钒掺杂的钛酸钠纳米管作为多相催化剂用于室温下硫化物的氧化

doi:10.1016/S1872-2067(15)61056-7

摘要/Abstract

摘要：

合成了一种含有TiO₂, Na和V的多相纳米管催化剂, 采用红外光谱、X射线衍射、扫描电镜、透射电镜和N₂吸附-脱附法对该催化剂的结构和织构性质进行了表征, 并用于水中30% H₂O₂选择性氧化硫化物制备对应的亚砜. 该法具有产率极高、多相体系和简便等优点, 可用于含一系列官能团底物的氧化, 产物分离简便.

关键词: 硫化物, 亚砜, 砜类, 负载型钒催化剂, 纳米管

Abstract:

A heterogeneous titanate nanotube (TNT) catalyst containing TiO₂, Na, and V has been synthesized and used in the chemoselective oxidation of sulfides to the corresponding sulfoxides in the presence of 30% H₂O₂ in water. Some of the advantages of our method include excellent yields, heterogeneous conditions, simplicity, compatibility with a variety of functionalities, and ease of isolation of the products. Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and N₂ adsorption were used for structural and textural characterization of the catalyst (VNaTNT).

Key words: Sulfide, Sulfoxide, Sulfone, Supported vanadia catalyst, Nanotube

Mohammad Ali Dadvar, Razieh Fazaeli. 钒掺杂的钛酸钠纳米管作为多相催化剂用于室温下硫化物的氧化[J]. 催化学报, 2016, 37(4): 494-501.

Mohammad Ali Dadvar, Razieh Fazaeli. Application of sodium titanate nanotubes doped with vanadium (VNaTNT) as a heterogeneous catalyst for oxidation of sulfides at room temperature[J]. Chinese Journal of Catalysis, 2016, 37(4): 494-501.

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