高效固体酸SBA-15-Zr(OTf)3催化胺或醇开环环氧化合物

doi:10.1016/S1872-2067(17)62794-3

催化学报 ›› 2017, Vol. 38 ›› Issue (4): 758-766.DOI: 10.1016/S1872-2067(17)62794-3

• 论文 • 上一篇

高效固体酸SBA-15-Zr(OTf)₃催化胺或醇开环环氧化合物

Kamlesh N.Tayade^a, 王连月^a, 尚森森^a, 戴文^a, Manish Mishra^b, 高爽^a

a 中国科学院大连化学物理研究所洁净能源国家实验室(筹), 辽宁大连 116023;
b 德赛大学技术学院化学工程系, Shah-Schulman表面科学与纳米技术中心, 古吉拉特邦, 纳迪亚德市, 印度

收稿日期:2016-11-21 修回日期:2017-01-06 出版日期:2017-04-18 发布日期:2017-04-12
通讯作者: 高爽
基金资助:
中国科学院国际人才计划（2016PT028）、国家自然科学基金（21273225、21403219）.

Zirconium triflate grafted on SBA-15 as a highly efficient solid acid catalyst for ring opening of epoxides by amines and alcohols

Kamlesh N.Tayade^a, Lianyue Wang^a, Sensen Shang^a, Wen Dai^a, Manish Mishra^b, Shuang Gao^a

a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b Department of Chemical Engineering And Shah-Schulman Center for Surface Science and Nanotechnology, Faculty of Technology, Dharmsinh Desai University, Nadiad 387001, Gujarat, India

Received:2016-11-21 Revised:2017-01-06 Online:2017-04-18 Published:2017-04-12
Supported by:
This work was supported by the CAS President's International Fellowship Initiative (2016PT028) and the National Natural Science Foundation of China (21273225 and 21403219).

摘要/Abstract

摘要：

通过简单的一锅两步法制备了三氟金属（铝，钛，锆）接枝介孔SBA-15 （AlTf/S，TiTf/S，ZrTf/S）固体酸材料，并通过XRD，N₂吸附，TGA，FTIR，原位吡啶FTIR和元素分析对这些材料进行了详细的表征.其中，ZrTf/S能够高效催化环氧化物温和条件下被胺或醇开环生成对应β-氨基醇或β-烷氧基醇，并且催化剂能循环利用.ZrTf/S相较于AlTf/S和TiTf/S酸性最强，因而催化活性也最高.

关键词: 环氧开环, 酸催化, 三氟金属, 接枝催化剂, 介孔硅

Abstract:

Metal (Al, Ti, Zr) triflate grafted mesoporous SBA-15 (AlTf/S, TiTf/S, ZrTf/S) samples were synthesized as inexpensive solid acid materials by a simple one-pot-two-step synthesis methodology. These materials were characterized by X-ray diffraction, N₂-sorption, thermogravimetric analysis, Fourier transform infrared spectroscopy (FT-IR), in-situ pyridine FT-IR spectroscopy, and elemental analysis. ZrTf/S was found to be a highly efficient and reusable solid acid catalyst for ring opening of epoxides with amines and alcohols and produced β-amino alcohols and β-alkoxy alcohols respectively under ambient reaction conditions. The ZrTf/S catalyst showed the highest activity, which was attributed to its high acidity compared with that of the Ti and Al containing samples.

Key words: Epoxide ring opening, Acid catalysis, Metal triflate, Grafted catalyst, Mesoporous silica

Kamlesh N.Tayade, 王连月, 尚森森, 戴文, Manish Mishra, 高爽. 高效固体酸SBA-15-Zr(OTf)₃催化胺或醇开环环氧化合物[J]. 催化学报, 2017, 38(4): 758-766.

Kamlesh N.Tayade, Lianyue Wang, Sensen Shang, Wen Dai, Manish Mishra, Shuang Gao. Zirconium triflate grafted on SBA-15 as a highly efficient solid acid catalyst for ring opening of epoxides by amines and alcohols[J]. Chinese Journal of Catalysis, 2017, 38(4): 758-766.

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高效固体酸SBA-15-Zr(OTf)₃催化胺或醇开环环氧化合物

Zirconium triflate grafted on SBA-15 as a highly efficient solid acid catalyst for ring opening of epoxides by amines and alcohols

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