I2/ionic liquid as a highly efficient catalyst for per-O-acetylation of sugar under microwave irradiation

doi:10.1016/S1872-2067(14)60219-9

Abstract

Abstract:

A practical and highly efficient approach was developed to synthesize peracetylated sugar derivatives using a recyclable iodine/PEG₄₀₀-based ionic liquid catalyst (I₂/IL). The peracetylated sugars were readily obtained in a few minutes in excellent yields (90%-99%, 13 examples) on a multi-gram scale (50.0 mmol) by the reaction of sugar and acetic anhydride under microwave irradiation in the absence of a volatile organic solvent. The desired product was easily obtained by simple extraction with toluene from the reaction mixture, and I₂/ILs can be readily recovered and reused at least six times without obvious loss in the yield. When the scale of the per-O-acetylation reaction was increased to 50.0 mmol, the desired product was still obtained in 90% yield after five recycles.

Key words: Peracetylated sugar, Iodine, Ionic liquid, Microwave irradiation

Xingquan Xiong, Chao Yi, Qian Han, Lin Shi, Sizhong Li. I₂/ionic liquid as a highly efficient catalyst for per-O-acetylation of sugar under microwave irradiation[J]. Chinese Journal of Catalysis, 2015, 36(2): 237-243.

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https://www.cjcatal.com/EN/Y2015/V36/I2/237

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I₂/ionic liquid as a highly efficient catalyst for per-O-acetylation of sugar under microwave irradiation

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