空间相邻氧化还原位点与自旋极化在ZnIn2S4中的协同作用促进H2O2光合成

doi:10.1016/S1872-2067(26)65206-0

催化学报 ›› 2026, Vol. 91: 252-262.DOI: 10.1016/S1872-2067(26)65206-0

空间相邻氧化还原位点与自旋极化在ZnIn₂S₄中的协同作用促进H₂O₂光合成

李志奇^a, 关晨^a, 许凯强^b^,^*(), 夏伟^c, Dilshod D. Nematov^d, 向全军^a^,^*()

^a 电子科技大学电子薄膜与集成器件国家重点实验室, 四川成都 611731, 中国
^b 上海应用技术大学化学与环境工程学院, 上海 201418, 中国
^c 茅台学院资源与环境系, 贵州仁怀 564507, 中国
^d 塔吉克斯坦国家科学院物理技术研究所, 杜尚别, 塔吉克斯坦

收稿日期:2026-01-12 接受日期:2026-01-30 出版日期:2026-12-18 发布日期:2026-10-13
通讯作者: ^*电子信箱: xiangqj@uestc.edu.cn (向全军),
xukaiqiang24@sit.edu.cn (许凯强).
基金资助:
国家自然科学基金(22479020);国家自然科学基金(W2512051);国家自然科学基金(22272019);四川省科技计划(2026NSFSC0079);重庆市科学技术局(CSTB2022NSCQ-MSX0246)

Synergy of spatially adjacent redox sites and spin polarization in ZnIn₂S₄ for boosted H₂O₂ photosynthesis

Zhiqi Li^a, Chen Guan^a, Kaiqiang Xu^b^,^*(), Wei Xia^c, Dilshod D. Nematov^d, Quanjun Xiang^a^,^*()

^a State Key Laboratory of Electronic Thin Film and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 611731, Sichuan, China
^b School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China
^c Department of Resources and Environment, Moutai Institute, Renhuai 564507, Guizhou, China
^d S. U. Umarov Physical-Technical Institute of NAST, 734042 Dushanbe, Tajikistan

Received:2026-01-12 Accepted:2026-01-30 Online:2026-12-18 Published:2026-10-13
About author:First author contact:Author contributions
Zhiqi Li conceived the idea, designed the experiments, and wrote the original draft. Chen Guan has completed the tasks of writing, reviewing, and editing. Wei Xia reviewed the manuscript. Kaiqiang Xu and Dilshod D. Nematov reviewed and revised the manuscript. Quanjun Xiang supervised the work, reviewed and revised the manuscript.
Supported by:
National Natural Science Foundation of China(22479020);National Natural Science Foundation of China(W2512051);National Natural Science Foundation of China(22272019);Sichuan Science and Technology Program(2026NSFSC0079);Chongqing Science and Technology Bureau(CSTB2022NSCQ-MSX0246)

摘要/Abstract

摘要：

过氧化氢(H₂O₂)是一种多功能化学品, 广泛应用于消毒、化工及环境修复领域. 近年来, 通过光催化将H₂O和O₂转化为H₂O₂的反应被视为替代传统方法的环保策略. 此前, 大量研究致力于探讨光催化剂表面光诱导电子向O₂的转移机制. 然而, 过氧化氢光催化研究的最新进展日益凸显质子耦合电子转移(PCET)在提升催化效率中的关键作用. PCET对于驱动两电子氧还原路径生成H₂O₂至关重要. 然而, 在光催化H₂O₂生产过程中, 如何耦合相邻的水氧化反应与氧还原反应位点以放大PCET效应, 仍是一个巨大挑战.
解决这一挑战需要克服空间相邻氧化还原位点难以避免的载流子复合问题. 本文成功将钴和硫空位引入ZnIn₂S₄光催化剂中. 其中, 钴的引入诱导了自旋极化, 显著抑制了电荷载流子的复合; 而硫空位则在金属位点创造了不饱和配位环境, 促进了反应物的吸附, 从而形成了空间相邻的氧化还原位点. 我们提出一种策略, 通过同时掺入钴掺杂剂和硫空位, 在ZnIn₂S₄中实现自旋极化与空间相邻氧化还原位点的耦合. 硫空位的引入导致不饱和位点的生成, 钴位点通过积累电子活化O₂发生氧还原反应, 而相邻的硫空位捕获光生空穴驱动水氧化反应. 钴位点与硫空位在空间上的邻近排列, 在动力学层面实现了高效质子转移, 从而促进PCET过程. 此外, 钴掺杂诱导的显著电子自旋极化有效抑制了载流子复合. 扩展X-射线吸收精细结构与密度泛函理论模拟结果揭示了Co-Vs双位点的形成. 原位傅里叶变换红外光谱和拉曼光谱证实了PCET过程得到促进. 最终, 该催化剂实现了215.4 μmol g^-1 h^-1的H₂O₂产率, 相较于纯ZnIn₂S₄ (59.6 μmol g^-1 h^-1)提高了3.6倍.
综上, 本工作提出一种协同调控空间相邻氧化还原位点与电子自旋极化的策略, 通过这种协同展示了质子转移与载流子分离的双促进作用, 阐明了反应机制, 为实现高效光催化合成H₂O₂提供了有效途径, 为后续相关反应的开发和应用提供参考.

关键词: 自旋极化, 质子耦合电子转移, 空间相邻的氧化还原位点, ZnIn₂S₄, 光催化H₂O₂生成

Abstract:

Proton-coupled electron transfer (PCET) is essential for driving the two-electron oxygen reduction pathway toward H₂O₂ production. However, the coupled integration of the adjacent water oxidation reaction and oxygen reduction reaction sites to amplify PCET presents a considerable challenge in the photocatalytic H₂O₂production. Addressing this challenge requires overcoming the inevitable carrier recombination problem at spatially adjacent redox sites. In this work, we incorporated Co and sulfur vacancies into ZnIn₂S₄ as a photocatalyst, in which the incorporation of Co induced spin polarization, significantly inhibiting the recombination of charge carriers. While the sulfur vacancies created an unsaturated coordination environment at the metal sites to promote the adsorption of reactants, forming the spatially adjacent redox sites. Extended X-ray absorption fine structure results and density functional theory simulations revealed the formation of Co-Vs dual sites. In-situ Fourier transform infrared and Raman spectroscopy confirmed the promoted PCET. This resulted in a 3.6-fold increase (215.4 μmol g^-1 h^-1) in H₂O₂ yield compared to pure ZIS (59.6 μmol g^-1 h^-1). This work exhibited a strategy for constructing spatially synergistic sites and manipulating the electronic spin polarization, providing an effective approach to enhance photocatalytic H₂O₂ production.

Key words: Spin polarization, Proton-coupled electron transfer, Spatially adjacent redox sites, ZnIn₂S₄, Photocatalytic H₂O₂ production

李志奇, 关晨, 许凯强, 夏伟, Dilshod D. Nematov, 向全军. 空间相邻氧化还原位点与自旋极化在ZnIn₂S₄中的协同作用促进H₂O₂光合成[J]. 催化学报, 2026, 91: 252-262.

Zhiqi Li, Chen Guan, Kaiqiang Xu, Wei Xia, Dilshod D. Nematov, Quanjun Xiang. Synergy of spatially adjacent redox sites and spin polarization in ZnIn₂S₄ for boosted H₂O₂ photosynthesis[J]. Chinese Journal of Catalysis, 2026, 91: 252-262.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(26)65206-0

https://www.cjcatal.com/CN/Y2026/V91/I12/252

图/表 6

Fig. 1. (a) Schematic diagram of Co-ZIS-Vs synthesis. TEM (b), HRTEM (c), SAED (d), and elemental mappings (e) of Co-ZIS-Vs. (f) XRD spectra of samples. (g) SEM image of Co-ZIS-Vs.

Fig. 2. (a) XPS spectrum of Co 2p for Co-ZIS-Vs. XPS spectra of Zn 2p (b) and S 2p (c) for Co-ZIS-Vs and ZIS-Vs. (d) Co K-edge XANES spectra of Co-ZIS-Vs along with those of CoO, CoS, and Co-foil as reference standards. (e) Fourier transformed EXAFS spectra of Co-ZIS-Vs, CoO, CoS, and Co-foil. (f) EXAFS curve-fitting at Co K-edge of Co-ZIS-Vs in k space. (g) EXAFS curve-fitting at Co K-edge of Co-ZIS-Vs in R-space. (h) Wavelet transform contour plots of Co K-edge at R space

Fig. 3. (a) Photocatalytic H2O2 production rates of ZIS, ZIS-Vs, Co-ZIS, and Co-ZIS-Vs in O2-saturated pure water. (b) Photocatalytic H2O2 production rate of Cox-ZIS-Vs under visible light for 1 h, x indicates the molar amount of Co doping in the synthesis of Co-ZIS-Vs samples (0.01, 0.05, 0.1, 0.15, and 0.2 mmol). (c) Photocatalytic H2O2 production over Co-ZIS-Vs in air, N2 and N2+NaIO3. (d) Recycling test of Co-ZIS-Vs for photocatalytic H2O2 production. Reaction condition: 20 mg of catalyst, 30 mL of H2O, 2 h. (e) Photocatalytic AQY of Co-ZIS-Vs. (f) Band structures of Co-ZIS-Vs and ZIS.

Fig. 4. Calculated total DOS of Co-ZIS-Vs (a) and ZIS (b). (c) The spin-resolved PDOS of Co-ZIS-Vs. (d) The EPR spectroscopy of Co-ZIS-Vs, ZIS-Vs, and ZIS. TRPL decay spectra (e) and the steady-state PL (f) for Co-ZIS-Vs and ZIS. (g) Schematic illustration of the mechanism for spin polarization inhibiting photogenerated carrier recombination.

Fig. 5. In-situ Zn 2p (a), S 2p (b), and Co 2p (c) XPS spectra of Co-ZIS-Vs. In-situ FTIR spectra for photocatalytic H2O2 production of Co-ZIS-Vs (d) and ZIS (e). (f) Formation energy of the key *OOH intermediate on Co-ZIS-Vs and ZIS. (g) In-situ Raman spectra for photocatalytic H2O2 production of Co-ZIS-Vs.

Fig. 6. (a) Differential charge density and Bader charge transfer between different structures and O2 (yellow and cyan iso-surfaces represent regions of electron accumulation and depletion, respectively). (b) The bond length of O2 molecule on ZIS and Co-ZIS-Vs. (c) PDOS for Co-3d and O-2p on Co-ZIS-Vs. (d) The Gibbs free energy (ΔG) diagram for H2O2 production on ZIS and Co-ZIS-Vs. (e) The COHP of ZIS and Co-ZIS-Vs. (f) Photocatalytic H2O2 production mechanism diagram of Co-ZIS-Vs.

参考文献

[1]	X. Zhang, Y. Wan, Y. Wen, Y. Zhu, H. Liu, J. Qiu, Z. Zhu, Z. Sun, X. Gao, S. Bai, Y. Zhang, L. Zhang, X. Yan, J. Zhang, Y. Liu, S. Li, L.-D. Zhao, Nat. Catal., 2025, 8, 465-475.
[2]	W. Zhong, A. Meng, Y. Su, H. Yu, P. Han, J. Yu, Angew. Chem. Int. Ed., 2025, 64, e202425038.
[3]	X. Ruan, M. Xu, C. Ding, J. Leng, G. Fang, D. Meng, W. Zhang, Z. Jiang, S. K. Ravi, X. Cui, J. Yu, Adv. Energy Mater., 2025, 15, 2405478.
[4]	Y. Zhang, C. Pan, G. Bian, J. Xu, Y. Dong, Y. Zhang, Y. Lou, W. Liu, Y. Zhu, Nat. Energy, 2023, 8, 361-371.
[5]	L. Zhang, J. Zhang, J. Yu, Chem, 2026, 12, 102719.
[6]	Y. Bian, Z. Wang, M. Du, K. Dai, J. Yu, L. Zhang, Adv. Funct. Mater., 2026, 36, e19493.
[7]	X. Ruan, C. Ding, J. Leng, D. Jiao, X. Zhang, M. Xu, D. Meng, X. Cui, Z. Zheng, Y. Zhu, S. K. Ravi, Adv. Mater., 2025, 37, e11422.
[8]	Y. Ma, S. Wang, Y. Zhang, B. Cheng, L. Zhang, J. Materiomics, 2025, 11, 100978.
[9]	M. Sayed, H. Li, C. Bie, Acta Phys.-Chim. Sin., 2025, 41, 100117.
[10]	W. Zhang, G. Liu, Chin. J. Catal., 2024, 66, 76-109.
[11]	H. Peng, H. Yang, J. Han, X. Liu, D. Su, T. Yang, S. Liu, C.-W. Pao, Z. Hu, Q. Zhang, Y. Xu, H. Geng, X. Huang, J. Am. Chem. Soc., 2023, 145, 27757-27766.
[12]	X. Li, Z. Wang, Acta Phys.-Chim. Sin., 2025, 41, 100080.
[13]	Z. Li, Z. Yu, C. Guan, K. Xu, Q. Xiang, J. Materiomics, 2025, 11, 100982.
[14]	C. Wu, F. Chu, Y. Hao, X. Li, X. Jia, Y. Sun, J. Gu, P. Jia, A. Wang, J. Jiang, Chin. J. Catal., 2025, 74, 329-340.
[15]	B. Liu, J. Zhang, H. Li, B. Cheng, C. Bie, Acta Phys.-Chim. Sin., 2025, 41, 100121.
[16]	Y. Zhang, J. Qiu, B. Zhu, G. Sun, B. Cheng, L. Wang, Chin. J. Catal., 2024, 57, 143-153.
[17]	Y. Teng, X.-M. Zhang, R.-L. Zhu, S. Chen, M.-Y. Xie, K. Wu, Q.-P. Tian, X.-Y. Wang, Z. Wu, J.-L. Ma, L. Sun, D.-B. Kuang, Angew. Chem. Int. Ed., 2025, 64, e202516296.
[18]	Z. Jiang, J. Zhang, B. Cheng, Y. Zhang, J. Yu, L. Zhang, Small, 2025, 21, 2409079.
[19]	J. Zhou, Y. Mu, M. Qiao, M. Zhang, S. Yuan, M. Zhang, T. Lu, Angew. Chem. Int. Ed., 2025, 64, e202506963.
[20]	Y. Yang, X. Zhou, M. Gu, B. Cheng, Z. Wu, J. Zhang, Acta Phys.-Chim. Sin., 2025, 41, 100064.
[21]	X. Zhang, D. Gao, B. Zhu, B. Cheng, J. Yu, H. Yu, Nat. Commun., 2024, 15, 3212.
[22]	C. Jiang, C. Yuan, K. Xu, X. Zhou, C. Bie, J. Mater. Sci. Technol., 2025, 231, 36-44.
[23]	M. Li, X. Li, J. B. Ghasemi, Chin. J. Catal., 2025, 73, 12-15.
[24]	Z. Yu, D. Zhang, C. Ai, J. Zhang, Q. Xiang, Chin. J. Catal., 2024, 67, 71-81.
[25]	L. Li, Q. Bu, T. Lang, R. Zhang, Y. Pang, Y. Zhang, Y. Lin, D. Wang, T. Xie, D. Wang, Angew. Chem. Int. Ed., 2025, 64, e202501357.
[26]	D. Chu, C. Xing, D. Sun, S. Li, L. Ling, Adv. Funct. Mater., 2026, 36, e16500.
[27]	R. Zhang, H. Xu, Z. Huang, J. Zhang, L. Liu, Z. Ma, Z. Zhang, K. Wang, P. Liu, H. Liu, X. Zheng, Adv. Funct. Mater., 2025, 35, 2420504.
[28]	M. Li, S. Wu, D. Liu, Z. Ye, L. Wang, M. Kan, Z. Ye, M. Khan, J. Zhang, J. Am. Chem. Soc., 2024, 146, 15538-15548.
[29]	F. Xu, L. Zheng, J. Zhang, Y. He, H. Cao, X. Zheng, H. García, J. Yu, Nat. Catal., 2026, 9, 73-86.
[30]	H. Du, Y. Fu, R. Shi, Z. Cao, S. Zhang, K. Liu, J. Wang, B. Jiang, H. Li, Angew. Chem. Int. Ed., 2026, 65, e20354.
[31]	C. Cheng, J. Yu, D. Xu, L. Wang, G. Liang, L. Zhang, M. Jaroniec, Nat. Commun., 2024, 15, 1313.
[32]	M. Li, S. Wu, D. Liu, Z. Ye, C. He, J. Wang, X. Gu, Z. Zhang, H. Li, J. Zhang, ACS Catal., 2024, 14, 14098-14109.
[33]	Y. Li, X. Ma, J. Bai, F. Si, W. Zhang, T. Hou, Y. Li, Angew. Chem. Int. Ed., 2025, 64, e202512876.
[34]	K. Sun, Y. Huang, Q. Wang, W. Zhao, X. Zheng, J. Jiang, H.-L. Jiang, J. Am. Chem. Soc., 2024, 146, 3241-3249.
[35]	K. Meng, J. Zhang, B. Zhu, C. Jiang, H. García, J. Yu, Adv. Mater., 2025, 37, 2505088.
[36]	Z. Jiang, K. Tong, Z. Li, H. Tao, M. Zhu, Angew. Chem. Int. Ed., 2025, 64, e202500791.
[37]	H. Chi, Y. Leng, C. Ding, T. Li, Y. Zhang, J. Yuan, W. Tu, W. Gao, Y. Yao, X. Zhu, Y. Zhou, Z. Zou, Angew. Chem. Int. Ed., 2025, 64, e202425630.
[38]	Z. Liu, W. Gao, L. Liu, Y. Gao, C. Zhang, L. Chen, F. Lv, J. Xi, T. Du, L. Luo, J. Zhuo, W. Zhang, Y. Ji, Y. Shen, W. Liu, J. Wang, M. Luo, S. Guo, Nat. Commun., 2025, 16, 197.
[39]	C.-C. Lin, T.-R. Liu, S.-R. Lin, K. M. Boopathi, C.-H. Chiang, W.-Y. Tzeng, W. C. Chien, H.-S. Hsu, C.-W. Luo, H.-Y. Tsai, H.-A. Chen, P.-C. Kuo, J. Shiue, J.-W. Chiou, W.-F. Pong, C.-C. Chen, C.-W. Chen, J. Am. Chem. Soc., 2022, 144, 15718-15726.
[40]	Y. Su, Z. Wei, Y. Lian, Q. Mu, W. Pan, D. Song, Y. Qin, W. Hua, J. Cheng, Z. Deng, Y. Peng, Appl. Catal. B, 2023, 334, 122827.
[41]	J. Zhang, X. Tian, M. Liu, H. Guo, J. Zhou, Q. Fang, Z. Liu, Q. Wu, J. Lou, J. Am. Chem. Soc., 2019, 141, 19269-19275.
[42]	X. Tan, S. Si, D. Xiao, X. Bao, K. Song, Z. Wang, Y. Liu, Z. Zheng, P. Wang, Y. Dai, B. Huang, H. Cheng, ACS Catal., 2023, 13, 14395-14403.
[43]	B. Shao, T. Liu, D. Li, L. Meng, J. Wang, W. Zhai, L. Li, Adv. Mater., 2025, 37, 2504135.
[44]	Z. Qi, J. Chen, Q. Li, N. Wang, S. A. C. Carabineiro, K. Lv, Small, 2023, 19, 2303318.
[45]	X. Wang, X. Wang, J. Huang, S. Li, A. Meng, Z. Li, Nat. Commun., 2021, 12, 4112.
[46]	Q. Xu, J. Han, F. Tian, X. Zhao, J. Rong, J. Zhang, P. She, J.-S. Qin, H. Rao, J. Am. Chem. Soc., 2025, 147, 10587-10597.
[47]	G. Tang, J. Zhang, C. Bie, X. Zheng, C. Jiang, J. Yu, Adv. Mater., 2025, 37, e14576.
[48]	Y. Liu, Y. Liu, Z. Yao, Z. Yu, H. Zhu, C. Xing, Y. Wang, X. Tan, Y. Huang, Y. Hou, S. Wang, Appl. Catal. B, 2025, 371, 125275.
[49]	C. Li, Z. Sun, J. Song, B. Tang, P. Ma, R. Zhang, L. Lu, K. Zheng, Angew. Chem. Int. Ed., 2025, 64, e202514661.
[50]	X. Zhou, S. Yang, X. Wang, Z. Wu, Y. Huo, J. Zhang, J. Mater. Sci. Technol., 2025, 234, 60-70.
[51]	W. Yu, Chin. J. Catal., 2025, 73, 8-11.
[52]	X. Zhou, C. Ai, X. Wang, Z. Wu, J. Zhang, J. Materiomics, 2025, 11, 100974.
[53]	C. Zhu, L. Lu, Q. Fang, S. Song, B. Chen, Y. Shen, Adv. Funct. Mater., 2023, 33, 2210905.
[54]	M. Guo, A. Talebian-Kiakalaieh, E. M. Hashem, B. Xia, J. Ran, S.-Z. Qiao, Adv. Funct. Mater., 2024, 34, 2406356.
[55]	C. Guan, X. Yue, Y. Liao, Q. Xiang, Angew. Chem. Int. Ed., 2025, 64, e202415538.
[56]	J. Li, Q. Pei, R. Wang, Y. Zhou, Z. Zhang, Q. Cao, D. Wang, W. Mi, Y. Du, ACS Nano, 2018, 12, 3351-3359.
[57]	M. Ai, L. Pan, C. Shi, Z.-F. Huang, X. Zhang, W. Mi, J.-J. Zou, Nat. Commun., 2023, 14, 4562.
[58]	L. Wang, B. Cheng, L. Zhang, J. Yu, Small, 2021, 17, 2103447.
[59]	Y. Wang, H. Zhao, P. Li, J. Zhang, X. Sun, R. Zhang, Y. Guo, Y. Dong, Y. Zhu, Chem. Eng. J., 2024, 491, 151825.
[60]	M. Xu, X. Ruan, J. Guo, C. Ding, D. Jiao, D. Meng, G. Fang, J. Leng, K. Ba, T. Xie, W. Zhang, S. K. Ravi, X. Cui, Nano Lett., 2025, 25, 13315-13325.
[61]	B. Liu, X. Zhou, H. Ma, X. Hu, R. Fang, W. Xu, F. Dong, ACS Catal., 2025, 15, 17715-17725.
[62]	Y. Wu, Q. Yuan, Y. Zhao, K. Sun, H. Sun, K. Wang, S. Hu, G. I. N. Waterhouse, J. Wu, Z. Wang, J. Jiang, M. Fan, J. Am. Chem. Soc., 2025, 147, 25295-25305.
[63]	J. Qiu, C. Cheng, H. García, G. Liang, B. Zhu, L. Zhang, J. Yu, Angew. Chem. Int. Ed., 2025, 64, e202515898.
[64]	F. Chen, G. Cao, Q. Liu, Y. Duan, W. Li, Z. Shen, Angew. Chem. Int. Ed., 2025, 64, e202518232.
[65]	X. Wang, K. Qi, K. Xu, Chin. J. Catal., 2025, 70, 1-4.
[66]	K. Zhang, L. Tian, J. Yang, F. Wu, L. Wang, H. Tang, Z. Liu, Angew. Chem. Int. Ed., 2024, 63, e202317816.
[67]	D. Jiao, C. Ding, M. Xu, X. Ruan, S. K. Ravi, X. Cui, Adv. Funct. Mater., 2025, 35, 2416753.
[68]	Y. Luo, B. Zhang, C. Liu, D. Xia, X. Ou, Y. Cai, Y. Zhou, J. Jiang, B. Han, Angew. Chem. Int. Ed., 2023, 62, e202305355.
[69]	L. Wang, J. Zhao, J. Mater. Sci. Technol., 2026, 241, 18-20.

空间相邻氧化还原位点与自旋极化在ZnIn₂S₄中的协同作用促进H₂O₂光合成

Synergy of spatially adjacent redox sites and spin polarization in ZnIn₂S₄ for boosted H₂O₂ photosynthesis

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 6

参考文献

相关文章 15

编辑推荐

Metrics

[1]	孙冉, 张雨琦, 侯琨格, 谭钰杰, 刘新刚, 侯剑源, 赵玮璇, Andrew E. H. Wheatley, 张仁熙. 共价有机框架中氢键的构筑: 加速质子耦合电子转移以提升光催化合成过氧化氢性能[J]. 催化学报, 2026, 84(5): 274-287.
[2]	门亚娜, 矫宇州, 郑妍星, 王晓晏, 陈胜利, 李朋. 质子型离子液体调控分子铁催化剂氧还原活性的pH依赖性及其电化学界面起源[J]. 催化学报, 2026, 80(1): 258-269.
[3]	王少单, 杨恒, 薛丽君, 张建军, 欧阳述昕, 温丽丽. 金属掺杂ZnIn₂S₄/TpPa-1 S型异质结: 通过调控氢吸附/脱附和内建电场促进双功能光催化[J]. 催化学报, 2026, 80(1): 159-173.
[4]	张波, 肖如, 刘利媛, 刘晓斌, 邓英, 吕清良, 吴则星, 杜云梅, 黎艳艳, 肖振宇, 王磊. 氯腐蚀策略: 分钟级构筑氯功能化Ni/Fe-LDH, 以提升抗氯OER性能[J]. 催化学报, 2025, 70(3): 388-398.
[5]	张亮, 芮家梁, 李依倩, 杨智智, 久冨木志郎, 王军虎, 张博凡. Co纳米颗粒调控Co-N的自旋极化驱动活化路径转化实现污染物高效氧化[J]. 催化学报, 2025, 77(10): 184-198.
[6]	张宝龙, 刘方璇, 孙彬, 高婷婷, 周国伟. ZnIn₂S₄修饰TiO₂的分级S型异质结用于促进光催化析氢[J]. 催化学报, 2024, 59(4): 334-345.
[7]	谷苗莉, 杨祎, 程蓓, 张留洋, 肖鹏, 陈涛. 利用电荷分离调控S型异质结光催化氧化产物选择性[J]. 催化学报, 2024, 59(4): 185-194.
[8]	顾宇, 王磊, 徐柏庆, 施慧. 金属-水界面催化的分子机制: 加氢与氧化反应[J]. 催化学报, 2023, 54(11): 1-55.
[9]	李婧宇, 祁明雨, 徐艺军. 超薄Ni掺杂ZnIn₂S₄纳米片用于光催化醇裂解同时制备C-C耦合产物及氢气[J]. 催化学报, 2022, 43(4): 1084-1091.
[10]	李金懋, 吴聪聪, 李矜, 董兵海, 赵丽, 王世敏. 1D/2D TiO₂/ZnIn₂S₄ S型异质结光催化剂及其高效制氢性能[J]. 催化学报, 2022, 43(2): 339-349.
[11]	王乐乐, 杨涛, 彭李杰, 张琪琪, 佘希林, 唐华, 刘芹芹. 2D/2D/2D三明治结构ZnIn₂S₄/g-C₃N₄/Ti₃C₂ Mxene S型异质结-肖特基结双通道电荷转移路径促进的光催化析氢[J]. 催化学报, 2022, 43(10): 2720-2731.
[12]	赵梦雨, 刘森, 陈代梅, 张苏舒, Sónia A. C. Carabineiro, 吕康乐. ZnIn₂S₄纳米片与WO₃纳米棒构建3D结构的S型异质结用于可见光光催化分解水产氢[J]. 催化学报, 2022, 43(10): 2615-2624.
[13]	曾辉炎, 曾衍铨, 漆俊, 顾龙, 洪恩纳, 司锐, 杨纯臻. 析氧反应中催化剂-电解质界面的质子动力学研究[J]. 催化学报, 2022, 43(1): 139-147.
[14]	王星林, 李媛媛, 李朝晖. Ir₂S₃/ZnIn₂S₄催化下可见光诱导发生的烯烃/炔烃的高效硫氢化反应: Ir₂S₃的作用[J]. 催化学报, 2021, 42(3): 409-416.
[15]	祝凯, 欧阳杰, 曾黔, 孟苏刚, 滕伟, 宋艳华, 唐盛, 崔言娟. ZnIn₂S₄@CNO多级纳米片用于光催化分解水制氢和还原CO₂[J]. 催化学报, 2020, 41(3): 454-463.