Synthesis of mesoporous ZSM-5 using a new gemini surfactant as a mesoporous directing agent：A crystallization transformation process

doi:10.1016/S1872-2067(14)60128-5

Chinese Journal of Catalysis ›› 2014, Vol. 35 ›› Issue (10): 1727-1739.DOI: 10.1016/S1872-2067(14)60128-5

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Synthesis of mesoporous ZSM-5 using a new gemini surfactant as a mesoporous directing agent：A crystallization transformation process

Quanyi Wang^a,b,e, Yingxu Wei^a, Shutao Xu^a, Mozhi Zhang^a,e, Shuanghe Meng^a, Dong Fan^a,e, Yue Qi^a, Jinzhe Li^a, Zhengxi Yu^a, Cuiyu Yuan^a, Yanli He^a, Shuliang Xu^a, Jingrun Chen^a,e, Jinbang Wang^a, baolian Su^b,c, Zhongmin Liu^a,d

a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b Laboratory of Inorganic Materials Chemistry (CMI), University of Namur (FUNDP), 61 rue de Bruxelles, B-5000 Namur, Belgium;
c State key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, Hubei, China;
d State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
e University of Chinese Academy of Sciences, Beijing 100049, China

Received:2014-04-09 Revised:2014-05-28 Online:2014-09-28 Published:2014-09-30
Supported by:
This work was supported by the National Natural Science Foundation of China (21273230, 21273005, 21103176, 21103180).

Abstract

Abstract:

A new gemini surfactant, [C₁₈H₃₇(CH₃)₂-N⁺-(CH₂)₃-N⁺-(CH₃)₂C₁₈H₃₇]Cl₂ (C_18-3-18), has been successfully used as the mesopore directing agent in the hydrothermal synthesis of mesoporous ZSM-5 (MZSM-5). The synthesis of MZSM-5 was realized with a low temperature crystallization process at 130 ℃. The amount of C_18-3-18 used in the synthesis affected the relative crystallinity and the textural properties of the obtained MZSM-5. Detailed investigation showed that the formation of MZSM-5 followed a crystallization transformation process. The use of C_18-3-18 resulted in the formation of mesoporous material during the early stage of the synthesis, which was converted into MZSM-5 crystals templated by tetrapropylammonium bromide to form the MFI phase. As the synthesis proceeded, the MZSM-5 crystals aggregated into particles by weak interactions. This work shows that C_18-3-18 can be used as a mesopore directing agent, which could provide a route for the synthesis of other mesoporous zeolites.

Key words: Mesoporous ZSM-5, Dual-templating, Gemini surfactant, Inter-crystalline mesopore, Crystallization transformation

Quanyi Wang, Yingxu Wei, Shutao Xu, Mozhi Zhang, Shuanghe Meng, Dong Fan, Yue Qi, Jinzhe Li, Zhengxi Yu, Cuiyu Yuan, Yanli He, Shuliang Xu, Jingrun Chen, Jinbang Wang, baolian Su, Zhongmin Liu. Synthesis of mesoporous ZSM-5 using a new gemini surfactant as a mesoporous directing agent：A crystallization transformation process[J]. Chinese Journal of Catalysis, 2014, 35(10): 1727-1739.

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References

[1] Serrano D P, Aguado J, Escola J M, Rodríguez J M, Peral. Chem Mater, 2006, 18: 2462
[2] Chal R, Gérardin C, Bulut M, van Donk S. ChemCatChem, 2011, 3: 67
[3] Na K, Choi M, Ryoo R, Micropor Mesopor Mater, 2013, 166: 3
[4] Li X Y, Sun M H, Rooke J C, Chen L H, Sun B L. Chin J Catal (李小云, 孙明慧, Rooke Joanna Claire, 陈丽华, 苏宝连. 催化学报), 2013, 34: 22
[5] Zhang C M, Liu Q, Xu Z, Wang K S. Microporous Mesoporous Mater, 2003, 62: 157
[6] Beers A E W, van Bokhoven J A, de Lathouder K M, Kapteijn F, Moulijn J A. J Catal, 2003, 218: 239
[7] Viswanadham N, Kumar M. Microporous Mesoporous Mater, 2006, 92: 31
[8] Song Y M, Ren N, Tang Y. Chin J Catal (宋燕梅, 任楠, 唐颐. 催化学报), 2012, 33: 192
[9] Groen J C, Peffer L A A, Moulijn J A, Perez-Ramirez J. Chem Eur J, 2005, 11: 4983
[10] Qi X L, Chen X M, Kong D J, Zheng J L, Yuan X H, Yang D Q. Chin J Catal (祁晓岚, 陈雪梅, 孔德金, 郑均林, 袁小红, 杨德琴. 催化学报), 2009, 30: 1197
[11] Triantafillidis C S, Vlessidis A G, Evmiridis N P. Ind Eng Chem Res, 2000, 39: 307
[12] Jacobsen C J H, Madsen C, Houzvicka J, Schmidt I, Carlsson A. J Am Chem Soc, 2000, 122: 7116
[13] Tao Y S, Kanoh H, Kaneko K. J Am Chem Soc, 2003, 125: 6044
[14] Zhao J J, Zhou J, Chen Y, He Q J, Ruan M L, Guo L M, Shi J L, Chen H R. J Mater Chem, 2009, 19: 7614
[15] Zhu H B, Liu Z C, Wang Y D, Kong D J, Yuan X H, Xie Z K. Chem Mater, 2008, 20: 1134
[16] Holland B T, Abrams L, Stein A. J Am Chem Soc, 1999, 121: 4308
[17] Zhu Y, Hua Z L, Zhou J, Wang L J, Zhao J J, Gong Y, Wu W, Ruan M L, Shi J L. Chem Eur J, 2011, 17: 14618
[18] Wang Q Y, Xu S T, Chen J R, Wei Y X, Li J Z, Fan D, Yu Z X, Qi Y, He Y L, Xu S L, Yuan C Y, Zhou Y, Wang J B, Zhang M Z, Su B L, Liu Z M. RSC Adv, 2014, 4:21479
[19] Zhou J, Hua Z L, Liu Z C, Wu W, Zhu Y, Shi J L. ACS Catal, 2011, 1: 287
[20] Serrano D P, García R A, Vicente G, Linares M, Procházková D, ?ejka J. J Catal, 2011, 279: 366
[21] Song J W, Ren L M, Yin C Y, Ji Y Y, Wu Z F, Li J X, Xiao F S. J Phys Chem C, 2008, 112: 8609
[22] Wang H, Pinnavaia T J. Angew Chem Int Ed, 2006, 45: 7603
[23] Jin J J, Zhang X D, Li Y S, Li H, Wu W, Cui Y L, Chen Q, Li L, Gu J L, Zhao W R, Shi J L. Chem Eur J, 2012, 18: 16549
[24] Choi M, Na K, Kim J, Sakamoto Y, Terasaki O, Ryoo R. Nature, 2009, 461: 246
[25] Na K, Choi M, Park W, Sakamoto Y, Terasaki O, Ryoo R. J Am Chem Soc, 2010, 132: 4169
[26] Na K, Jo C, Kim J, Cho K, Jung J, Seo Y, Messinger R J, Chmelka B F, Ryoo R. Science, 2011, 333: 328

Synthesis of mesoporous ZSM-5 using a new gemini surfactant as a mesoporous directing agent：A crystallization transformation process

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