Coupling of epoxides and carbon dioxide catalyzed by Brönsted acid ionic liquids

doi:10.1016/S1872-2067(14)60227-8

Abstract

Abstract:

A series of Brönsted acid ionic liquids (BAILs) containing a long chain Brönsted acid site in the cationic part and a Lewis basic site in the anionic part were designed, synthesized, and used as catalyst for the coupling of epoxides and carbon dioxide to cyclic carbonates without a co-catalyst or co-solvent. The effects of catalyst structure and other parameters on the catalytic performance were investigated. The long chain 2-(N,N-dimethyldodecylammonium) acetic acid bromide ([(CH₂COOH)DMDA]Br) showed high catalytic activity and good reusability. This protocol was expanded to various epoxides, which gave the corresponding cyclic carbonates in good yields. The acidity of the catalyst influenced its catalytic activity.

Key words: Carbon dioxide fixation, Coupling reaction, Brönsted acidic ionic liquid, Cyclic carbonate, Hammett acidity

Tao Chang, Xiaorui Gao, Li Bian, Xiying Fu, Mingxia Yuan, Huanwang Jing. Coupling of epoxides and carbon dioxide catalyzed by Brönsted acid ionic liquids[J]. Chinese Journal of Catalysis, 2015, 36(3): 408-413.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60227-8

https://www.cjcatal.com/EN/Y2015/V36/I3/408

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