Proton catalysis with active carbons and partially pyrolyzed carbonaceous materials

doi:10.1016/S1872-2067(14)60147-9

摘要/Abstract

摘要：

The development of environmentally friendly solid acid catalysts is a priority task. Highly oxidized activated carbon and their ion-substituted (saline) forms are effective proton transfer catalysts in esterification, hydrolysis, and dehydration, and thus are promising candidates as solid acid catalysts. Computations by the ab initio method indicated the cause for the enchanced acidity of the carboxylic groups attached to the surface of highly oxidized carbon. The synthesis of phosphorilated carbon was considered, and the proton transfer reactions catalyzed by them in recent studies were analyzed. The development of an amorphous carbon acid catalyst comprising polycyclic carbonaceous (graphene) sheets with-SO₃H,-COOH and phenolic type OH-groups was carried out. These new catalysts were synthesized by partial pyrolysis and subsequent sulfonation of carbohydrates, polymers, and other organic compounds. Their high catalytic activities in proton transfere reactions including the processing of bio-based raw materials was demonsrated.

关键词: Active carbon, Oxidized carbon, Solid acid catalyst, Quantum chemical calculation, Sulfonated carbonaceous material, Phosphorylated carbon, Partially pyrolised organic compound, Catalytic conversion biobased raw, material

Abstract:

Key words: Active carbon, Oxidized carbon, Solid acid catalyst, Quantum chemical calculation, Sulfonated carbonaceous material, Phosphorylated carbon, Partially pyrolised organic compound, Catalytic conversion biobased raw, material

V. V. Strelko, S. S. Stavitskaya, Yu. I. Gorlov. Proton catalysis with active carbons and partially pyrolyzed carbonaceous materials[J]. 催化学报, 2014, 35(6): 815-823.

V. V. Strelko, S. S. Stavitskaya, Yu. I. Gorlov. Proton catalysis with active carbons and partially pyrolyzed carbonaceous materials[J]. Chinese Journal of Catalysis, 2014, 35(6): 815-823.

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