催化学报

催化学报 ›› 2009, Vol. 30 ›› Issue (6): 577-586.

• 综述 • 上一篇    

铑/双膦配体催化均相内烯烃氢甲酰化反应的研究进展

刘雯静,袁茂林,付海燕,李瑞祥,陈华   

  1. 四川大学化学学院有机金属络合催化研究所, 绿色化学与技术教育部重点实验室, 四川成都 610064
  • 收稿日期:2009-06-25 出版日期:2009-06-25 发布日期:2013-03-22

Progress of Rhodium/Diphosphine-Catalyzed Homogeneous Hydroformylation of Internal Olefins

LIU Wenjing, YUAN Maolin, FU Haiyan, LI Ruixiang, CHEN Hua*   

  1. Key Laboratory of Green Chemistry and Technology of Ministry of Education, Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, Sichuan, China
  • Received:2009-06-25 Online:2009-06-25 Published:2013-03-22

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1191

被引次数

21

摘要： 烯烃氢甲酰化反应是工业上合成醛的重要方法. 由于双膦配体良好的配位能力, 形成的铑配合物有很好的催化活性, 在内烯烃氢甲酰化反应中, 可以有效地提高直链醛选择性. 本文系统地综述了近年来双膦配体铑配合物催化均相内烯烃氢甲酰化反应的研究进展, 讨论了双膦配体结构对催化剂活性和生成直链醛选择性的影响.

关键词: 铑, 双膦配体, 内烯烃, 氢甲酰化

Abstract: Internal olefins are cheaper and more readily available feedstock than terminal olefins. The development of highly selective and active hydroformylation catalysts for internal olefins to produce linear aldehydes is of great importance from economic and energy points of view. This review systematically summarized the progress in this area using a variety of diphosphine ligands.

Key words: rhodium, diphosphorous ligand, internal olefin, hydroformylation