Selective oxidation of alcohols over copper zirconium phosphate

doi:10.1016/S1872-2067(14)60096-6

催化学报 ›› 2014, Vol. 35 ›› Issue (9): 1529-1533.DOI: 10.1016/S1872-2067(14)60096-6

Selective oxidation of alcohols over copper zirconium phosphate

Abdol R. Hajipour^a,b, Hirbod Karimi^a

a Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156, Iran;
b Department of Neuroscience, University of Wisconsin, Medical School, Madison, WI 53706-1532, USA

收稿日期:2014-02-21 修回日期:2014-03-31 出版日期:2014-08-19 发布日期:2014-08-22
通讯作者: Abdol R. Hajipour
基金资助:
This work was supported by the Isfahan University of Technology, Iran.

Selective oxidation of alcohols over copper zirconium phosphate

Abdol R. Hajipour^a,b, Hirbod Karimi^a

a Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156, Iran;
b Department of Neuroscience, University of Wisconsin, Medical School, Madison, WI 53706-1532, USA

Received:2014-02-21 Revised:2014-03-31 Online:2014-08-19 Published:2014-08-22
Supported by:
This work was supported by the Isfahan University of Technology, Iran.

摘要/Abstract

摘要：

The catalytic activity of copper zirconium phosphate (ZPCu) in the selective oxidation of alcohols to their corresponding ketones or aldehydes, using H₂O₂ as an oxidizing agent, was studied. The oxidation reaction was performed without any organic solvent, phase-transfer catalyst, or additive. Steric factors associated with the substrates influenced the reaction. The catalyst was characterized using X-ray diffraction, inductively coupled plasma atomic emission spectroscopy, energy-dispersive X-ray spectroscopy, and scanning electron microscopy. It was shown that the interlayer distance increased from 0.74 to 0.80 nm and the crystallinity was reduced after Cu²⁺ intercalation into the layers. This catalyst can be recovered and reused three times without significant loss of activity and selectivity.

关键词: Copper zirconium phosphate, Selective oxidation, Solid catalyst, Alcohol

Abstract:

Key words: Copper zirconium phosphate, Selective oxidation, Solid catalyst, Alcohol

Abdol R. Hajipour, Hirbod Karimi. Selective oxidation of alcohols over copper zirconium phosphate[J]. 催化学报, 2014, 35(9): 1529-1533.

Abdol R. Hajipour, Hirbod Karimi. Selective oxidation of alcohols over copper zirconium phosphate[J]. Chinese Journal of Catalysis, 2014, 35(9): 1529-1533.

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Selective oxidation of alcohols over copper zirconium phosphate

Selective oxidation of alcohols over copper zirconium phosphate

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