Oyster shell waste supported CuCl2 for aldehyde-alkyne-amine coupling reaction to propargylamines

doi:10.1016/S1872-2067(14)60195-9

Chinese Journal of Catalysis ›› 2014, Vol. 35 ›› Issue (12): 2006-2013.DOI: 10.1016/S1872-2067(14)60195-9

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Oyster shell waste supported CuCl₂ for aldehyde-alkyne-amine coupling reaction to propargylamines

Xingquan Xiong, Huixin Chen, Rongjun Zhu

College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, Fujian, China

Received:2014-06-08 Revised:2014-07-17 Online:2014-11-29 Published:2014-11-29
Supported by:
This work was supported by the National Natural Science Foundation of China (21004024), the Province Natural Science Foundation of Fujian, China (2011J01046), the Program for New Century Excellent Talents in University of Fujian Province (2012FJ-NCET-ZR03), the University Distinguished Young Research Talent Training Program of Fujian Province (11FJPY02), and the Promotion Program for Young and Middle-aged Teacher in Science and Technology Research of Huaqiao University (ZQN-YX103).

Abstract

Abstract:

The development of an economic and simple heterogeneous oyster shell waste supported CuCl₂ catalyst for the aldehyde-alkyne-amine (A3) coupling reaction was reported. The waste oyster shell powder (OSP) supported CuCl₂ (OSP-CuCl₂) catalyst was prepared by a simple method from waste OSPs and CuCl₂, which was shown to be a highly active and recyclable catalyst for the A3-coupling reaction. A range of propargylamines were obtained in good to excellent yields (85%-97%) under solvent-free and microwave-heated conditions. The OSP-CuCl₂ catalyst can be simply recovered by filtration and reused for at least six runs. Propargylamine can be produced in 87% yield even when the scale of the A3-coupling reaction was increased to 150 mmol.

Key words: Propargylamine, A3-coupling reaction, Oyster shell waste, Microwave irradiation, Green chemistry

Xingquan Xiong, Huixin Chen, Rongjun Zhu. Oyster shell waste supported CuCl₂ for aldehyde-alkyne-amine coupling reaction to propargylamines[J]. Chinese Journal of Catalysis, 2014, 35(12): 2006-2013.

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Oyster shell waste supported CuCl₂ for aldehyde-alkyne-amine coupling reaction to propargylamines

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