催化学报

催化学报 ›› 2011, Vol. 32 ›› Issue (2): 303-308.DOI: 10.3724/SP.J.1088.2011.00910

• 研究论文 • 上一篇    下一篇

载体焙烧温度对稀燃天然气汽车尾气净化 Pd/Zr0.5Al0.5O1.75 催化剂性能的影响

王云, 唐石云, 龙恩艳, 林之恩, 龚茂初, 陈耀强   

  1. 四川大学化学学院绿色化学与技术教育部重点实验室, 四川成都 610064
  • 收稿日期:2010-09-11 修回日期:2010-10-27 出版日期:2011-01-26 发布日期:2014-06-25

Influence of Supported-Calcination Temperature on the Performance of Pd/Zr0.5Al0.5O1.75 Catalyst Used in Lean-Burn Natural Gas Vehicles

WANG Yun, TANG Shiyun, LONG Enyan, LIN Zhien, GONG Maochu, CHEN Yaoqiang*   

  1. Key Laboratory of Green Chemistry and Technology of the Ministry of Education, Sichuan University, Chengdu 610064, Sichuan, China
  • Received:2010-09-11 Revised:2010-10-27 Online:2011-01-26 Published:2014-06-25

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摘要： 以不同温度焙烧得到的 Zr0.5Al0.5O1.75 复合氧化物为载体, 制备了系列 1.5% Pd/Zr0.5Al0.5O1.75 催化剂样品. 采用 N2 吸附-脱附、X 射线衍射、H2程序升温还原、O2程序升温脱附及 CO 化学吸附等手段对催化剂进行了表征, 并测试了催化剂在模拟稀燃天然气汽车尾气中的活性和抗 H2O 中毒性能. 结果表明, 载体焙烧温度对催化剂活性的影响很大, 其中以 950 °C 焙烧时催化剂的活性最高. 在不含 H2O 的条件下, 该催化剂对甲烷的起燃温度 (T50) 和完全转化温度 (T90) 分别为 274 和 315 °C; 而在含 H2O 条件下的 T50 和 T90分别为 325 和 356 °C, 表现出较高的低温活性和优良的抗 H2O 中毒能力.

关键词: 锆, 铝, 复合氧化物, 钯, 负载型催化剂, 稀燃天然气汽车

Abstract: The Zr0.5Al0.5O1.75 mixed oxide was prepared by coprecipitation method, and calcined at different temperatures and then used as a support to prepare a 1.5% Pd/Zr0.5Al0.5O1.75 catalyst. The catalyst activity and H2O resisting properties were evaluated in a mixed gas that simulated the exhaust of lean-burn natural gas fuelled vehicles (lean-burn NGVs). The catalyst was further characterized by N2 adsorption-desorption, X-ray diffraction, H2 temperature-programmed reduction, O2 temperature-programmed desorption and CO chemisorption. It was found that the catalyst activity was greatly influenced by the calcination temperature of the Zr0.5Al0.5O1.75 support. For the catalyst with the support calcined at 950 °C, the light-off temperature (T50) and complete conversion temperature (T90) of methane in the absence of H2O were 274 and 315 °C, respectively. In the presence of H2O, T50 and T90 were 325 and 356 °C, respectively. The results indicated that the catalyst had higher catalytic activity at low temperature and higher capability to resist H2O poisoning.

Key words: zirconium, aluminium, mixed oxide, palladium, supported catalyst, lean-burn natural gas fuelled vehicle