氯腐蚀策略: 分钟级构筑氯功能化Ni/Fe-LDH, 以提升抗氯OER性能

doi:10.1016/S1872-2067(24)60215-9

催化学报 ›› 2025, Vol. 70: 388-398.DOI: 10.1016/S1872-2067(24)60215-9

氯腐蚀策略: 分钟级构筑氯功能化Ni/Fe-LDH, 以提升抗氯OER性能

张波^a, 肖如^a, 刘利媛^a, 刘晓斌^b, 邓英^a^,^*(), 吕清良^b, 吴则星^a, 杜云梅^b, 黎艳艳^a^,^c, 肖振宇^a^,^*(), 王磊^a^,^*()

^a青岛科技大学化学与分子工程学院, 生态化工教育部重点实验室, 生态化工与绿色制造国际科技合作基地, 山东青岛 266042
^b青岛科技大学环境与安全工程学院, 山东省海洋环境腐蚀与安全防护工程技术研究中心, 山东青岛 266042
^c中国电动汽车百人会山东氢谷新能源技术研究院, 山东氢研产业发展有限公司, 山东济南 251401

收稿日期:2024-11-01 接受日期:2024-12-09 出版日期:2025-03-18 发布日期:2025-03-20
通讯作者: * 电子信箱: dengyingchem@163.com (邓英),inorgxiaozhenyu@163.com (肖振宇),inorchemwl@126.com (王磊).
基金资助:
国家自然科学基金(52272222);国家自然科学基金(52072197);国家自然科学基金(52372205);山东省自然科学基金(ZR2023MB142);山东省高等学校青年创新科技支持计划(2022KJ308);山东省高等学校青年创新科技支持计划(2019KJC004);青岛市博士后研究人员应用研究项目(QDBSH20230102046);山东省博士后创新人才支持计划(SDBX2022025);中国博士后科学基金(2023M731858);中国博士后科学基金(2024T170451);泰山学者青年人才计划(tsqn201909114)

Electrochemistry assisted chlorine corrosion strategy: The minute-level fabrication of lattice Cl^- functioned high spin-polarized Ni/Fe-LDH array for enhanced anti-Cl^- OER performance

Bo Zhang^a, Ru Xiao^a, Liyuan Liu^a, Xiaobin Liu^b, Ying Deng^a^,^*(), Qingliang Lv^b, Zexing Wu^a, Yunmei Du^b, Yanyan Li^a^,^c, Zhenyu Xiao^a^,^*(), Lei Wang^a^,^*()

^aKey Laboratory of Eco-chemical Engineering, Ministry of Education, International Science and Technology Cooperation Base of Eco-chemical Engineering and Green Manufacturing, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, Shandong, China
^bShandong Engineering Research Center for Marine Environment Corrosion and Safety Protection, College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao 266042, Shandong, China
^cShandong Institute of Hydrogen Energy Technology, China EV100, Jinan 250117, Shandong, China

Received:2024-11-01 Accepted:2024-12-09 Online:2025-03-18 Published:2025-03-20
Contact: * E-mail:dengyingchem@163.com (Y. Deng),inorgxiaozhenyu@163.com (Z. Xiao),inorchemwl@126.com (L. Wang).
Supported by:
National Natural Science Foundation of China(52272222);National Natural Science Foundation of China(52072197);National Natural Science Foundation of China(52372205);Natural Science Foundation of Shandong Province, China(ZR2023MB142);Science and Technology Support Plan for Youth Innovation of Colleges and Universities in Shandong Province(2022KJ308);Science and Technology Support Plan for Youth Innovation of Colleges and Universities in Shandong Province(2019KJC004);Qingdao Postdoctoral Researcher Applied Research Project(QDBSH20230102046);Postdoctoral Innovative Talents Support Program of Shandong Province, China(SDBX2022025);China Postdoctoral Science Foundation(2023M731858);China Postdoctoral Science Foundation(2024T170451);Taishan Scholar Young Talent Program(tsqn201909114)

摘要/Abstract

摘要：

电化学水分解技术, 特别是利用可再生能源(如光伏电站、风力发电或潮汐能)驱动的电化学水分解, 被视为未来大规模生产“绿色”且低成本氢燃料的途径, 以有效应对日益严峻的能源危机和环境问题. 鉴于海水占地球总水量的97%, 几乎可视为无穷无尽的资源. 因此, 直接海水电解技术的发展已成为科学界的研究热点. 然而, 由于海水成分复杂(Cl^‒: ~0.55 mol L^‒1, Na⁺: ~0.48 mol L^‒1, Mg⁺: ~0.05 mol L^‒1等)以及存在竞争的阳极析氯反应(CER), 商业贵金属基催化剂(如RuO₂或IrO₂)的稳定性和大电流密度下的析氧反应(OER)性能仍不理想, 这阻碍了其工业化进程. 因此, 开发低成本、稳定且能在工业级安培电流下高效工作的海水分解催化剂, 成为该领域亟待解决的重大挑战.

本文提出了电化学辅助氯离子腐蚀策略, 并在镍铁泡沫上构建了具有增强活性和稳定性的晶格氯离子功能化Ni/Fe-LDH阵列(E-NF-LDH_Cl). 该策略不仅具有超快的合成速率(仅需数分钟), 还展现出较好的抗氯离子腐蚀性能, 这主要得益于晶格氯离子的同离子排斥效应. 此外, 将氯离子引入镍/铁氢氧化物中可以产生缺陷并调节Ni/Fe的自旋状态, 从而增强本征活性并暴露更多可获得的活性中心, 进而实现卓越的OER性能. 因此, 优化的E-NF-LDH_Cl在1 mol L^‒1 KOH中以355 mV的低OER过电位即可达到1 A cm^‒2的电流密度, 同时在1 mol L^‒1 KOH和1 mol L^‒1 KOH + 0.5 mol L^‒1 NaCl溶液中均能保持400 h的稳定性. 同时, 通过相同的方法以海水替代0.5 mol L^‒1 NaCl制备的E-NF-LDH_SW, 在1 mol L^‒1 KOH海水中达到1 A cm^‒2的OER电流密度, 仅需要384 mV过电位. 通过将E-NF-LDH_SW与商用Pt/C催化剂匹配, 构建了一个高效的电解槽(Pt-C/NFF||E-NF-LDH_SW), 在1 mol L^‒1 KOH海水电解质中仅需1.637 V即可达到100 mA cm^‒2的电流密度, 比商用两电极电解槽(Pt-C/NFF||RuO₂/NFF)低172 mV. 分子动力学模拟和实验证明了晶格氯离子的强同离子排斥效应可以排斥溶液中游离氯离子. 因此, E-NF-LDH_Cl电极的内亥姆霍兹平面区域几乎不存在氯离子. 此外, 引入的氯离子可以通过降低晶体场分裂能并诱导形成更多单电子, 来有效增强催化剂的本征活性. 电化学辅助氯离子腐蚀策略不仅提供了一种快速且低成本的合成方法, 还通过引入晶格氯降低了过电位并增强了抗氯离子稳定性, 为实现大规模海水电解工业化提供了一条途径.

综上所述, 电化学辅助氯腐蚀策略为开发高性能、抗氯离子的OER催化剂提供了新的思路. 未来, 将继续探索更多新策略与新结构, 以进一步提升催化剂的抗氯离子腐蚀性能和OER活性. 同时, E-NF-LDH_Cl中晶格氯对溶液中自由氯的排斥效应的深入分析, 将为设计更高效的催化剂提供坚实的理论基础.

关键词: 层状双氢氧化物, 析氧反应, 海水分解, 抗氯离子腐蚀, 高自旋极化

Abstract:

Although the intermittent energy-driven direct seawater splitting technology provides an unparalleled approach to achieving sustainable development, the severe corrosion via aggressive Cl^- severely affects the stability and efficiency of the anode catalyst and limits its industrial application. Herein, a lattice Cl^- functioned NiFe-LDH electrode (E-NF-LDH_Cl or E-NF-LDH_SW) is firstly constructed by a minute-level electrochemistry assisted chlorine corrosion strategy, which presents enhanced oxygen evolution reaction (OER) performance and excellent anti-Cl^- corrosion behavior for seawater splitting. The optimized E-NF-LDH_Cl and E-NF-LDH_SW deliver low OER overpotential of 355 and 384 mV to reach 1 A cm⁻² current density in the 1 mol L^-1 KOH and 1 mol L^-1 KOH seawater, respectively, as well as excellent stability of E-NF-LDH_Cl is maintained at 1 A cm^-2 for 400 h in the 1 mol L^-1 KOH and 1 mol L^-1 KOH + 0.5 mol L^-1 NaCl. MD (molecular dynamics) simulation and DFT (density functional theory) calculation confirmed that strong common-ion repulsion effect in IHP region repels free Cl^-, forming high spin polarization centers and more single electrons to enhance the intrinsic activity of OER.

Key words: Layered double hydroxides, Oxygen evolution reaction, Seawater splitting, Anti-Cl^- corrosion, High spin polarization

张波, 肖如, 刘利媛, 刘晓斌, 邓英, 吕清良, 吴则星, 杜云梅, 黎艳艳, 肖振宇, 王磊. 氯腐蚀策略: 分钟级构筑氯功能化Ni/Fe-LDH, 以提升抗氯OER性能[J]. 催化学报, 2025, 70: 388-398.

Bo Zhang, Ru Xiao, Liyuan Liu, Xiaobin Liu, Ying Deng, Qingliang Lv, Zexing Wu, Yunmei Du, Yanyan Li, Zhenyu Xiao, Lei Wang. Electrochemistry assisted chlorine corrosion strategy: The minute-level fabrication of lattice Cl^- functioned high spin-polarized Ni/Fe-LDH array for enhanced anti-Cl^- OER performance[J]. Chinese Journal of Catalysis, 2025, 70: 388-398.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(24)60215-9

https://www.cjcatal.com/CN/Y2025/V70/I3/388

图/表 5

Fig. 1. (a) Process diagram of preparing E-NF-LDHCl nanosheets using NFF as template. (b) Diagram of chloride ion corrosion during brine electrolysis. SEM (c), TEM (d) image, HRTEM (e) images, selected area atomic mass contrast distribution (f), TEM image and the corresponding mapping for Fe, Ni, O, Cl (g) of E-NF-LDHCl.

Fig. 2. (a) XRD patterns of E-NF-LDHCl powder and E-NF-LDHCl. (b) EPR spectra of NF-LDHCl and E-NF-LDHCl. Fe 2p (c), Cl 2p (d) and O 1s (e) orbital XPS spectra of NF-LDHCl and E-NF-LDHCl. (f) UPS valence band spectra of NF-LDHCl and E-NF-LDHCl.

Fig. 3. OER polarization curves (a), histograms reflecting η100, η1000, and Tafel slope values (b), Cdl curves of the OER (c) and ECSA values and TOF (d) of NFF, NF-LDHCl, E-NF-LDHOH and E-NF-LDHCl. (e,f) in situ electrochemical Raman spectroscopy of E-NF-LDHCl and E-NF-LDHOH in alkaline electrolyte. (g) CP curves of E-NF-LDHCl at 1 A galvanostatic current in different electrolytes. (h) Comparison of OER activities between E-NF-LDHCl in this work and some state-of-the-art Ni/Fe-based OER electrodes in alkaline media from previous reports under the same test conditions.

Fig. 4. (a) OER polarization curves of E-NF-LDHSW, E-NF-LDHOH, NF-LDHSW, RuO2/NFF and NFF. (b) Tafel slope of different samples. (c) Histograms reflecting η100, η1000, and Tafel slope values of the as-formed samples. (d) Comparison of the overpotential (η100) for OER between E-NF-LDHSW and other Ni/Fe-based OER electrodes 1 mol L-1 KOH seawater electrolyzer. (e) The polarization curves of Pt-C/NFF||E-NF-LDHSW and Pt-C/NFF||RuO2/NFF for total seawater splitting in 1 mol L-1 KOH seawater electrolyzer. (f) Faradaic efficiency of E-NF-LDHSW and theoretically calculated and experimentally measured H2 and O2 gas versus time at 200 mA cm?2. Collected H2 volume images generated every 200 s for 1400 s (g), H-type electrolytic cell device diagram (h), and collected O2 volume images generated every 200 s for 1400 s (i) of Pt-C/NFF||E-NF-LDHSW.

Fig. 5. (a,b) Number of Cl? and OH? versus distance above E-NF-LDHCl and E-NF-LDHOH surface from classical MD simulation results. (c) Number comparison of various anions in different regions. (d) Experimental Cdl values of NFF, NF-LDHCl, E-NF-LDHOH and E-NF-LDHCl in alkaline electrolyte and alkaline saline electrolyte, respectively. (e) Fe 3d, Ni 3d, O 2p and Cl 2p PDOS spectra of the E-NF-LDHCl with an inset of the enlarged shaded area. (f) Fe 3d, Ni 3d and O 2p PDOS spectra of the E-NF-LDHOH with an inset of the enlarged shaded area. (g) H2O molecular adsorption energies at the Ni, Fe sites of E-NF-LDHCl and E-NF-LDHOH. (h) The adsorption model of E-NF-LDHCl in OER process. (i) OER reaction pathway for E-NF-LDHCl and E-NF-LDHOH model.

参考文献

[1]	L. Wan, M. Pang, J. Le, Z. Xu, H. Zhou, Q. Xu, B. Wang, Nat. Commun., 2022, 13, 7956.
[2]	H. Zhang, Y. Wu, X. Wang, C. Li, Z. Xiao, Y. Liu, Y. Deng, Z. Li, L. Wang, Chem. Eng. J., 2023, 463, 142448.
[3]	J. Li, C. Zhang, C. Zhang, H. Ma, Z. Guo, C. Zhong, M. Xu, X. Wang, Y. Wang, H. Ma, J. Qiu, Adv. Mater., 2022, 34, 2203900.
[4]	W. Zhang, M. Liu, X. Gu, Y. Shi, Z. Deng, N. Cai, Chem. Rev., 2023, 123, 7119-7192.
[5]	Y. N. Zhou, W. L. Yu, H. J. Liu, R. Y. Fan, G. Q. Han, B. Dong, Y. M. Chai, Eco Energy, 2023, 1, 425-436.
[6]	M. S. A. Sher Shah, G. Y. Jang, K. Zhang, J. H. Park, Eco Energy, 2023, 1, 344-374.
[7]	P. Wang, K. Wang, Y. Liu, H. Li, Y. Guo, Y. Tian, S. Guo, M. Luo, Y. He, Z. Liu, S. Guo, Adv. Funct. Mater., 2024, 34, 2316709.
[8]	Y. Chen, Y. Liu, W. Zhai, H. Liu, T. Sakthivel, S. Guo, Z. Dai, Adv. Energy Mater., 2024, 14, 2400059.
[9]	S. Zhao, S. F. Hung, L. Deng, W. J. Zeng, T. Xiao, S. Li, C. H. Kuo, H. Y. Chen, F. Hu, S. Peng, Nat. Commun., 2024, 15, 2728.
[10]	H. Jin, X. Wang, C. Tang, A. Vasileff, L. Li, A. Slattery, S. Z. Qiao, Adv. Mater., 2021, 33, 2007508.
[11]	L. Yu, Q. Zhu, S. Song, B. McElhenny, D. Wang, C. Wu, Z. Qin, J. Bao, Y. Yu, S. Chen, Z. Ren, Nat. Commun., 2019, 10, 5106.
[12]	H. You, D. Wu, D. Si, M. Cao, F. Sun, H. Zhang, H. Wang, T. F. Liu, R. Cao, J. Am. Chem. Soc., 2022, 144, 9254-9263.
[13]	J. Chang, G. Wang, Z. Yang, B. Li, Q. Wang, R. Kuliiev, N. Orlovskaya, M. Gu, Y. Du, G. Wang, Y. Yang, Adv. Mater., 2021, 33, 2101425.
[14]	X. Liu, Q. Yu, X. Qu, X. Wang, J. Chi, L. Wang, Adv. Mater., 2024, 36, 2307395.
[15]	Y. Qin, B. Cao, X.-Y. Zhou, Z. Xiao, H. Zhou, Z. Zhao, Y. Weng, J. Lv, Y. Liu, Y.-B. He, F. Kang, K. Li, T.-Y. Zhang, Nano Energy, 2023, 115, 108727.
[16]	H. Xu, G. Xin, W. Hu, Z. Zhang, C. Si, J. Chen, L. Lu, Y. Peng, X. Li, Appl. Catal. B, 2023, 339, 123157.
[17]	J. Lee, A. Kumar, T. Yang, X. Liu, A. R. Jadhav, G. H. Park, Y. Hwang, J. Yu, C. T. K. Nguyen, Y. Liu, S. Ajmal, M. G. Kim, H. Lee, Energy Environ. Sci., 2020, 13, 5152-5164.
[18]	D. Yue, T. Feng, Z. Zhu, S. Lu, B. Yang, ACS Catal., 2024, 14, 3006-3017.
[19]	M. Bollu, D. T. Tran, S. Prabhakaran, D. H. Kim, N. H. Kim, J. H. Lee, Nano Energy, 2024, 123, 109413.
[20]	Y. Wang, W. Yu, B. Zhou, W. Xiao, J. Wang, X. Wang, G. Xu, B. Li, Z. Li, Z. Wu, L. Wang, J. Mater. Chem. A, 2023, 11, 1886-1893.
[21]	Y. Du, Q. Li, M. Liu, D. Liu, W. Xiao, Z. Xiao, Z. Li, Y. Yamauchi, S. M. Osman, Z. Wu, L. Wang, Chem. Eng. J., 2023, 475, 146057.
[22]	L. Yu, L. Wu, B. McElhenny, S. Song, D. Luo, F. Zhang, Y. Yu, S. Chen, Z. Ren, Energy Environ. Sci., 2020, 13, 3439-3446.
[23]	H. Zhang, Z. Bi, P. Sun, A. Chen, T. Wagberg, X. Hu, X. Liu, L. Jiang, G. Hu, ACS Nano, 2023, 17, 16008-16019.
[24]	L. Tan, J. Yu, C. Wang, H. Wang, X. Liu, H. Gao, L. Xin, D. Liu, W. Hou, T. Zhan, Adv. Funct. Mater., 2022, 32, 2200951.
[25]	Q. Su, P. Wang, Q. Liu, R. Sheng, W. Cheng, J. Ding, Y. Lei, Y. Huang, Appl. Catal. B, 2024, 351, 123994.
[26]	W. Bao, Y. Tang, J. Yu, W. Yan, C. Wang, Y. Li, Z. Wang, J. Yang, L. Zhang, F. Yu, Appl. Catal. B, 2024, 346, 123706.
[27]	M. Cai, Q. Zhu, X. Wang, Z. Shao, L. Yao, H. Zeng, X. Wu, J. Chen, K. Huang, S. Feng, Adv. Mater., 2023, 35, 2209338.
[28]	L. Wang, L. Zhang, W. Ma, H. Wan, X. Zhang, X. Zhang, S. Jiang, J. Y. Zheng, Z. Zhou, Adv. Funct. Mater., 2022, 32, 2203342.
[29]	S. Zhang, Y. Wang, S. Li, Z. Wang, H. Chen, L. Yi, X. Chen, Q. Yang, W. Xu, A. Wang, Z. Lu, Nat. Commun., 2023, 14, 4822.
[30]	S. Song, Y. Wang, X. Liu, X. Tian, Y. Liu, X. Liu, F. Sun, Y. Yuan, W. Li, J. Zang, Appl. Surf. Sci., 2022, 604, 154588.
[31]	W.-D. Zhang, Q.-T. Hu, L.-L. Wang, J. Gao, H.-Y. Zhu, X. Yan, Z.-G. Gu, Appl. Catal. B, 2021, 286, 119906.
[32]	T. Li, X. Zhao, M. Getaye Sendeku, X. Zhang, L. Xu, Z. Wang, S. Wang, X. Duan, H. Liu, W. Liu, D. Zhou, H. Xu, Y. Kuang, X. Sun, Chem. Eng. J., 2023, 460, 141413.
[33]	L. Wu, L. Yu, F. Zhang, B. McElhenny, D. Luo, A. Karim, S. Chen, Z. Ren, Adv. Funct. Mater., 2020, 31, 2006484.
[34]	B. Zhang, S. Liu, S. Zhang, Y. Cao, H. Wang, C. Han, J. Sun, Small, 2022, 18, 2203852.
[35]	W. Liu, J. Yu, M. G. Sendeku, T. Li, W. Gao, G. Yang, Y. Kuang, X. Sun, Angew. Chem. Int. Ed., 2023, 62, e202309882.
[36]	T. Ma, W. Xu, B. Li, X. Chen, J. Zhao, S. Wan, K. Jiang, S. Zhang, Z. Wang, Z. Tian, Z. Lu, L. Chen, Angew. Chem. Int. Ed., 2021, 60, 22740-22744.
[37]	W. Xu, Z. Wang, P. Liu, X. Tang, S. Zhang, H. Chen, Q. Yang, X. Chen, Z. Tian, S. Dai, L. Chen, Z. Lu, Adv. Mater., 2024, 36, 2306062.
[38]	L. Wu, M. Ning, X. Xing, Y. Wang, F. Zhang, G. Gao, S. Song, D. Wang, C. Yuan, L. Yu, J. Bao, S. Chen, Z. Ren, Adv. Mater., 2023, 35, 2306097.
[39]	Y. Kou, J. Liu, Y. Li, S. Qu, C. Ma, Z. Song, X. Han, Y. Deng, W. Hu, C. Zhong, ACS Appl. Mater. Interfaces, 2018, 10, 796-805.
[40]	Y. Li, H. Zhang, M. Jiang, Q. Zhang, P. He, X. Sun, Adv. Funct. Mater., 2017, 27, 1702513.
[41]	Y. Jiang, T. Y. Chen, J. L. Chen, Y. Liu, X. Yuan, J. Yan, Q. Sun, Z. Xu, D. Zhang, X. Wang, C. Meng, X. Guo, L. Ren, L. Liu, R. Y.-Y. Lin, Adv. Mater., 2024, 36, 2306910.
[42]	S. Wang, H. Wang, S. Chen, K. K. K. Cheung, H. F. Wong, C. W. Leung, J. A. Zapien, Int. J. Hydrogen Energy, 2023, 48, 17045-17054.
[43]	T. Ishii, S. Tsuboi, S. Yukinari, G. Sakane, M. Yamashita, B. K. Breedlove, Int. J. Quantum Chem., 2009, 109, 2734-2743.
[44]	Y. Zhang, Q. Wu, J. Z. Y. Seow, Y. Jia, X. Ren, Z. J. Xu, Chem. Soc. Rev., 2024, 53, 8123-8136.
[45]	L. Zhuang, J. Li, K. Wang, Z. Li, M. Zhu, Z. Xu, Adv. Funct. Mater., 2022, 32, 2201127.
[46]	H. Jiang, Q. He, X. Li, X. Su, Y. Zhang, S. Chen, S. Zhang, G. Zhang, J. Jiang, Y. Luo, P. M. Ajayan, L. Song, Adv. Mater., 2019, 31, 1805127.
[47]	H. Fan, W. Chen, G. Chen, J. Huang, C. Song, Y. Du, C. Li, K. Ostrikov, Appl. Catal. B, 2020, 268, 118440.
[48]	Y.-N. Zhou, W.-L. Yu, Y.-N. Cao, J. Zhao, B. Dong, Y. Ma, F.-L. Wang, R.-Y. Fan, Y.-L. Zhou, Y.-M. Chai, Appl. Catal. B, 2021, 292, 120150.
[49]	Z. Cai, J. Liang, Z. Li, T. Yan, C. Yang, S. Sun, M. Yue, X. Liu, T. Xie, Y. Wang, T. Li, Y. Luo, D. Zheng, Q. Liu, J. Zhao, X. Sun, B. Tang, Nat. Commun., 2024, 15, 6624.
[50]	L. Deng, S. F. Hung, Z. Y. Lin, Y. Zhang, C. Zhang, Y. Hao, S. Liu, C. H. Kuo, H. Y. Chen, J. Peng, J. Wang, S. Peng, Adv. Mater., 2023, 35, 2305939.
[51]	H. Qu, B. Li, Y. Ma, Z. Xiao, Z. Lv, Z. Li, W. Li, L. Wang, Adv. Mater., 2023, 35, 2301359.
[52]	J. Zhang, Y. Cui, L. Jia, B. He, K. Zhang, L. Zhao, Int. J. Hydrogen Energy, 2019, 44, 24077-24085.
[53]	Y. Wu, Y. Zhao, P. Zhai, C. Wang, J. Gao, L. Sun, J. Hou, Adv. Mater., 2022, 34, 2202523.
[54]	M. T. Greiner, L. Chai, M. G. Helander, W. M. Tang, Z. H. Lu, Adv. Funct. Mater., 2012, 23, 215-226.
[55]	P. F. Liu, S. Yang, L. R. Zheng, B. Zhang, H. G. Yang, J. Mater. Chem. A, 2016, 4, 9578-9584.
[56]	S. Xu, D. Jiao, X. Ruan, Z. Jin, Y. Qiu, Z. Feng, L. Zheng, J. Fan, W. Zheng, X. Cui, Adv. Funct. Mater., 2024, 34, 10.1002/adfm.202401265.
[57]	K. Yu, H. Yang, J. Xu, W. Yuan, R. Yang, M. Hou, Z. Kang, Y. Liu, P. W. Menezes, Z. Chen, Angew. Chem. Int. Ed., 2024, 63, e202408508.
[58]	J. Ge, J. Y. Zheng, J. Zhang, S. Jiang, L. Zhang, H. Wan, L. Wang, W. Ma, Z. Zhou, R. Ma, J. Mater. Chem. A, 2021, 9, 14432-14443.
[59]	S. Wu, Y. Zhu, G. Yang, H. Zhou, R. Li, S. Chen, H. Li, L. Li, O. Fontaine, J. Deng, Chem. Eng. J., 2022, 446, 136833.
[60]	P. Ye, K. Fang, H. Wang, Y. Wang, H. Huang, C. Mo, J. Ning, Y. Hu, Nat. Commun., 2024, 15, 1012.

氯腐蚀策略: 分钟级构筑氯功能化Ni/Fe-LDH, 以提升抗氯OER性能

Electrochemistry assisted chlorine corrosion strategy: The minute-level fabrication of lattice Cl^- functioned high spin-polarized Ni/Fe-LDH array for enhanced anti-Cl^- OER performance

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 5

参考文献

相关文章 15

编辑推荐

Metrics

[1]	陈明星, 杜子翯, 刘念, 李慧杰, 齐静, 上官恩波, 李晶, 曹嘉豪, 杨树姣, 张伟, 曹睿. 阴阳离子调节策略激活晶格氧促进析氧性能[J]. 催化学报, 2025, 69(2): 282-291.
[2]	孙艺萌, 陈军, 刘琳, 池海波, 韩洪宪. 原子级铱掺杂增强γ-MnO₂析氧活性和稳定性的机理研究[J]. 催化学报, 2025, 69(2): 99-110.
[3]	谢旻斐, 姬星, 孟华颖, 姜南冰, 罗贞玉, 黄千千, 孙耿, 张云怀, 肖鹏. 赤铁矿光阳极界面钛原子在析氧反应多位点机制中的作用: 反应活性位点还是助催化位点?[J]. 催化学报, 2024, 64(9): 77-86.
[4]	朱鸿睿, 徐慧民, 黄陈金, 张志杰, 詹麒尼, 帅婷玉, 李高仁. 光电催化析氧和CO₂还原反应催化剂的研究进展[J]. 催化学报, 2024, 62(7): 53-107.
[5]	吕青芸, 张伟伟, 龙志鹏, 王建涛, 邹星礼, 任伟, 侯龙, 鲁雄刚, 赵玉峰, 余兴, 李喜. Fe稳固的FeOOH@NiOOH电催化剂的大电流极化设计与析氧研究[J]. 催化学报, 2024, 62(7): 254-264.
[6]	郭静雅, 刘炜, 商文喆, 司端惠, 朱超, 胡金文, 辛存存, 程旭升, 张松林, 宋俗禅, 王秀云, 史彦涛. 完全暴露的碳基电极边缘-平面位点用于高效水氧化[J]. 催化学报, 2024, 60(5): 272-283.
[7]	Adel Al-Salihy, 梁策, Abdulwahab Salah, Abdel-Basit Al-Odayni, 卢子昂, 陈孟新, 刘倩倩, 徐平. 用于提升全水解性能的超低含量Ru掺杂NiMoO₄@Ni₃(PO₄)₂核壳纳米结构[J]. 催化学报, 2024, 60(5): 360-375.
[8]	罗健颖, 傅捷, 叶丰铭, 梁汉锋, 王伟俊. 释放多孔纳米结构的活力: 可持续电催化水分解[J]. 催化学报, 2024, 58(3): 37-85.
[9]	郭英杰, 李世龙, 王竞洋, 石磊, 刘迪, 赵慎龙. 非衍生金属有机框架纳米片电解水催化剂: 基础理论、调控策略和最新进展[J]. 催化学报, 2024, 67(12): 21-53.
[10]	宋龙, 迟京起, 唐俊恒, 刘晓斌, 肖振宇, 吴则星, 王磊. 高效海水电解和抑制氯化物氧化的阳极设计原则[J]. 催化学报, 2024, 66(11): 53-75.
[11]	施兆平, 王子昂, 吴鸿翔, 肖梅玲, 刘长鹏, 邢巍. 快速配体转换制备高密度Ir单原子用于高效催化酸性水氧化[J]. 催化学报, 2024, 66(11): 223-232.
[12]	夏亚男, 迟京起, 唐俊恒, 刘晓斌, 肖振宇, 赖建平, 王磊. 阴离子空位在析氧反应电催化剂中的研究进展[J]. 催化学报, 2024, 66(11): 110-138.
[13]	王潇涵, 田汉, 余旭, 陈立松, 崔香枝, 施剑林. 非晶相电催化剂在电解水领域的研究进展[J]. 催化学报, 2023, 51(8): 5-48.
[14]	韩璟怡, 管景奇. 通过表面镧改性和体相锰掺杂协助钴尖晶石酸性下析氧[J]. 催化学报, 2023, 51(8): 1-4.
[15]	张光颖, 刘旭, 张欣欣, 梁志坚, 邢耕宇, 蔡斌, 沈迪, 王蕾, 付宏刚. P修饰提高Fe-N-C的氧反应活性用于高稳定的锌-空气电池[J]. 催化学报, 2023, 49(6): 141-151.

氯腐蚀策略: 分钟级构筑氯功能化Ni/Fe-LDH, 以提升抗氯OER性能

Electrochemistry assisted chlorine corrosion strategy: The minute-level fabrication of lattice Cl- functioned high spin-polarized Ni/Fe-LDH array for enhanced anti-Cl- OER performance

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 5

参考文献

相关文章 15

编辑推荐

Metrics

Electrochemistry assisted chlorine corrosion strategy: The minute-level fabrication of lattice Cl^- functioned high spin-polarized Ni/Fe-LDH array for enhanced anti-Cl^- OER performance