催化学报

催化学报 ›› 2012, Vol. 33 ›› Issue (7): 1086-1094.DOI: 10.1016/S1872-2067(11)60401-4

• 研究论文 • 上一篇    下一篇

Selective Oxidation of Diphenylmethane to Benzophenone over CeAlPO-5 Molecular Sieves

Subbiah DEVIKA, Muthiahpillai PALANICHAMY, Velayutham MURUGESAN*   

  1. Department of Chemistry, Anna University, Chennai 600 025, India
  • 收稿日期:2011-09-26 修回日期:2012-01-13 出版日期:2012-06-21 发布日期:2012-06-21

Selective Oxidation of Diphenylmethane to Benzophenone over CeAlPO-5 Molecular Sieves

Subbiah DEVIKA, Muthiahpillai PALANICHAMY, Velayutham MURUGESAN*   

  1. Department of Chemistry, Anna University, Chennai 600 025, India
  • Received:2011-09-26 Revised:2012-01-13 Online:2012-06-21 Published:2012-06-21

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摘要： Selective oxidation of diphenylmethane to benzophenone requires active and selective catalysts. The framework incorporation of cerium in AlPO-5 molecular sieves creates active cerium sites in isolation. These active sites are responsible for selective oxidation. Cerium incorporated AlPO-5 with different Al/Ce ratios were synthesized, and the vapor phase oxidation of diphenylmethane in air over these catalysts was studied at 250, 275, 300, 325, and 350 °C. The diphenylmethane conversion and selectivity for benzophenone were more than 90%. CeAlPO-5(25) was found to be more active than other catalysts. The stability of the catalyst was verified by the time on stream study which indicated steady diphenylmethane conversion and benzophenone selectivity. Hence framework incorporated CeAlPO-5 molecular sieves are stable and active catalysts for the selective oxidation of diphenylmethane.

关键词: CeAlPO-5 molecular sieve, hydrothermal synthesis, oxidation, diphenylmethane, benzophenone

Abstract: Selective oxidation of diphenylmethane to benzophenone requires active and selective catalysts. The framework incorporation of cerium in AlPO-5 molecular sieves creates active cerium sites in isolation. These active sites are responsible for selective oxidation. Cerium incorporated AlPO-5 with different Al/Ce ratios were synthesized, and the vapor phase oxidation of diphenylmethane in air over these catalysts was studied at 250, 275, 300, 325, and 350 °C. The diphenylmethane conversion and selectivity for benzophenone were more than 90%. CeAlPO-5(25) was found to be more active than other catalysts. The stability of the catalyst was verified by the time on stream study which indicated steady diphenylmethane conversion and benzophenone selectivity. Hence framework incorporated CeAlPO-5 molecular sieves are stable and active catalysts for the selective oxidation of diphenylmethane.

Key words: CeAlPO-5 molecular sieve, hydrothermal synthesis, oxidation, diphenylmethane, benzophenone