D. Lou, C. S. Lee, Adv. Mater., 2024, 36, 2303287.
[60]	Z. Liu, L. Mao, Z. Liu, M. Zhou, H. Wang, J. Li, R. Zhang, K. Nie, B. Yan, H. Zhang, Z. Jiang, S. Song, W. Shi, Angew. Chem. Int. Ed., 2026, 65, e22838.
[61]	Y. Wang, Z. Fan, Y. Wan, M. Xu, J. Li, Y. Ling, Y. Xie, K. Yang, X. Li, Appl. Catal. B, 2025, 366, 125017.
[62]	F. Xie, C. Bie, J. Sun, Z. Zhang, B. Zhu, J. Mater. Sci. Technol., 2024, 170, 87-94.

共价有机框架中不对称的N-Ru-S偶极子增强内建电场以实现高效的CO₂光还原

Asymmetric N-Ru-S dipole within covalent organic framework enhances internal electric field for efficient CO₂ photoreduction

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 5

参考文献

相关文章 15

编辑推荐

Metrics

[1]	姜晓康, 高永泽, 张博闻, 杨晓东, 袁之敏, 许兆宁, 孙彬, 姜在勇, 周国伟, 周恩龙. 内建电场耦合非贵金属等离基元效应助推MIL-125光催化二氧化碳还原活性[J]. 催化学报, 2026, 87(8): 100-112.
[2]	段江林, 邓鹏程, 熊惠峰, 杨娜, 周雪灵, 王静雯, 张瑞, 冯丹, 杨级, 覃勇, 任煜京. 亚埃尺度空间调控Fe₁-N₄配位结构实现高效C-H键氧化过程[J]. 催化学报, 2026, 87(8): 305-315.
[3]	李世杰, 李蕊, 刘艳萍, 于欣, 马德运, 姜建辉, 周小松, 庄春强, 赵再望, 姜维. Ag/AgBr/C₃N₅中LSPR增强S型电荷转移促进活性氧物种生成实现高效光催化降解抗生素废水[J]. 催化学报, 2026, 87(8): 126-139.
[4]	Polina Lavrik, Jurjen Cazemier, Mohamed N. Hedhili, Sudheesh K. Veeranmaril, Abdallah Nassereddine, Antonio Aguilar-Tapia, Marina Chernova, Jean-Louis Hazemann, Alla Dikhtiarenko, Javier Ruiz-Martínez. 钯核数与乙炔半氢化催化活性及选择性之间的关系[J]. 催化学报, 2026, 85(6): 384-393.
[5]	韩怡雯, 刘润雨, 张雨昕, 叶磊, Phuc T. T. Nguyen, 龚天军, 吕学斌, 傅尧, 颜宁. 单原子锚定的中空纳米反应器中构建内建电场以实现高效塑料光热重整[J]. 催化学报, 2026, 84(5): 301-313.
[6]	杨博霖, 靳菲, 靳治良. 非贵金属负载共价有机框架构建异质结高效光催化产氢[J]. 催化学报, 2026, 81(2): 172-184.
[7]	王少单, 杨恒, 薛丽君, 张建军, 欧阳述昕, 温丽丽. 金属掺杂ZnIn₂S₄/TpPa-1 S型异质结: 通过调控氢吸附/脱附和内建电场促进双功能光催化[J]. 催化学报, 2026, 80(1): 159-173.
[8]	宋鑫, 李中华, 盛利, 刘扬. 单原子催化剂中自旋密度对称性破缺介导的析氢反应[J]. 催化学报, 2026, 80(1): 213-226.
[9]	卞玉琴, 代凯. ZnO/COF通过Zn-N键的界面电荷转移促进光催化生成H₂O₂[J]. 催化学报, 2025, 76(9): 1-5.
[10]	李世杰, 李蕊, 董珂欣, 刘艳萍, 于欣, 李文尧, 刘通, 赵再望, 张明义, 张宾, 陈晓波. 自漂浮Bi₄O₅Br₂/磷掺杂氮化碳/碳纤维布S型异质结光催化剂增强去除新兴有机污染物[J]. 催化学报, 2025, 76(9): 37-49.
[11]	张云超, 潘劲康, 倪响, 莫非奇, 徐远国, 董鹏玉. 有机/无机杂化FS-COF/WO₃ S型异质结电荷载流子动力学及其光催化析氢性能[J]. 催化学报, 2025, 74(7): 250-263.
[12]	王刚, Imran Muhammad, 阎慧敏, 李隽, 王阳刚. 用杂原子调控Ni单原子催化剂的局部环境以实现高效CO₂电还原[J]. 催化学报, 2025, 74(7): 120-129.
[13]	王尔玉, 褚艺淳, 张文君, 魏彦平, 司传领, Regina Palkovits, 吴新平, 陈祖鹏. 利用Pt-C₃N₄单原子催化剂实现木质纤维素光重整共生产H₂与乳酸[J]. 催化学报, 2025, 74(7): 308-318.
[14]	胡晓春, 陶龙刚, 雷坤, 孙志强, 谭明务. 揭示TiO₂相效应对Pt单原子催化剂高效CO₂转化的影响[J]. 催化学报, 2025, 73(6): 186-195.
[15]	刘粉利, 杨曼, 段江林, 殷祉钰, 史名扬, 陈馥清, 熊惠峰, 刘忻, 刘文刚, 夏琦兴, 孙少东, 冯丹, 齐海峰, 覃勇, 任煜京. 外围氮空位诱导电子传递至Fe单原子以实现高效的氧气活化过程[J]. 催化学报, 2025, 72(5): 187-198.