Pure and Ni-substituted Co3O4 spinel catalysts for direct N2O decomposition

doi:10.1016/S1872-2067(14)60058-9

Abstract

Abstract:

A series of Ni_xCo_1-xCo₂O₄ (0 ≤ x ≤ 1) spinel catalysts were prepared by the co-precipitation method and used for direct N₂O decomposition. The decomposition pathway of the parent precipitates was characterized by thermal analysis. The catalysts were calcined at 500℃ for 3 h and characterized by powder X-ray diffraction, Fourier transform infrared, and N₂ adsorption-desorption. Nickel cobaltite spinel was formed in the solid state reaction between NiO and Co₃O₄. The N₂O decomposition measurement revealed significant increase in the activity of Co₃O₄ spinel oxide catalyst with the partial replacement of Co²⁺ by Ni²⁺. The activity of this series of catalysts was controlled by the degree of Co²⁺ substitution by Ni²⁺, spinel crystallite size, catalyst surface area, presence of residual K⁺, and calcination temperature.

Key words: Nitrous oxide decomposition, Spinel, Cobalt oxide, Greenhouse gas, Nickel cobaltite

Bahaa M. Abu-Zied, Soliman A. Soliman, Sarah E. Abdellah. Pure and Ni-substituted Co₃O₄ spinel catalysts for direct N₂O decomposition[J]. Chinese Journal of Catalysis, 2014, 35(7): 1105-1112.

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Pure and Ni-substituted Co₃O₄ spinel catalysts for direct N₂O decomposition

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