催化学报

催化学报 ›› 2013, Vol. 34 ›› Issue (5): 964-972.DOI: 10.1016/S1872-2067(12)60585-3

• 研究论文 • 上一篇    下一篇

NO在Cu(111)表面吸附和分解的XPS和TPD研究：不同氧物种的影响

陈博昊a,b,c, 马运生a, 丁良兵a, 许令顺a,b,c, 邬宗芳a,b,c, 袁青a,b,c, 黄伟新a,b,c   

  1. a 中国科学技术大学化学物理系, 安徽 合肥 230026;
    b 中国科学院能量转换材料重点实验室, 安徽 合肥 230026;
    c 中国科学技术大学微尺度物质科学国家实验室(筹), 安徽 合肥 230026
  • 收稿日期:2013-01-05 修回日期:2013-05-20 出版日期:2013-05-06 发布日期:2013-05-06
  • 通讯作者: 马运生,黄伟新
  • 基金资助:

    国家自然科学基金(21073172);国家重点基础研究发展计划(973计划,2013CB933104,2013CB933102,2010CB923301);中央高校基本科研业务费专项资金资助.

XPS and TPD study of NO interaction with Cu(111)：Role of different oxygen species

CHEN Bohaoa,b,c, MA Yunshenga, DING Liangbinga, XU Lingshuna,b,c, WU Zongfanga,b,c, YUAN Qinga,b,c, HUANG Weixina,b,c   

  1. a Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, Anhui, China;
    b CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei 230026, Anhui, China;
    c Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026, Anhui, China
  • Received:2013-01-05 Revised:2013-05-20 Online:2013-05-06 Published:2013-05-06
  • Supported by:

    This work was supported by the National Natural Science Foundation of China (21073172), the National Basic Research Program of China (973 Program, 2013CB933104, 2013CB933102, 2010CB923301), and the Fundamental Research Funds for the Central Universities.

PDF

955

摘要：

利用X射线光电子能谱和程序升温脱附谱研究了NO在清洁和预吸附氧的Cu(111)表面上的吸附和反应.通过改变NO的暴露量和退火温度,在Cu(111)表面可以制备出不同种类的化学吸附氧物种,其O 1s的结合能分别位于531.0 eV (O531)和529.7 eV (O529).表面O531物种的存在对NO的不同吸附状态有着显著影响,同时使得大部分NO吸附分子(NO(a))在加热过程中发生分解并以N2O和N2形式脱附; 而表面O529物种对NO(a)的解离脱附有着明显的抑制作用.相对于O531物种来说,O529物种对NO吸附表现出更强的位阻效应.上述结果表明,NO在Cu(111) 表面的吸附和分解行为与预吸附氧物种的种类和覆盖度密切相关.

关键词: 一氧化氮, Cu(111)表面, 氧物种, 吸附, X射线光电子能谱, 程序升温脱附谱

Abstract:

The adsorption and reaction of NO on clean and O-precovered Cu(111) has been studied using X-ray photoelectron spectroscopy and temperature-programmed desorption spectroscopy. By varying NO exposure and annealing temperature, two different types of chemisorbed oxygen species, with O 1s binding energies (BE) of 531.0 (O531) and 529.7 eV (O529), were prepared on Cu(111). In the presence of O531 species, the relative occupation of different NO adsorption states was largely affected, and most of the adsorbed NO(a) underwent dissociative desorption, releasing N2O and N2 upon heating. In contrast, in the presence of O529 species, the dissociative desorption of NO(a) was largely suppressed. Furthermore, the O529 species show a more significant blocking effect on NO adsorption than the chemisorbed O531 species. Our results reveal that the effect of precovered oxygen species on the adsorption and reaction of NO on Cu(111) is closely related to the type of oxygen species and oxygen coverage.

Key words: Nitrogen oxide, Cu(111), Oxygen species, Adsorption, Temperature-programmed desorption, X-ray photoelectron spectroscopy