PdS修饰的ZnIn2S4复合材料用于可见光催化硫醇偶联制备二硫化物同时产氢

doi:10.1016/S1872-2067(23)64481-X

催化学报 ›› 2023, Vol. 51: 55-65.DOI: 10.1016/S1872-2067(23)64481-X

PdS修饰的ZnIn₂S₄复合材料用于可见光催化硫醇偶联制备二硫化物同时产氢

李晓娟, 祁明雨, 李婧宇, 谭昌龙, 唐紫蓉(), 徐艺军()

福州大学化学学院, 能源与环境光催化国家重点实验室, 福建福州350116

收稿日期:2023-04-23 接受日期:2023-06-29 出版日期:2023-08-18 发布日期:2023-09-11
通讯作者: *电子信箱: zrtang@fzu.edu.cn (唐紫蓉), yjxu@fzu.edu.cn (徐艺军).
基金资助:
国家自然科学基金(22172030);国家自然科学基金(22072023);国家自然科学基金(21872029);国家自然科学基金(21173045);国家自然科学基金(U1463204);福建省高校领军人才;国家万人计划科技创新领军人才(00387072);福建省自然科学基金(2017J07002);福建省自然科学基金(019J01631);福建省首批青年拔尖创新人才

Visible light-driven dehydrocoupling of thiols to disulfides and H₂ evolution over PdS-decorated ZnIn₂S₄ composites

Xiao-Juan Li, Ming-Yu Qi, Jing-Yu Li, Chang-Long Tan, Zi-Rong Tang(), Yi-Jun Xu()

College of Chemistry, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou 350116, Fujian, China

Received:2023-04-23 Accepted:2023-06-29 Online:2023-08-18 Published:2023-09-11
Contact: *E-mail: zrtang@fzu.edu.cn (Z.-R. Tang), yjxu@fzu.edu.cn (Y.-J. Xu).
Supported by:
Natural Science Foundation of China(22172030);Natural Science Foundation of China(22072023);Natural Science Foundation of China(21872029);Natural Science Foundation of China(21173045);Natural Science Foundation of China(U1463204);Program for Leading Talents of Fujian Universities;Program for National Science and Technology Innovation Leading Talents(00387072);Natural Science Foundation of Fujian Province(2017J07002);Natural Science Foundation of Fujian Province(019J01631);1st Program of Fujian Province for Top Creative Young Talents

摘要/Abstract

摘要：

二硫化物及其衍生物是生物、医药和工业合成的重要中间体,不仅在蛋白质功能化和药物传递系统中发挥着重要作用,而且在橡胶硫化剂、农药和抗氧化剂的生产中广泛应用.在传统合成策略中,有毒或昂贵的试剂通常被用于硫醇的偶联,且该过程存在反应条件苛刻、选择性低和反应时间长等问题.相比之下,光催化技术能够通过S−S偶联,将硫醇选择性地转化为二硫化物同时产氢,构建一种由光催化析氢和选择性有机合成相结合的光氧化还原体系.该双功能光催化反应体系能够充分利用光生电子和空穴的能量,同时获得绿色的清洁燃料和高价值的精细化学品,从而满足经济和社会可持续发展的目标.
本文采用简便的水热法和原位沉积法成功合成了PdS助催化剂修饰的ZnIn₂S₄复合光催化剂.在可见光照射下,二元PdS-ZnIn₂S₄复合材料可以高效地催化硫醇进行选择性脱氢偶联,充分利用高能电子和空穴,同时获得清洁的氢能源以及增值的二硫化物.研究表明,PdS作为一种高效的氧化型助催化剂,不仅可以有效地从ZnIn₂S₄半导体中捕获光生空穴,促进光生载流子的分离和转移,而且能作为硫醇氧化的活性反应位点,从而显著提高ZnIn₂S₄的光催化性能.3%PdS-ZnIn₂S₄复合材料具备最佳的光催化活性,其双(4-甲氧基苯基)二硫化物和氢气的产量分别是ZnIn₂S₄的8.4和10.7倍.此外,二硫化物在该光催化反应过程中表现出优异的选择性(> 99.0%).循环活性实验以及催化反应前后的X射线光电子能谱结果表明,二元PdS-ZnIn₂S₄复合材料具有良好的光催化稳定性.PdS-ZnIn₂S₄可以有效地催化多种具有不同取代基的硫醇的脱氢偶联,生成相应的S−S目标产物,说明了二元PdS-ZnIn₂S₄复合材料在光催化硫醇转化中的普适性.此外,原位傅里叶变换红外光谱揭示了反应物在催化剂表面的动态变化.通过电子顺磁共振光谱技术对反应过程中的自由基中间体进行原位监测,确认了硫中心自由基是硫醇氧化偶联过程中关键的自由基中间体.综上,本文为以绿色可持续的方式同时获得清洁太阳能燃料和具有高附加值的化学品提供了参考.

关键词: 氧化型助催化剂, 硫铟锌, 光氧化还原反应, 二硫化物合成, 析氢

Abstract:

The simultaneous utilization of photogenerated electrons and holes in one cooperative photoredox system for the dehydrocoupling of thiols into value-added disulfides and clean hydrogen (H₂) fuel meets the development criteria of green chemistry. Herein, we report the synthesis and application of cocatalyst PdS decorated ZnIn₂S₄ (PdS-ZIS) composites for photocatalytic coupling of thiols into disulfides and H₂ evolution under visible light irradiation. The superior photocatalytic performance over PdS-ZIS composites compared with blank ZIS is attributed to the function of PdS as oxidation cocatalyst, which dramatically promotes the separation and transfer of photogenerated charge carriers due to its excellent hole trapping ability. In-situ Fourier transform infrared spectra reveal the dynamic variation of reactants on the catalyst surface. Electron paramagnetic resonance technology confirms that sulfur-centered radicals are the key reaction intermediates in this coupling process. Moreover, the application of PdS-ZIS composites to the dehydrocoupling of various thiols with different substituent groups into the corresponding S-S coupling products has been demonstrated to be practicable. This work is expected to offer insights into the rational design of cocatalyst-decorated semiconductor photocatalysts with efficient utilization of photogenerated electrons and holes for the co-production of high-value chemicals and clean H₂ energy in a cooperative photoredox catalysis process.

Key words: Oxidation cocatalyst, ZnIn2S4, Photoredox reaction, Disulfide synthesis, Hydrogen evolution

李晓娟, 祁明雨, 李婧宇, 谭昌龙, 唐紫蓉, 徐艺军. PdS修饰的ZnIn₂S₄复合材料用于可见光催化硫醇偶联制备二硫化物同时产氢[J]. 催化学报, 2023, 51: 55-65.

Xiao-Juan Li, Ming-Yu Qi, Jing-Yu Li, Chang-Long Tan, Zi-Rong Tang, Yi-Jun Xu. Visible light-driven dehydrocoupling of thiols to disulfides and H₂ evolution over PdS-decorated ZnIn₂S₄ composites[J]. Chinese Journal of Catalysis, 2023, 51: 55-65.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(23)64481-X

https://www.cjcatal.com/CN/Y2023/V51/I8/55

图/表 8

Scheme 1. Comparison between previous works and this work for the dehydrocoupling of thiols to disulfides.

Fig. 1. (a) Systematic illustration of the synthetic procedure of the PdS decorated ZIS composites. (b) SEM image of ZIS. SEM (c), TEM (d), HRTEM (e) and high angle annular dark field (HAADF)-scanning TEM images and the element mapping results (f) of PdS-ZIS.

Fig. 2. XPS spectra of Zn 2p (a), In 3d (b) and S 2p (c) of ZIS and PdS-ZIS. (d) Pd 3d of PdS-ZIS. XRD patterns (e) and DRS spectra (f) of ZIS and PdS-ZIS composites containing different weight ratios of PdS.

Fig. 3. (a) Graphical representation of the photocatalytic selective dehydrogenation coupling of 4-MTP into 4-MPD and H2 evolution. (b) Photocatalytic activities of blank ZIS and x%PdS-ZIS (x = 0.5, 1, 3, 5). (c) Time-yield plots over 3%PdS-ZIS. (d) DRS spectrum of 3%PdS-ZIS and AQY of 4-MPD under different monochromatic lights. (e) Recycle tests over 3%PdS-ZIS. Reaction conditions of photocatalytic activity tests and recycle tests: 10 mg catalysts, 0.1 mmol 4-MTP, 10 mL MeCN, visible light, irradiation for 8 h.

Table 1 Photocatalytic dehydrogenation coupling of thiols with different substituents into corresponding disulfides and H2 evolution a.

Entry	Substrate	Yield of disulfide^b (%)	Selectivity of disulfide^c (%)	Disulfide generation rate (μmol/g_ZIS/h)	H₂ production rate (μmol/g_ZIS/h)	Carbon balance^d (%)	e^-/h^{+ e}
1	4-NH₂C₆H₄SH	98.5	99.4	615.7	607.1	99.6	0.99
2	4-NO₂C₆H₄SH	97.3	99.7	608.2	582.3	100	0.96
3	4-CH₃C₆H₄SH	80.2	99.5	501.2	493.7	99.5	0.99
4	4-ClC₆H₄SH	59.8	99.6	373.5	353.7	100	0.95
5	4-(CH₃)₃CC₆H₄SH	54.4	99.5	339.7	334.5	99.5	0.98
6	4-CF₃C₆H₄SH	48.4	99.4	302.8	276.3	99.4	0.91
7	4-FC₆H₄SH	51.9	99.8	324.3	293.4	99.8	0.90
8	4-CH₃CH₂C₆H₄SH	52.8	99.1	330.3	327.1	99.2	0.99
9	CH₃CH₂SH	98.5	99.9	615.5	607.1	99.9	0.99
10	HOOCCH₂SH	96.0	99.8	600.3	594.7	99.8	0.99

Fig. 4. Transient photocurrent response plots (a), EIS Nyquist plots (b), polarization curves (c), electron lifetime (d), PL spectra (e) and TRPL decay spectra (f) over ZIS and 3%PdS-ZIS.

Fig. 5. (a) Controlled tests for the photocatalytic coupling of 4-MTP with H2 evolution over 3%PdS-ZIS. Reaction conditions: 10 mg catalysts, 10 mL MeCN, 0.1 mmol 4-MTP, 0.2 mmol quenchers, Ar atmosphere, visible light, 8 h. (b) In-situ FTIR spectra over 3%PdS-ZIS. (c) EPR spectra of blank ZIS and 3%PdS-ZIS using DMPO as the trapping agents (dark and light). (d) Quantitative analysis of EPR spectrum for 3%PdS-ZIS.

Fig. 6. (a) Schematic diagram of the internal electric field formed between ZIS and PdS. (b) Systematic illustration of the photoredox catalyzed mechanism for dehydrogenation coupling of 4-MTP into 4-MPD and H2 evolution over PdS-ZIS photocatalyst (λ > 420 nm).

参考文献

[1]	A. M. Almeida, R. Li, S. H. Gellman, J. Am. Chem. Soc., 2012, 134, 75-78.
[2]	D. Fass, C. Thorpe, Chem. Rev., 2018, 118, 1169-1198.
[3]	J.-H. Ryu, R. T. Chacko, S. Jiwpanich, S. Bickerton, R. P. Babu, S. Thayumanavan, J. Am. Chem. Soc., 2010, 132, 17227-17235.
[4]	K. Y. D. Tan, G. F. Teng, W. Y. Fan, Organometallics, 2011, 30, 4136-4143.
[5]	J. A. Yoon, J. Kamada, K. Koynov, J. Mohin, R. Nicolaÿ, Y. Zhang, A. C. Balazs, T. Kowalewski, K. Matyjaszewski, Macromolecules, 2011, 45, 142-149.
[6]	F. Hosseinpoor, H. Golchoubian, Catal. Lett., 2006, 111, 165-168.
[7]	B. Zeynizadeh, N. Iranpoor, J. Chin. Chem. Soc., 2003, 50, 849-852.
[8]	M.-H. Sun, M.-Y. Qi, Z.-R. Tang, Y.-J. Xu, Appl. Catal. B, 2023, 321, 122019.
[9]	H.-X. Xu, Z.-R. Zhao, Y. Patehebieke, Q.-Q. Chen, S.-G. Fu, S.-J. Chang, X.-X. Zhang, Z.-L. Zhang, X. Wang, Green Chem., 2021, 23, 1280-1285.
[10]	H. Xu, Y.-F. Zhang, X. Lang, Chin. Chem. Lett., 2020, 31, 1520-1524.
[11]	H. Xu, J.-L. Shi, S. Lyu, X. Lang, Chin. J. Catal., 2020, 41, 1468-1473.
[12]	C. Bottecchia, N. Erdmann, P. M. Tijssen, L. G. Milroy, L. Brunsveld, V. Hessel, T. Noel, ChemSusChem, 2016, 9, 1781-1785.
[13]	S. Shi, H. Li, Y. Zhang, Y. Shi, N. Zhang, T. Li, Y. Zhang, Q. Li, P. Duan, Y. Li, J. Mater. Chem. A, 2023, 11, 2726-2736.
[14]	M.-Y. Qi, M. Conte, M. Anpo, Z.-R. Tang, Y.-J. Xu, Chem. Rev., 2021, 121, 13051-13085.
[15]	M. Hao, X. Deng, L. Xu, Z. Li, Appl. Catal. B, 2019, 252, 18-23.
[16]	C.-L. Tan, M.-Y. Qi, Z.-R. Tang, Y.-J. Xu, Appl. Catal. B, 2021, 298, 120541.
[17]	F. Zhao, N. Zhang, H. Li, X. Zhang, Z. Luo, Y. Wang, Energy Environ. Mater., 2021, 5, 1229-1237.
[18]	J. Zhang, Z. Yu, Z. Gao, H. Ge, S. Zhao, C. Chen, S. Chen, X. Tong, M. Wang, Z. Zheng, Y. Qin, Angew. Chem. Int. Ed., 2017, 56, 816-820.
[19]	Y. Liu, S. Ding, Y. Shi, X. Liu, Z. Wu, Q. Jiang, T. Zhou, N. Liu, J. Hu, Appl. Catal. B, 2018, 234, 109-116.
[20]	Q. Sun, N. Wang, J. Yu, J. C. Yu, Adv. Mater., 2018, 30, 1804368.
[21]	X.-L. Li, G.-Q. Yang, S.-S. Li, N. Xiao, N. Li, Y.-Q. Gao, D. Lv, L. Ge, Chem. Eng. J., 2020, 379, 122350.
[22]	R. Zhang, X. Jia, Y. Li, X. Yu, Y. Xing, Int. J. Hydrogen Energy, 2022, 47, 25300-25308.
[23]	J. Yang, H. Yan, X. Wang, F. Wen, Z. Wang, D. Fan, J. Shi, C. Li, J. Catal., 2012, 290, 151-157.
[24]	K. Khan, X. Tao, Y. Zhao, B. Zeng, M. Shi, N. Ta, J. Li, X. Jin, R. Li, C. Li, J. Mater. Chem. A, 2019, 7, 15607-15614.
[25]	M. Wang, G. Zhang, Z. Guan, J. Yang, Q. Li, Small, 2021, 17, 2006952.
[26]	H. Yan, J. Yang, G. Ma, G. Wu, X. Zong, Z. Lei, J. Shi, C. Li, J. Catal., 2009, 266, 165-168.
[27]	Y. Zhu, T. Chen, S. Li, S. Shimada, L.B. Han, J. Am. Chem. Soc., 2016, 138, 5825-5828.
[28]	G. Schäfer, A. Merot, T. Fleischer, Org. Process Res. Dev., 2022, 26, 3373-3379.
[29]	T. Schlatzer, H. Schroder, M. Trobe, C. Lembacher-Fadum, S. Stangl, C. Schlogl, H. Weber, R. Breinbauer, Adv. Synth. Catal., 2020, 362, 331-336.
[30]	F. Chen, Y. Zhang, H. Huang, Chin. Chem. Lett., 2023, 34, 107523.
[31]	S. Meng, C. Chen, X. Gu, H. Wu, Q. Meng, J. Zhang, S. Chen, X. Fu, D. Liu, W. Lei, Appl. Catal. B, 2021, 285, 119789.
[32]	F. Wang, Y. Su, S. Min, Y. Li, Y. Lei, J. Hou, J. Solid State Chem., 2018, 260, 23-30.
[33]	Y. He, H. Rao, K. Song, J. Li, Y. Yu, Y. Lou, C. Li, Y. Han, Z. Shi, S. Feng, Adv. Funct. Mater., 2019, 29, 1905153.
[34]	F. Xing, Q. Liu, C. Huang, Solar RRL, 2019, 4, 1900483.
[35]	Z. Guan, Z. Xu, Q. Li, P. Wang, G. Li, J. Yang, Appl. Catal. B, 2018, 227, 512-518.
[36]	L. Zhang, J. Qiu, D. Dai, Y. Zhou, X. Liu, J. Yao, J. Cleaner Prod., 2022, 341, 130891.
[37]	S. Zhang, X. Liu, C. Liu, S. Luo, L. Wang, T. Cai, Y. Zeng, J. Yuan, W. Dong, Y. Pei, Y. Liu, ACS Nano, 2018, 12, 751-758.
[38]	M.-Y. Qi, M. Conte, Z.-R. Tang, Y.-J. Xu, ACS Nano, 2022, 16, 17444-17453.
[39]	M.-Y. Qi, Q. Lin, Z.-R. Tang, Y.-J. Xu, Appl. Catal. B, 2022, 307, 121158.
[40]	J.-H. Zheng, M.-Y. Qi, Z.-R. Tang, Y.-J. Xu, J. Mater. Chem. A, 2023, 11, 4013-4019.
[41]	J. Jin, Y. Cao, T. Feng, Y. Li, R. Wang, K. Zhao, W. Wang, B. Dong, L. Cao, Catal. Sci. Technol., 2021, 11, 2753-2761.
[42]	P. Wang, Z. Shen, Y. Xia, H. Wang, L. Zheng, W. Xi, S. Zhan, Adv. Funct. Mater., 2019, 29, 1807013.
[43]	G. Han, Y.-H. Jin, R. A. Burgess, N. E. Dickenson, X.-M. Cao, Y. Sun, J. Am. Chem. Soc., 2017, 139, 15584-15587.
[44]	G. Han, X. Liu, Z. Cao, Y. Sun, ACS Catal., 2020, 10, 9346-9355.
[45]	N. Luo, T. Montini, J. Zhang, P. Fornasiero, E. Fonda, T. Hou, W. Nie, J. Lu, J. Liu, M. Heggen, L. Lin, C. Ma, M. Wang, F. Fan, S. Jin, F. Wang, Nat. Energy, 2019, 4, 575-584.
[46]	Y. Zhang, N. Zhang, Z.-R. Tang, Y.-J. Xu, ACS Nano, 2012, 6, 9777-9789.
[47]	J. Wang, C. Hu, Y. Zhang, H. Huang, Chin. J. Catal., 2022, 43, 1277-1285.
[48]	T. Su, C. Men, L. Chen, B. Chu, X. Luo, H. Ji, J. Chen, Z. Qin, Adv. Sci., 2022, 9, 2103715.
[49]	F. Zhang, Y.-H. Li, M.-Y. Qi, Z.-R. Tang, Y.-J. Xu, Appl. Catal. B, 2020, 268, 118380.
[50]	Y.-H. Li, F. Zhang, Y. Chen, J.-Y. Li, Y.-J. Xu, Green Chem., 2020, 22, 163-169.
[51]	X. Chen, X. Zhang, Y.-H. Li, M.-Y. Qi, J.-Y. Li, Z.-R. Tang, Z. Zhou, Y.-J. Xu, Appl. Catal. B, 2021, 281, 119516.
[52]	Y.-S. Xie, N. Zhang, Z.-R. Tang, M. Anpo, Y.-J. Xu, Catal. Today, 2020, 340, 121-127.
[53]	M.-Y. Qi, Y.-H. Li, F. Zhang, Z.-R. Tang, Y. Xiong, Y.-J. Xu, ACS Catal., 2020, 10, 3194-3202.
[54]	Q. Liu, S. Wang, W. Mo, Y. Zheng, Y. Xu, G. Yang, S. Zhong, J. Ma, D. Liu, S. Bai, Small, 2022, 18, 2104681.
[55]	R. Shi, H. F. Ye, F. Liang, Z. Wang, K. Li, Y. Weng, Z. Lin, W. F. Fu, C. M. Che, Y. Chen, Adv. Mater., 2018, 30, 1705941.
[56]	Q. Lin, Y.-H. Li, M.-Y. Qi, J.-Y. Li, Z.-R. Tang, M. Anpo, Y. M. A. Yamada, Y.-J. Xu, Appl. Catal. B, 2020, 271, 118946.
[57]	Z. Zhang, Y. Huang, K. Liu, L. Guo, Q. Yuan, B. Dong, Adv. Mater., 2015, 27, 5906-5914.
[58]	L. Liu, M. Li, F. Chen, H. Huang, Small Struct., 2022, 4, 2200188.
[59]	M. Makowska, A. Hartikainen, T. Pellinen, Mater. Struct., 2017, 50, 189.
[60]	G. N. Bondarenko, S. M. Zenovich, Pharm. Chem. J., 2015, 48, 703-705.
[61]	Q. Guo, S. Y. Qian, R. P. Mason, J. Am. Soc. Mass Spectrom., 2003, 14, 862-871.
[62]	C. Du, Q. Zhang, Z. Lin, B. Yan, C. Xia, G. Yang, Appl. Catal. B, 2019, 248, 193-201.
[63]	F.-K. Shang, M.-Y. Qi, C.-L. Tan, Z.-R. Tang, Y.-J. Xu, ACS Phys. Chem. Au, 2022, 2, 216-224.
[64]	Z. Zhao, J. Bian, L. Zhao, H. Wu, S. Xu, L. Sun, Z. Li, Z. Zhang, L. Jing, Chin. J. Catal., 2022, 43, 1331-1340.

PdS修饰的ZnIn₂S₄复合材料用于可见光催化硫醇偶联制备二硫化物同时产氢

Visible light-driven dehydrocoupling of thiols to disulfides and H₂ evolution over PdS-decorated ZnIn₂S₄ composites

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 8

参考文献

相关文章 15

编辑推荐

Metrics

[1]	王潇涵, 田汉, 余旭, 陈立松, 崔香枝, 施剑林. 非晶相电催化剂在电解水领域的研究进展[J]. 催化学报, 2023, 51(8): 5-48.
[2]	韩策, 梅丙宝, 张庆华, 张慧敏, 姚鹏飞, 宋平, 宫雪, 崔培昕, 姜政, 谷林, 徐维林. 钒掺杂钨青铜内通道氨配位的钌单原子用于高效析氢反应[J]. 催化学报, 2023, 51(8): 80-89.
[3]	孙利娟, 王伟康, 路平, 刘芹芹, 王乐乐, 唐华. 纳米高熵合金实现光催化剂肖特基势垒的调控用于光催化制氢与苯甲醇氧化耦合反应[J]. 催化学报, 2023, 51(8): 90-100.
[4]	余治晗, 关晨, 岳晓阳, 向全军. 碳环渗入的结晶氮化碳S型同质结及其光催化析氢[J]. 催化学报, 2023, 50(7): 361-371.
[5]	陈斌, 蒋亚飞, 肖海, 李隽. 石墨炔负载的双金属单团簇催化剂用于碱性析氢反应[J]. 催化学报, 2023, 50(7): 306-313.
[6]	马方沛, 汤庆平, 席识博, 李国庆, 陈涛, 凌星辰, 吕忆农, 刘云鹏, 赵小龙, 周瑜, 王军. 嵌入铂单原子的苯并咪唑基共价有机框架实现高效可见光析氢[J]. 催化学报, 2023, 48(5): 137-149.
[7]	詹麒尼, 帅婷玉, 徐慧民, 黄陈金, 张志杰, 李高仁. 单原子催化剂的合成及其在电化学能量转换中的应用[J]. 催化学报, 2023, 47(4): 32-66.
[8]	Sue-Faye Ng, 陈星竹, Joel Jie Foo, 熊墨, Wee-Jun Ong. 2D氮化碳: 通过调节非金属硼掺杂C₃N₅阐明宽酸性及碱性pH范围的光催化析氢的反应机理[J]. 催化学报, 2023, 47(4): 150-160.
[9]	吴则星, 高玉肖, 王子璇, 肖卫平, 王新萍, 李彬, 李镇江, 刘晓斌, 马天翼, 王磊. 表面富集的超小铂纳米颗粒耦合缺陷磷化钴用于高效的电催化水分解和柔性锌空气电池[J]. 催化学报, 2023, 46(3): 36-47.
[10]	李卓根, 张伟斌, 朱陆军, 高健智, 石先进, 黄宇, 刘鹏, 朱刚强. 通过实验和理论验证Pt⁰/SrTiO_3‒_δ复合催化剂双反应路径促进CO₂还原[J]. 催化学报, 2023, 46(3): 113-124.
[11]	王妮, 张学鹏, 韩金秀, 雷海涛, 张清鑫, 张航, 张伟, 曹睿. 第二配位层磺酸根在电催化析氢反应中的作用[J]. 催化学报, 2023, 45(2): 88-94.
[12]	杨竣皓, 安露露, 王双, 张辰浩, 罗官宇, 陈应泉, 杨会颖, 王得丽. 层状双氢氧化物基电解水催化剂的缺陷工程调控策略[J]. 催化学报, 2023, 55(12): 116-136.
[13]	王其忧, 龚钰杰, 谭耀, 资鑫, Reza Abazari, 李红梅, 蔡超, 刘康, 傅俊伟, 陈善勇, 罗涛, 张世国, 李文章, 盛义发, 刘俊, 刘敏. 通过诱导局域电场和电子局域化协同碱性析氢[J]. 催化学报, 2023, 54(11): 229-237.
[14]	苏慧, 姜静, 宋少佳, 安博涵, 李宁, 高旸钦, 戈磊. 过渡金属硫化物相关电催化剂的设计与应用研究[J]. 催化学报, 2023, 44(1): 7-49.
[15]	白雪, 管景奇. 过渡金属碳氮化物在电催化领域的应用: 改性和杂化[J]. 催化学报, 2022, 43(8): 2057-2090.