Chinese Journal of Catalysis ›› 2014, Vol. 35 ›› Issue (10): 1752-1760.DOI: 10.1016/S1872-2067(14)60143-1

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Effect of N2/Ar plasma treatment on the visible light photocatalytic activity of CuO/TiO2

Zhengwei Luo, Hui Jiang, Longzhi Hu, Dan Li, Wenhua Geng, Ping Wei   

  1. College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu, China
  • Received:2014-03-27 Revised:2014-05-12 Online:2014-09-28 Published:2014-09-30
  • Supported by:

    This work was supported by the Natural Science Foundation of Jiangsu Province of China (BK2011808), the Natural Science Foundation of the Jiangsu Higher Education Institutions (10KJB61005), Scientific Research Foundation of Returnees of Ministry of Education ([2011]1568), and Academic Foundation of Young Teacher of Nanjing Tech University (39707003).

Abstract:

The effect of N2/Ar dielectric barrier discharge plasma on the photocatalytic activity of CuO/TiO2 under visible light irradiation was studied. The photocatalysts were characterized by X-ray diffraction, ultraviolet-visible spectrophotometry, transmission electron microscopy, X-ray photoelectron spectroscopy, and electron paramagnetic resonance spectroscopy. The plasma parameters including gas composition, treatment time, and plasma power were investigated. The activities of the plasma-treated photocatalysts were evaluated by the photodegradation of methyl orange under visible light illumination. The optimal operation conditions were N2:Ar = 8:2, treatment time of 20 min, and a discharge current of 1.0 A. Simulated mercury-containing wastewater was treated by the photocatalysts.

Key words: Titanium dioxide, Plasma, Modification, Nitrogen doping, Mercury