组合催化剂WO3+Raney Ni上高效转化菊芋秸秆制乙二醇

doi:10.1016/S1872-2067(12)60686-X

催化学报 ›› 2013, Vol. 34 ›› Issue (11): 2041-2046.DOI: 10.1016/S1872-2067(12)60686-X

组合催化剂WO₃+Raney Ni上高效转化菊芋秸秆制乙二醇

周立坤^a,b, 庞纪峰^a, 王爱琴^a, 张涛^a

a 中国科学院大连化学物理研究所催化基础国家重点实验室, 辽宁大连116023;
b 中国科学院大学, 北京100049

收稿日期:2013-04-04 修回日期:2013-06-05 出版日期:2013-10-18 发布日期:2013-10-18
通讯作者: Tao Zhang
基金资助:
国家重点基础研究发展计划(973计划,2009CB226102);国家自然科学基金(21176235).

Catalytic conversion of Jerusalem artichoke stalk to ethylene glycol over a combined catalyst of WO₃ and Raney Ni

Likun Zhou^a,b, Jifeng Pang^a, Aiqin Wang^a, Tao Zhang^a

a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China

Received:2013-04-04 Revised:2013-06-05 Online:2013-10-18 Published:2013-10-18
Contact: Tao Zhang
Supported by:
This work was supported by the National Basic Research Program of China (973 Program, 2009CB226102) and the National Natural Science Foundation of China (21176235).

摘要/Abstract

摘要：

采用商业WO₃和Raney Ni为组合催化剂, 以菊芋秸秆为反应原料制备了乙二醇. 菊芋秸秆中含纤维素51.6 wt%、半纤维素10.3 wt%、木质素17.2 wt%、灰分1.7 wt%和水溶性物质19.2 wt%. 木质素对纤维素和半纤维素的转化影响较小, 而水溶性物质的存在抑制了乙二醇的生成, 因此由未经过预处理的菊芋秸秆得到的乙二醇收率只有29.9%. 而经简单的热水预处理可除掉其中的大部分水溶物, 因而乙二醇收率提高到37.6%. 此外, 组合催化剂在经过热水预处理的菊芋秸秆的转化中表现出了更好的循环使用性能. 同时考察了反应温度和时间对菊芋秸秆转化的影响.

关键词: 木质纤维素, 菊芋秸秆, 三氧化钨, 雷尼镍, 乙二醇

Abstract:

Jerusalem artichoke stalk (JAS) was employed as the feedstock for the production of ethylene glycol (EG) with a combined catalyst comprising commercial WO₃ and Raney Ni. The raw JAS contains 51.6 wt% cellulose, 10.3 wt% hemicellulose, 17.2 wt% lignin, 1.7 wt% ash, and 19.2 wt% water-soluble substances. It was found that the lignin component in the JAS had little effect on the conversion of hemicellulose while the water-soluble substances caused a negative effect, which led to an EG yield of only 29.9%. After a simple hot water pretreatment, most of the water-soluble substances were removed, and the EG yield was increased to 37.6%. Moreover, the hot water pretreatment also led to an improvement in the durability of the catalyst. The effects of reaction temperature and reaction duration were also investigated.

Key words: Lignocellulose, Jerusalem artichoke stalk, Tungsten trioxide, Raney nickel, Ethylene glycol

周立坤, 庞纪峰, 王爱琴, 张涛. 组合催化剂WO₃+Raney Ni上高效转化菊芋秸秆制乙二醇[J]. 催化学报, 2013, 34(11): 2041-2046.

Likun Zhou, Jifeng Pang, Aiqin Wang, Tao Zhang. Catalytic conversion of Jerusalem artichoke stalk to ethylene glycol over a combined catalyst of WO₃ and Raney Ni[J]. Chinese Journal of Catalysis, 2013, 34(11): 2041-2046.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(12)60686-X

https://www.cjcatal.com/CN/Y2013/V34/I11/2041

参考文献

[1] Huber G W, Chheda J N, Barrett C J, Dumesic J A. Science, 2005, 308: 1446
[2] Goldemberg J. Energy Environ Sci, 2008, 1: 523
[3] Ma J P, Yu W Q, Wang M, Jia X Q, Lu F, Xu J. Chin J Catal (马继平, 于维强, 王敏, 贾秀全, 路芳, 徐杰. 催化学报), 2013, 34: 492
[4] Mascal M, Nikitin E B. Green Chem, 2010, 12: 370
[5] Zhou C H, Xia X, Lin C X, Tong D S, Beltramini J. Chem Soc Rev, 2011, 40: 5588
[6] Long J X, Li X H, Guo B, Wang F R, Yu Y H, Wang L F. Green Chem, 2012, 14: 1935
[7] Zhao C, Kou Y, Lemonidou A A, Li X B, Lercher J A. Angew Chem Int Ed, 2009, 48: 3987
[8] Song Q, Wang F, Xu J. Chem Commun, 2012, 48: 7019
[9] Song Q, Wang F, Cai J Y, Wang Y H, Zhang J J, Yu W Q, Xu J. Energy Environ Sci, 2013, 6: 994
[10] Wang A Q, Zhang T. Acc Chem Res, 2013, 46: 1377
[11] Fukuoka A, Dhepe P L. Angew Chem Int Ed, 2006, 45: 5161
[12] Luo C, Wang S, Liu H C. Angew Chem Int Ed, 2007, 46: 7636
[13] Pang J F, Wang A Q, Zheng M Y, Zhang T. Chem Commun, 2010, 46: 6935
[14] Zhang Y H, Wang A Q, Zhang T. Chem Commun, 2010, 46: 862
[15] Li C Z, Zhao Z K. Adv Synth Catal, 2007, 349: 1847
[16] Ji N, Zhang T, Zheng M Y, Wang A Q, Wang H, Wang X D, Chen J G. Angew Chem Int Ed, 2008, 47: 8510
[17] Zheng M Y, Wang A Q, Ji N, Pang J F, Wang X D, Zhang T. ChemSusChem, 2010, 3: 63
[18] Yue H R, Zhao Y J, Ma X B, Gong J L. Chem Soc Rev, 2012, 41: 4218
[19] Ma J P, Pang Y, Wang M, Xu J, Ma H, Nie X. J Mater Chem, 2012, 22: 3457
[20] Ji N, Zhang T, Zheng M Y, Wang A Q, Wang H, Wang X D, Shu Y Y, Stottlemyer A L, Chen J G. Catal Today, 2009, 147: 77
[21] Zhao G H, Zheng M Y, Wang A Q, Zhang T. Chin J Catal (赵冠鸿, 郑明远, 王爱琴, 张涛. 催化学报), 2010, 31: 928
[22] Liu Y, Luo C, Liu H C. Angew Chem Int Ed, 2012, 51: 3249
[23] Pang J F, Zheng M Y, Wang A Q, Zhang T. Ind Eng Chem Res, 2011, 50: 6601
[24] Li C Z, Zheng M Y, Wang A Q, Zhang T. Energy Environ Sci, 2012, 5: 6383
[25] Kays S J, Nottingham S F. Biology and Chemistry of Jerusalem Artichoke: Helianthus Tuberosus L. Boca Raton: CRC Press, 2007
[26] Ge X Y, Zhang W G. Food Technol Biotechnol, 2005, 43: 241
[27] Cheng Y, Zhou W G, Gao C F, Lan K, Gao Y, Wu Q Y. J Chem Technol Biotechnol, 2009, 84: 777
[28] Zhou L K, Wang A Q, Li C Z, Zheng M Y, Zhang T. ChemSusChem, 2012, 5: 932
[29] Goering H K, Van Soest P J. Forage Fiber Analysis, USDA-ARS Agriculture Handbook Number 379. Washington DC: Agricultural Research Service, United States Department of Agriculture, 1970. 12
[30] Dhepe P L, Fukuoka A. ChemSusChem, 2008, 1: 969
[31] Nitsos C K, Matis K A, Triantafyllidis K S. ChemSusChem, 2013, 6: 110
[32] De Frias J A, Feng H. Green Chem, 2013, 15: 1067
[33] Tai Z J, Zhang J Y, Wang A Q, Zheng M Y, Zhang T. Chem Commun, 2012, 48: 7052

组合催化剂WO₃+Raney Ni上高效转化菊芋秸秆制乙二醇

Catalytic conversion of Jerusalem artichoke stalk to ethylene glycol over a combined catalyst of WO₃ and Raney Ni

PDF

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	孟帅奇, 李忠玉, 张鹏, Francisca Contreras, 季宇, Ulrich Schwaneberg. 深度学习指导的热裂褐藻角质酶工程用于促进PET解聚[J]. 催化学报, 2023, 50(7): 229-238.
[2]	刘玥, 章伟, 刘海超. 三氧化钨基催化剂在纤维素选择性转化合成二元醇反应中的活性相态[J]. 催化学报, 2023, 46(3): 56-63.
[3]	Johannes A. Lercher. 三氧化钨催化糖分子选择裂解新机理及其对生物质利用的重要意义[J]. 催化学报, 2023, 46(3): 1-3.
[4]	王力梅, 杜大学, 张彪, 谢顺吉, 张庆红, 王海燕, 王野. 高稳定性的氮掺杂氧化钽光催化甲醇C-H活化和直接C-C偶联制乙二醇[J]. 催化学报, 2021, 42(9): 1459-1467.
[5]	曾融蓉, 王昆, 邵伟, 赖俊杭, 宋树芹, 王毅. 溶剂热助乙二醇还原法制备Pt/C催化剂过程中酸碱配位机制及工艺参数优化[J]. 催化学报, 2020, 41(5): 820-829.
[6]	古文泉, 王万军, 李桂英, 谢皓晶, 王保强, 安太成. 微波辅助合成缺陷型氧化钨及其光催化杀菌机理:氧空位的作用[J]. 催化学报, 2020, 41(10): 1488-1497.
[7]	王帅, 刘海超. 木质纤维素生物质催化转化制备液体燃料和化学品[J]. 催化学报, 2019, 40(s1): 178-186.
[8]	唐雪君, 方达晖, 瞿丽娟, 徐东彦, 秦晓平, 覃博文, 宋微, 邵志刚, 衣宝廉. 微量Co修饰的碳载超细Pt纳米粒子的制备及其在燃料电池氧还原催化中的应用[J]. 催化学报, 2019, 40(4): 504-514.
[9]	黄静伟, 岳彭飞, 王磊, 佘厚德, 王其召. 基于三氧化钨的光阳极水氧化综述[J]. 催化学报, 2019, 40(10): 1408-1420.
[10]	刘佳驹, 贺鹏, 王利国, 刘辉, 曹妍, 李会泉. 碳酸乙烯酯选择加氢合成甲醇与乙二醇高效稳定Cu/SiO₂催化剂研究[J]. 催化学报, 2018, 39(8): 1283-1293.
[11]	杨荔, 刘旸, 张瑞阳, 李伟, 李璞, 王星, 周莹. 整体式三氧化钨/氧化石墨烯气凝胶增强可见光光催化氧化NO性能[J]. 催化学报, 2018, 39(4): 646-653.
[12]	李亚文, 布玉珍, 刘倩, 张霞, 徐君莉. WO₃纳米颗粒修饰ZnO纳米管的光催化性能[J]. 催化学报, 2018, 39(1): 54-62.
[13]	Mohsen Nikoorazm, Farshid Ghorbani, Arash Ghorbani-Choghamarani, Zahra Erfani. 可重复使用的新型催化剂的合成、表征及在绿色条件下催化Suzuki和Heck反应:锚合在磁性纳米多孔的MCM-41上Pd(0)希夫碱络合物[J]. 催化学报, 2017, 38(8): 1413-1422.
[14]	Arash Ghorbani-Choghamarani, Zahra Taherinia. 肽纳米纤维固载Pd纳米颗粒为催化剂、羟基苯并三唑为新型苯基化试剂合成联芳[J]. 催化学报, 2017, 38(3): 469-474.
[15]	张亚平, 王龙飞, 李娟, 张会岩, 徐海涛, 肖睿, 杨林军. V₂O₅-WO₃/TiO₂-ZrO₂脱硝催化剂中ZrO₂和WO₃的促进作用:催化性能、形态及反应机理[J]. 催化学报, 2016, 37(11): 1918-1930.