催化学报

催化学报 ›› 2011, Vol. 32 ›› Issue (5): 872-876.DOI: 10.1016/S1872-2067(10)60198-2

• 研究论文 • 上一篇    

Ru-Re/SiO2 催化剂上丙三醇氢解制丙二醇: 催化剂的酸性质与 Re 组分的作用

马兰1,2, 李宇明1, 贺德华1   

  1. 1清华大学化学系有机光电子与分子工程教育部重点实验室分子催化与定向转化研究室, 北京 100084; 2防化指挥工程学院三系, 北京 102205
  • 收稿日期:2010-12-08 修回日期:2011-01-17 出版日期:2011-05-31 发布日期:2014-09-29

Glycerol Hydrogenolysis to Propanediols over Ru-Re/SiO2: Acidity of Catalyst and Role of Re

MA Lan1,2, LI Yuming1, HE Dehua1,*   

  1. 1Innovative Catalysis Program, Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China; 2Institute of Chemical Defence, Beijing 102205, China
  • Received:2010-12-08 Revised:2011-01-17 Online:2011-05-31 Published:2014-09-29

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摘要： 考察了 Ru-Re/SiO2 双组分催化剂的酸性质, 并探讨了 Re 组分在丙三醇氢解制丙二醇反应中对提高该催化剂性能所起的作用. 本文采用氨气程序升温脱附法和吸附吡啶原位红外光谱法表征了双组分 Ru-Re/SiO2 和单组分 Ru/SiO2、Re/SiO2 催化剂的酸性质, 并比较了催化剂在丙三醇氢解反应中的催化性能. 结果显示, Ru-Re/SiO2、Ru/SiO2 和 Re/SiO2 催化剂表面均有酸性位, 但 Ru-Re/SiO2 和 Re/SiO2 催化剂的酸量明显高于 Ru/SiO2 催化剂. 本文对不同 Re 含量的 Ru-Re/SiO2 催化剂的催化性能也进行了考察. Ru-Re/SiO2 催化剂的活性随催化剂表面的酸量增加而增大, 且催化剂表面的酸量与催化剂上铼氧化物的含量直接相关. 讨论了铼氧化物在 Ru-Re/SiO2 催化剂催化的丙三醇氢解反应过程中所起的作用.

关键词: 钌, 铼, 氧化铼, 丙三醇氢解, 丙二醇, 酸性质

Abstract: The acidic property of Ru-Re/SiO2 catalysts and the role of Re were investigated. The acidic properties of Ru-Re/SiO2, Ru/SiO2, and Re/SiO2 were characterized by temperature programmed desorption of ammonia and in situ IR spectra of pyridine adsorption. Their catalytic performances in glycerol hydrogenolysis were compared. Ru-Re/SiO2, Ru/SiO2, and Re/SiO2 possessed acid sites, but the site amounts of Ru-Re/SiO2 and Re/SiO2 were much higher than that of Ru/SiO2. The activities of Ru-Re/SiO2 with different Re contents were evaluated. The activity of Ru-Re/SiO2 increased with the acid amount, which correlated with the amount of Re oxide on the catalyst. The role of Re oxide in Ru-Re/SiO2 catalyzed glycerol hydrogenolysis was discussed.

Key words: catalyst acidity, ruthenium-rhenium catalyst, rhenium oxide, glycerol hydrogenolysis, propanediols