Tetrabutylammonium hexatungstate [TBA]2[W6O19]: Novel and reusable heterogeneous catalyst for rapid solvent-free synthesis of polyhydroquinolines via unsymmetrical Hantzsch reaction

doi:10.1016/S1872-2067(12)60547-6

Abstract

Abstract:

A novel, efficient, and environmentally friendly method for the synthesis of polyhydroquinoline derivatives by a one-pot, four-component unsymmetrical Hantzsch condensation of dimedone, aldehydes, ethyl acetoacetate, and ammonium acetate in the presence of a catalytic amount of tetrabutylammonium hexatungstate [TBA]₂[W₆O₁₉] under solvent-free conditions has been developed. The results showed that this heterogeneous catalyst has high catalytic activity and the desired products were obtained in good to high yields. Moreover, the catalyst was found to be reusable and considerable catalytic activity was still achieved after the fifth run.

Key words: Heterogeneous catalysis, Polyhydroquinolines, Tetrabutylammonium hexatungstate

Abolghasem DAVOODNIA, Maryam KHASHI, Niloofar TAVAKOLI-HOSEINI. Tetrabutylammonium hexatungstate [TBA]₂[W₆O₁₉]: Novel and reusable heterogeneous catalyst for rapid solvent-free synthesis of polyhydroquinolines via unsymmetrical Hantzsch reaction[J]. Chinese Journal of Catalysis, 2013, 34(6): 1173-1178.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(12)60547-6

https://www.cjcatal.com/EN/Y2013/V34/I6/1173

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Tetrabutylammonium hexatungstate [TBA]₂[W₆O₁₉]: Novel and reusable heterogeneous catalyst for rapid solvent-free synthesis of polyhydroquinolines via unsymmetrical Hantzsch reaction

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