A Rapid and Green Method for Solvent-Free Synthesis of 1,8-Dioxodecahydroacridines Using Tetrabutylammonium Hexatungstate as a Reusable Heterogeneous Catalyst

doi:10.1016/S1872-2067(11)60449-X

催化学报 ›› 2012, Vol. 33 ›› Issue (11): 1797-1801.DOI: 10.1016/S1872-2067(11)60449-X

A Rapid and Green Method for Solvent-Free Synthesis of 1,8-Dioxodecahydroacridines Using Tetrabutylammonium Hexatungstate as a Reusable Heterogeneous Catalyst

Abolghasem DAVOODNIA*, Atefeh ZARE-BIDAKI, Hossein BEHMADI

Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran

收稿日期:2012-07-12 修回日期:2012-08-21 出版日期:2012-11-16 发布日期:2012-11-16

A Rapid and Green Method for Solvent-Free Synthesis of 1,8-Dioxodecahydroacridines Using Tetrabutylammonium Hexatungstate as a Reusable Heterogeneous Catalyst

Abolghasem DAVOODNIA*, Atefeh ZARE-BIDAKI, Hossein BEHMADI

Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran

Received:2012-07-12 Revised:2012-08-21 Online:2012-11-16 Published:2012-11-16

摘要/Abstract

摘要： Tetrabutylammonium hexatungstate, [TBA]₂[W₆O₁₉], has been used as an efficient, inexpensive, and recyclable green catalyst for the one-pot three-component synthesis of 1,8-dioxodecahydroacridines by the reaction of dimedone with aromatic or aliphatic aldehydes in the presence of a nitrogen source (ammonium acetate or aromatic amines) under neat conditions. There are several advantages to the current process over the standard procedures available in the literature, including shorter reaction times (7–14 min), higher yields, facile work-up, and minimal environmental impact. Furthermore, the catalyst can be conveniently recovered and reused.

关键词: 1,8-dioxodecahydroacridine, solvent-free condition, tetrabutylammonium hexatungstate

Abstract: Tetrabutylammonium hexatungstate, [TBA]₂[W₆O₁₉], has been used as an efficient, inexpensive, and recyclable green catalyst for the one-pot three-component synthesis of 1,8-dioxodecahydroacridines by the reaction of dimedone with aromatic or aliphatic aldehydes in the presence of a nitrogen source (ammonium acetate or aromatic amines) under neat conditions. There are several advantages to the current process over the standard procedures available in the literature, including shorter reaction times (7–14 min), higher yields, facile work-up, and minimal environmental impact. Furthermore, the catalyst can be conveniently recovered and reused.

Key words: 1,8-dioxodecahydroacridine, solvent-free condition, tetrabutylammonium hexatungstate

Abolghasem DAVOODNIA, Atefeh ZARE-BIDAKI, Hossein BEHMADI. A Rapid and Green Method for Solvent-Free Synthesis of 1,8-Dioxodecahydroacridines Using Tetrabutylammonium Hexatungstate as a Reusable Heterogeneous Catalyst[J]. 催化学报, 2012, 33(11): 1797-1801.

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A Rapid and Green Method for Solvent-Free Synthesis of 1,8-Dioxodecahydroacridines Using Tetrabutylammonium Hexatungstate as a Reusable Heterogeneous Catalyst

A Rapid and Green Method for Solvent-Free Synthesis of 1,8-Dioxodecahydroacridines Using Tetrabutylammonium Hexatungstate as a Reusable Heterogeneous Catalyst

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