Cycloaddition of CO2 and propylene oxide by using M(HBTC)(4,4'-bipy)·3DMF (M=Ni, Co, Zn) metal-organic frameworks

doi:10.1016/S1872-2067(17)63005-5

Abstract

Abstract:

Three pillar-layered metal-organic frameworks (MOFs) based on M(HBTC)(4,4'-bipy)·3DMF (M=Ni, Co, and Zn; HBTC=1,3,5-benzenetricarboxylic acid, 4,4'-bipy=4,4'-bipyridine) were synthesized using a solvothermal method. Zn(HBTC)(4,4'-bipy)·3DMF was synthesized for the first time using both a solvothermal and microwave method, and subsequently characterized by various physicochemical methods. The structure of M(HBTC)(4,4'-bipy)·3DMF consisted of honeycomb grid layers of M²⁺ ions and BTC units, which were further linked by the 4,4'-bipy pillars to form a three-dimensional highly porous framework. All the MOFs displayed excellent synergistic catalytic properties with alkyl ammonium halides (TBAX) in the solventless fixation of CO₂ with epoxides to produce cyclic carbonates. The catalytic activities of these MOFs followed the trend Zn > Co > Ni, which was explained by the acid-base bifunctional properties. The microwave-synthesized Zn(HBTC)(4,4'-bipy)·3DMF material exhibited physical, chemical, and catalytic properties that were similar to those of the catalyst obtained using a conventional solvothermal synthesis. The scope of various parameters, including recyclability, was studied, and a plausible reaction mechanism was suggested.

Key words: M(HBTC)(4,4'-bipy)·, 3DMF(M=Ni, Co, Zn), Microwave method, Carbon dioxide, Epoxide, Cyclic carbonate

Seol-Hee Kim, Robin Babu, Dong-Woo Kim, Wonjoo Lee, Dae-Won Park. Cycloaddition of CO₂ and propylene oxide by using M(HBTC)(4,4'-bipy)·3DMF (M=Ni, Co, Zn) metal-organic frameworks[J]. Chinese Journal of Catalysis, 2018, 39(8): 1311-1319.

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https://www.cjcatal.com/EN/Y2018/V39/I8/1311

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Cycloaddition of CO₂ and propylene oxide by using M(HBTC)(4,4'-bipy)·3DMF (M=Ni, Co, Zn) metal-organic frameworks

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