Methanol aromatization over HZSM-5 catalysts modified with different zinc salts

doi:10.1016/S1872-2067(14)60145-5

Abstract

Abstract:

HZSM-5 catalysts modified with various Zn salts, namely zinc sulfate, zinc acetate, zinc nitrate, and zinc chloride, were prepared using an impregnation method. The resultant catalysts were characterized by X-ray diffraction, N₂ adsorption, thermogravimetry-mass spectrometry, temperature-programmed desorption of NH3, and infrared spectroscopy using pyridine as the probe molecule. The methanol-to-aromatic (MTA) performance over the modified catalysts was investigated. The results showed that the type of Zn species in the catalyst significantly influenced the catalyst surface acidity. The distribution of acid sites and Zn species in the HZSM-5 catalyst modified with zinc sulfate effectively improved the MTA performance.

Key words: HZSM-5 zeolite, Zinc salt, Methanol, Aromatization

Yii, Yingli Wang, Xin Chen, Zhengxi Yu, Lei Xu. Methanol aromatization over HZSM-5 catalysts modified with different zinc salts[J]. Chinese Journal of Catalysis, DOI: 10.1016/S1872-2067(14)60145-5.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60145-5

https://www.cjcatal.com/EN/Y2014/V35/I10/1740

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