扩散受限的中间体富集增强CO2加氢合成重质烃: 半开放与开放系统对比

doi:10.1016/S1872-2067(26)65161-3

催化学报 ›› 2027, Vol. 92: 300-315.DOI: 10.1016/S1872-2067(26)65161-3

扩散受限的中间体富集增强CO₂加氢合成重质烃: 半开放与开放系统对比

郭立升^a,*,1, 郑丽如^a,1, 张新宇^a, 王馨^a, 程杰^a, 蔡梦蝶^a, 刘娜^b,*, 王凯歌^c,*, 田友峰^d, 李杰^e, 孙松^a,*

^a安徽大学化学与化工学院, 安徽合肥 230601;
^b中南林业科技大学, 木本油料资源利用全国重点实验室, 湖南长沙 410004;
^c浙江大学, 能源清洁利用国家重点实验室, 浙江杭州 310027;
^d安徽中鼎密封件股份有限公司, 安徽宣城 341881;
^e扬州大学化学与材料学院, 江苏扬州 225002

收稿日期:2026-02-06 接受日期:2026-02-24 出版日期:2027-01-18 发布日期:2026-10-30
通讯作者: *电子信箱: lsguo@ahu.edu.cn (郭立升),Liuna1912@163.com (刘娜),kaigewang@zju.edu.cn (王凯歌),suns@ustc.edu.cn (孙松).
作者简介:¹共同第一作者.
基金资助:
国家自然科学基金(22102001, 22472001); 木本油料资源利用国家重点实验室开放基金; 浙江省重点研发计划(2025C01173); 安徽省高校协同创新计划(GXXT-2023-009).

Enhanced CO₂ hydrogenation to heavy hydrocarbons through diffusion-limited intermediate enrichment: Semi-open vs. open systems

Lisheng Guo^a,1,*, Liru Zheng^a,1, Xinyu Zhang^a, Xin Wang^a, Jie Cheng^a, Mengdie Cai^a, Na Liu^b,*, Kaige Wang^c,*, Youfeng Tian^d, Jie Li^e, Song Sun^a,*

^aSchool of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, Anhui, China;
^bState Key Laboratory of Woody Oil Resources Utilization, Central South University of Forestry and Technology, Changsha 410004, Hunan, China;
^cState Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, Zhejiang, China;
^dAnhui Zhongding Sealing Parts Co., Ltd, Xuancheng 341881, Anhui, China;
^eSchool of Chemistry and Materials, Yangzhou University, Yangzhou 225002, Jiangsu, China

Received:2026-02-06 Accepted:2026-02-24 Online:2027-01-18 Published:2026-10-30
Contact: *E-mail: lsguo@ahu.edu.cn (L. Guo), Liuna1912@163.com (N. Liu), kaigewang@zju.edu.cn (K. Wang), suns@ustc.edu.cn (S. Sun).
About author:¹ Contributed equally to this work.
Supported by:
National Natural Science Foundation of China (22102001, 22472001), the Open Foundation of State Key Laboratory of Woody Oil Resources Utilization, Key R&D Program of Zhejiang (2025C01173), and the University Synergy Innovation Program of Anhui Province (GXXT-2023-009).

摘要/Abstract

摘要： 随着煤炭、石油等碳基资源的大量开发利用, 二氧化碳的大量排放引发了温室效应、海洋酸化等一系列环境问题. 在此背景下, 实现CO₂的资源化利用并定向转化为高附加值重质烃对推进“双碳”目标、构建碳循环体系具有重要意义. CO₂催化加氢是碳资源化利用的重要途径, 但传统催化体系存在重质烃选择性低、活性相易烧结、反应路径调控难等问题, 且多聚焦于广口开放非限域体系, 三维限域下双金属活性位点的研究十分匮乏. 通过纳米限域微环境调控多相催化反应路径, 成为提升CO₂转化效率与产物定向性的关键突破口, 开发兼具高活性、高选择性与高稳定性的催化体系已成为该领域的研究重点.
本文以调控纳米限域微环境、优化CO₂加氢反应路径为设计思路. 采用溶剂介导的聚合诱导自组装策略, 制备了孔径可调(0–100 nm)的半开放多孔碳球载体(MPCS_x), 并通过限域CoFe合金构筑了Fe₁₀Co₂@MPCS_x系列催化剂. 系统研究了半开放限域环境对CO₂加氢制重质烃性能的调控规律, 并结合有限元模拟与原位漫反射红外光谱技术, 揭示了限域调控的微观作用机制. X-射线衍射、透射电镜-能量散射谱、X-射线吸收光谱等多种表征手段证实了CoFe合金的成功合成与均匀分散. 通过对比不同限域孔径催化剂的结构特性与性能, 发现孔径为14 nm的Fe₁₀Co₂@MPCS₁₄性能最优, 其CO₂转化率为24.7%, C₅₊产率较开放体系提升约2倍, 且在100 h连续测试中性能稳定, 未观察到明显金属颗粒烧结现象. 研究机理表明, 14 nm的半开放孔域在活性位点周围形成了独特的“富集-扩散”动态平衡, 显著提升了CO₂/H₂的局部浓度, 并且稳定了HCOO^*, HCO₃^*, CO₃^*等关键C₁中间体, 延长了表面停留时间, 从而极大促进了C–C偶联. 反之, 孔径过小会导致传质阻力增加, 产物堆积并竞争性占据活性位点. 孔径过大则限域效应减弱, 中间体易脱附, 导致重质烃选择性下降.
综上, 本研究阐明了纳米限域微环境对CO₂加氢反应路径的调控规律, 不仅为CO₂加氢定向转化为高附加值烃类提供了设计思路, 也为通过空间限域调控多相催化反应的选择性建立了范例, 可为CO₂加氢催化剂的后续开发提供理论支撑.

关键词: CO₂加氢, 纳米孔域, 半开放系统, 钴铁合金, 自组装

Abstract: Precisely tuning the nanoconfined microenvironment to optimize heterogeneous catalytic reaction pathways represents one of the critical challenges for achieving efficient and directional CO₂ conversion. In this study, we systematically investigated the impact of confinement dimensions on CO₂ hydrogenation performance by constructing a series of semi-open porous carbon spheres (MPCS_x) with tunable pore sizes (x = 0, 10, 14, 30, 100 nm) supported CoFe alloy catalysts. Experimental results revealed that the catalyst Fe₁₀Co₂@MPCS₁₄ with a pore size of 14 nm exhibits C₅₊ selectivity was twice that of open systems. To gain deeper insights into the structural origins of this optimal performance, we further elucidated the underlying microscopic mechanisms by combining Finite element method simulation with in-situ diffuse reflectance Fourier transform infrared spectroscopy. The 14 nm semi-open structure established a unique “enrichment-diffusion” dynamic equilibrium around the active sites, which not only substantially enhanced the local concentrations of CO₂/H₂ but also effectively stabilized key C1 intermediates such as HCOO^*, HCO₃^*, and CO₃^*. thereby promoting C–C coupling and carbon chain growth. This work provides important mechanistic insights into the regulation of selectivity in heterogeneous catalytic reactions through spatial confinement microenvironment modulation.

Key words: CO₂ hydrogenation, Nanopore domain, Semi-open system, CoFe alloy, Self-assembly

郭立升, 郑丽如, 张新宇, 王馨, 程杰, 蔡梦蝶, 刘娜, 王凯歌, 田友峰, 李杰, 孙松. 扩散受限的中间体富集增强CO₂加氢合成重质烃: 半开放与开放系统对比[J]. 催化学报, 2027, 92: 300-315.

Lisheng Guo, Liru Zheng, Xinyu Zhang, Xin Wang, Jie Cheng, Mengdie Cai, Na Liu, Kaige Wang, Youfeng Tian, Jie Li, Song Sun. Enhanced CO₂ hydrogenation to heavy hydrocarbons through diffusion-limited intermediate enrichment: Semi-open vs. open systems[J]. Chinese Journal of Catalysis, 2027, 92: 300-315.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(26)65161-3

https://www.cjcatal.com/CN/Y2027/V92/I1/300

参考文献

[1] E. C. Ra, K. Y. Kim, E. H. Kim, H. Lee, K. An, J. S. Lee,ACS Catal., 2020, 10, 11318-11345.
[2] P. Liu, Q. Wu, K. Yan, L. Wang, F.-S. Xiao,Chem. Synth., 2024, 4, 31.
[3] J. Wei, R. Yao, Y. Han, Q. Ge, J. Sun,Chem. Soc. Rev., 2021, 50, 10764-10805.
[4] L. Guo, X. Guo, Y. He, N. Tsubaki,J. Mater. Chem. A, 2023, 11, 11637-11669.
[5] A. I. Latsiou, N. D. Charisiou, Z. Frontistis, A. Bansode, M. A. Goula,Catal. Today, 2023, 420, 114179.
[6] W. Wang, K. Huo, Y. Wang, J. Xie, X. Sun, Y. He, M. Li, J. Liang, X. Gao, G. Yang, S. Lin, F. Cao, H. Jiang, M. Wu, N. Tsubaki,ACS Catal., 2024, 14, 9887-9900.
[7] B. Zhang, T. Xiao, C. Hu, Z. Liu, P. Chen, Z. Zhao, D. Lai, J. Huang, H. Zhang, X. Bao, P. Yuan,Chem. Synth., 2025, 5, 18.
[8] N. Rui, F. Zhang, K. Sun, Z. Liu, W. Xu, E. Stavitski, S. D. Senanayake, J. A. Rodriguez, C.-J. Liu,ACS Catal., 2020, 10, 11307-11317.
[9] M. Tawalbeh, R. M. N.Javed, A. Al-Othman, F. Almomani, S. Ajith,Environ. Technol. Innov., 2023, 31, 103217.
[10] J. Liang, J. Liu, L. Guo, W. Wang, C. Wang, W. Gao, X. Guo, Y. He, G. Yang, S. Yasuda, B. Liang, N. Tsubaki,Nat. Commun., 2024, 15, 512.
[11] Y. Ge, T. Zou, A. J. Martín, J. Pérez-Ramírez,ACS Catal., 2023, 13, 9946-9959.
[12] X. Wang, J. Qian, Z. Lu, J. Huang, L. Zheng, Y. Jiang, M. Cai, Y. Wei, L. Guo, S. Sun,Green Carbon, 2025, 3, 36-43.
[13] D. Deng, L. Yu, X. Chen, G. Wang, L. Jin, X. Pan, J. Deng, G. Sun, X. Bao,Angew. Chem. Int. Ed., 2013, 52, 371-375.
[14] L. Krausser, Q. Yang, E. V. Kondratenko,ChemCatChem, 2024, 16, e202301716.
[15] G. Song, M. Li, P. Yan, M. A. Nawaz, D. Liu,ACS Catal., 2020, 10, 11268-11279.
[16] J. Han, Y. Han, J. Yu, Y. Sun, X. Cui, Q. Ge, J. Sun,Angew. Chem. Int. Ed., 2025, 64, e202420621.
[17] T. Li, L. Zhang, J. Liang, Y. Han, Z. Liu, J. Sui, Q. Liu, T. Li, T. Xing, G. Liu, P. Zhang, X. Feng, Z. Jin, N. Tsubaki,Adv. Funct. Mater., 2025, 35, 2505432.
[18] L. Zhang, Y. Dang, X. Zhou, P. Gao, A. Petrus van Bavel, H. Wang, S. Li, L. Shi, Y. Yang, E. I. Vovk, Y. Gao, Y. Sun,Innovation, 2021, 2, 100170.
[19] L. Guo, X. Gao, W. Gao, H. Wu, X. Wang, S. Sun, Y. Wei, Y. Kugue, X. Guo, J. Sun, N. Tsubaki,Chem. Sci., 2022, 14, 171-178.
[20] S.-M. Hwang, S. J. Han, H.-G. Park, H. Lee, K. An, K.-W. Jun, S. K. Kim,ACS Catal., 2021, 11, 2267-2278.
[21] Y. Liu, Q. Cheng, S. Lyu, X. Li, S. Song, T. Ding, Y. Tian, X. Li,Chem. Eng. J., 2024, 494, 152936.
[22] Sonal, E. Ahmad, S. Upadhyayula, K. K. Pant,Int. J. Hydrogen Energy, 2019, 44, 27741-27748.
[23] C. Yang, B. Zhao, R. Gao, S. Yao, P. Zhai, S. Li, J. Yu, Y. Hou, D. Ma,ACS Catal., 2017, 7, 5661-5667.
[24] A. Stein, Z. Wang, M. A. Fierke,Adv. Mater., 2009, 21, 265-293.
[25] J. Lee, J. Kim, T. Hyeon,Adv. Mater., 2006, 18, 2073-2094.
[26] Z. Liu, W. Li, W. Sheng, S. Liu, R. Li, Q. Li, D. Li, S. Yu, M. Li, Y. Li, X. Jia,J. Am. Chem. Soc., 2023, 145, 5310-5319.
[27] S.-M. Hwang, C. Zhang, S. J. Han, H.-G. Park, Y. T. Kim, S. Yang, K.-W. Jun, S. K. Kim,J. CO₂ Util., 2020, 37, 65-73.
[28] T. Witoon, T. Numpilai, K. Nueangnoraj, C. K. Cheng, M. Chareonpanich, J. Limtrakul,Int. J. Hydrogen Energy, 2022, 47, 42185-42199.
[29] H. Lv, R. Guo, B. Liu,J. Am. Chem. Soc., 2025, 147, 31849-31858.
[30] C. Galeano, J. C. Meier, V. Peinecke, H. Bongard, I. Katsounaros, A. A. Topalov, A. Lu, K. J. J.Mayrhofer, F. Schüth,J. Am. Chem. Soc., 2012, 134, 20457-20465.
[31] L. Yu, D. Deng, X. Bao,Angew. Chem. Int. Ed., 2020, 59, 15294-15297.
[32] J. Xiao, X. Pan, S. Guo, P. Ren, X. Bao,J. Am. Chem. Soc., 2015, 137, 477-482.
[33] S. Wang, Q. Zhao, H. Wei, J.-Q. Wang, M. Cho, H. S. Cho, O. Terasaki, Y. Wan,J. Am. Chem. Soc., 2013, 135, 11849-11860.
[34] L. Sun, H. Yao, F. Jia, Y. Wang, B. Liu,Adv. Energy Mater., 2023, 13, 2302274.
[35] T.-T. Zhuang, Y. Pang, Z.-Q. Liang, Z. Wang, Y. Li, C.-S. Tan, J. Li, C. T. Dinh, P. De Luna, P.-L. Hsieh, T. Burdyny, H.-H. Li, M. Liu, Y. Wang, F. Li, A. Proppe, A. Johnston, D.-H. Nam, Z.-Y. Wu, Y.-R. Zheng, A. H. Ip, H. Tan, L.-J. Chen, S.-H. Yu, S. O. Kelley, D. Sinton, E. H. Sargent,Nat. Catal., 2018, 1, 946-951.
[36] Y. Kong, H. Yang, C. He, J. Sun, X. Jiang, X. Li, S. Feng, Y. Zhao, Q. Hu, C. He,CCS Chem., 2025, 7, 1227-1239.
[37] Z. Xue, B. Zhang, Q. Guo, Y. Wang, Q. Li, K. Yang, S. Qiao,Adv. Mater., 2025, 37, e10201.
[38] L.-X. Liu, Y. Cai, H. Du, X. Lu, X. Li, F. Liu, J. Fu, J.-J. Zhu,ACS Appl. Mater. Interfaces, 2023, 15, 16673-16679.
[39] Z. Zhao,ChemCatChem, 2020, 12, 3960-3981.
[40] J. Han, H. Xu, B. Zhao, R. Sun, G. Chen, T. Wu, G. Zhong, Y. Gao, S.-L. Zhang, Y. Yamauchi, B. Guan,J. Am. Chem. Soc., 2024, 146, 18979-18988.
[41] P. I. Ravikovitch, A. Vishnyakov, R. Russo, A. V. Neimark,Langmuir, 2000, 16, 2311-2320.
[42] C. G. Sonwane, S. K. Bhatia,J. Phys. Chem. B, 2000, 104, 9099-9110.
[43] P. I. Ravikovitch, A. V. Neimark,Stud. Surf. Sci. Catal., 2000, 129, 597-606.
[44] N. Liu, J. Wei, J. Xu, Y. Yu, J. Yu, Y. Han, K. Wang, J. I. Orege, Q. Ge, J. Sun,Appl. Catal. B, 2023, 328, 122476.
[45] M. Zhu, G. Sun, Q. Xin,Electrochim. Acta, 2009, 54, 1511-1518.
[46] L. Colmenares, H. Wang, Z. Jusys, L. Jiang, S. Yan, G. Q. Sun, R. J. Behm,Electrochim. Acta, 2006, 52, 221-233.
[47] H. Li, G. Sun, L. Cao, L. Jiang, Q. Xin,Electrochim. Acta, 2007, 52, 6622-6629.
[48] C. Baldizzone, S. Mezzavilla, H. W. P.Carvalho, J. C. Meier, A. K. Schuppert, M. Heggen, C. Galeano, J.-D. Grunwaldt, F. Schüth, K. J. J. Mayrhofer,Angew. Chem. Int. Ed., 2014, 53, 14250-14254.
[49] J. Knossalla, P. Paciok, D. Göhl, D. Jalalpoor, E. Pizzutilo, A. M. Mingers, M. Heggen, R. E.Dunin-Borkowski, K. J. J. Mayrhofer, F. Schüth, M. Ledendecker,J. Am. Chem. Soc., 2018, 140, 15684-15689.
[50] A. Samanta, T. Rajesh, R. N. Devi,J. Mater. Chem. A, 2014, 2, 4398-4405.
[51] S. Fang, L. Shen, S. Li, G.-T. Kim, D. Bresser, H. Zhang, X. Zhang, J. Maier, S. Passerini,ACS Nano, 2019, 13, 9511-9519.
[52] Y. Wu, M. Song, Z. Zhao, G.-H. Wang, C. Wang, D. Astruc,Carbon Energy, 2024, 6, e455.
[53] W. Miao, R. Hao, J. Wang, Z. Wang, W. Lin, H. Liu, Z. Feng, Y. Lyu, Q. Li, D. Jia, R. Ouyang, J. Cheng, A. Nie, J. Wu,Adv. Sci., 2023, 10, 2205087.
[54] N. Liu, Q. Fan, J. Wei, G. Zhang, J. Sun, W. Li, C. Song, X. Guo,ACS Catal., 2025, 15, 179-192.
[55] L. Peng, C.-T. Hung, S. Wang, X. Zhang, X. Zhu, Z. Zhao, C. Wang, Y. Tang, W. Li, D. Zhao,J. Am. Chem. Soc., 2019, 141, 7073-7080.
[56] M. Kalbac, L. Kavan,Carbon, 2010, 48, 832-838.
[57] M. Jalalah, H. Han, A. K. Nayak, F. A. Harraz,Adv. Compos. Hybrid Mater., 2024, 7, 20.
[58] S. Rudra, N. Deka, A. K. Nayak, M. Pradhan, G. K. Dutta,J. Energy Storage, 2022, 50, 104615.
[59] L. Jiang, X. Chen, N. Lu, L. Chi,Acc. Chem. Res., 2014, 47, 3009-3017.
[60] Y. Zhang, D. Ma, J. Li, Y. Chen, L. Shi, X. Feng, J.-W. Shi,J. Mater. Chem. A, 2025, 13, 10431-10450.
[61] H. Wu, L. Guo, X. Wang, W. Zhou, F. Chen, D. Li, K. Liu, P. Ai, Y. Wei, M. Cai, S. Sun,AIChE J., 2024, 70, e18445.
[62] T. Li, H. Zhao, L. Guo, G. Liu, J. Wu, T. Xing, T. Li, Q. Liu, J. Sui, Y. Han, J. Liang, Y. He, N. Tsubaki,ACS Catal., 2025, 15, 1112-1122.
[63] X. Wang, L. Guo, P. Ai, H. Wu, Z. Lu, J. Huang, J. Tong, L. Zheng, S. Sun,Fuel, 2024, 364, 131054.
[64] X. Yu, Q. Chen, Z. Hu, Q. Zhu, X. Kong,ACS Sustainable Chem. Eng., 2025, 13, 2853-2863.
[65] K. Gong, Y. Wei, T. Lin, X. Qi, F. Sun, Z. Jiang, L. Zhong,ACS Catal., 2023, 13, 4533-4543.
[66] Q. Hu, C. Wu, Z. Dong, G. Zhang, Z. Ma, X. Wang, S. Sun, J. Xu,J. Mater. Chem. A, 2022, 10, 2786-2794.
[67] W. Li, Y. Chen, C. Guo, S. Jia, Y. Zhou, Z. Liu, E. Jiang, X. Chen, Y. Zou, P. Huo, Y. Yan, Z. Zhu, Y. H. Ng, Y. Gong, J. C. Crittenden, Y. Yan,ACS Catal., 2024, 14, 13400-13407.
[68] M. Yang, Z. Zhao, T. Zhi, S. Yue, J. Li, T. Fu, P. Wang, S. Zhan,Carbon Neutralization, 2025, 4, e70017.
[69] M. Zhang, J. Ye, Y. Gao, X. Duan, J. Zhao, S. Zhang, X. Lu, K. Luo, Q. Wang, Q. Niu, P. Zhang, S. Dai,ACS Nano, 2024, 18, 1449-1463.
[70] Y. Ju, D. Bae, J. Park, H. W. Choi, J. Kang, K.-H. Ryu, Y. J. Kim, M. Kim, S. B. Kang,Appl. Catal. B, 2025, 379, 125675.
[71] M. K. Gnanamani, G. Jacobs, H. H. Hamdeh, W. D. Shafer, F. Liu, S. D. Hopps, G. A. Thomas, B. H. Davis,ACS Catal., 2016, 6, 913-927.
[72] B. Miao, S. S. K.Ma, X. Wang, H. Su, S. H. Chan,Catal. Sci. Technol., 2016, 6, 4048-4058.
[73] H. Ren, H. Yang, J. Xin, C. Wu, H. Wang, J. Zhang, X. Bu, G. Yang, J. Li, Y. Sun, P. Gao,Appl. Catal. B, 2024, 358, 124440.
[74] E. Gross, J. H. Liu, F. D. Toste, G. A. Somorjai,Nat. Chem., 2012, 4, 947-952.

扩散受限的中间体富集增强CO₂加氢合成重质烃: 半开放与开放系统对比

Enhanced CO₂ hydrogenation to heavy hydrocarbons through diffusion-limited intermediate enrichment: Semi-open vs. open systems

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	李猛, 田亮. 基于MXene的S型催化剂用于光热CO₂加氢[J]. 催化学报, 2026, 88(9): 1-4.
[2]	Jiyeon Lee, Muhammad Irshad, Wonjoong Yoon, Jaehoon Kim. 高压开关: 将二氧化碳加氢产物从碳氢化合物转向羧酸和醇类[J]. 催化学报, 2026, 87(8): 70-86.
[3]	刘晓洁, 余治甫, 李奇, 王阳, 毕鑫泽, 霍凯旋, 李丁尧, 苑志昂, 闫怡帆, 李士斌, 鲁宜武, 刘强, 王文行, 吴明铂. 铁基催化剂热催化CO₂加氢制乙醇: 水管理和铁基碳化物/氧化物比例的关键作用[J]. 催化学报, 2026, 86(7): 112-124.
[4]	Ksenia A. Kokina, Anton S. Konopatsky, Ekaterina S. Chikanova, Danil V. Barilyuk, Tatyana O. Teplakova, Denis V. Leybo, Ekaterina V. Sukhanova, Zakhar I. Popov, Alexey Y. Antonov, Olga A. Boeva, Sergey A. Efimov, Dmitry V. Shtansky. 高熵氧化物(CrMnFeCoNi)₃O₄催化剂在二氧化碳加氢反应中是否需要载体来提高性能?[J]. 催化学报, 2026, 85(6): 168-181.
[5]	Syeda Sidra Bibi, Sheraz Ahmed, Heuntae Jo, Jaehoon Kim. 由甲烷化变为链增长: Co-ZrO_x催化剂上钠诱导的分叉机理[J]. 催化学报, 2026, 85(6): 394-411.
[6]	Fleur A. E. Bruekers, Tess I. van Benthem, Rajamohanan Sobhana Anju, N. Raveendran Shiju. 物相到性能: 碳化钼在逆水煤气变换反应中的先进作用[J]. 催化学报, 2026, 85(6): 1-12.
[7]	刘芷瑶, 刘唐康, 秦川, 刘国亮, 郑安民. 氧化锆介导界面催化在CO₂加氢反应中的研究进展[J]. 催化学报, 2026, 84(5): 1-24.
[8]	蒋仕灿, 易明宇, 刘作政, Abhishek Dutta Chowdhury. 碳包覆铁基催化剂合成策略对CO₂改进费托合成性能的调控机制研究[J]. 催化学报, 2026, 84(5): 236-249.
[9]	刘意, 张鹏, 李益君, 韩志华, 冯波, 聂小娃, 陈静允, 何若南, 王周君, 邵磊, 秦绍东, 张光辉, 郭新闻. Zn介导调控Fe-Si相互作用实现CO₂加氢反应稳定性与选择性平衡[J]. 催化学报, 2026, 91(12): 122-134.
[10]	陈栋航, 刘俊辰, 邓威, 高彪, 王逸夫, 渡邊源規, 石原逹己, 郭利民. 扩散-酸性协同效应调控ZnZrO_x/SAPO-34串联催化剂实现高选择性CO₂加氢制丙烯[J]. 催化学报, 2026, 90(11): 145-157.
[11]	Xiaoyu Zhou, Wei Zhou, James Paterson, Jamie Southouse, Alexey Fedorov, Christoph R. Müller, Christophe Copéret. 原子层沉积和表面有机金属化学法制备的TiO₂负载CO₂加氢催化剂中钴态的光谱学探究[J]. 催化学报, 2026, 89(10): 402-409.
[12]	李文慧, 刘洋伯, 张依琳, 杨庆雯, 杨虹, 聂小娃, 郭新闻. CO竞争吸附和C-C偶联强化的PtCo合金催化剂调控CO₂加氢产物选择性[J]. 催化学报, 2026, 89(10): 378-389.
[13]	Wonjoong Yoon, Malayil Gopalan Sibi, Jaehoon Kim. 三床层Na-FeAlOₓ/Zn-HZSM-5@SiO₂催化CO₂直接加氢稳定生成芳烃[J]. 催化学报, 2026, 80(1): 330-346.
[14]	庹杰, 盛振腾, 龚贤晨, 杨琪, 吴鹏, 徐浩. ZnCeZrO_x/MCM-22择形催化二氧化碳加氢耦合甲苯甲基化反应[J]. 催化学报, 2025, 73(6): 174-185.
[15]	吴剑峰, 梁丽烨, 车政, 苗宇婷, 丑凌军. 双金属氧化物催化CO₂加氢制备甲醇: 最新进展和挑战[J]. 催化学报, 2025, 73(6): 62-78.