Supported Au-Ni nano-alloy catalysts for the chemoselective hydrogenation of nitroarenes

doi:10.1016/S1872-2067(14)60254-0

Abstract

Abstract:

A modified two-step approach was developed for the synthesis of uniform and highly dispersed Au-Ni alloy nanoparticles on a silica support. The supported Au-Ni alloy nanoparticles were investigated for the chemoselective hydrogenation of substituted nitroarenes, which showed a strong synergistic effect between Au and Ni. The best catalyst was AuNi₃/SiO₂ that afforded a selectivity to 3-vinylaniline of 93.0% at a 3-nitrostyrene conversion of 90.8% after 70 min under mild conditions.

Key words: Gold-nickel, Alloy, Chemoselective hydrogenation, Nitroarenes

Haisheng Wei, Xing Wei, Xiaofeng Yang, Guangzhao Yin, Aiqin Wang, Xiaoyan Liu, Yanqiang Huang, Tao Zhang. Supported Au-Ni nano-alloy catalysts for the chemoselective hydrogenation of nitroarenes[J]. Chinese Journal of Catalysis, 2015, 36(2): 160-167.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60254-0

https://www.cjcatal.com/EN/Y2015/V36/I2/160

References

[1] Ono N. The Nitro Group in Organic Synthesis. NewYork: John Wiley & Sons, 2003
[2] Xu K L, Zhang Y, Chen X R, Huang L, Zhang R, Huang J. Adv Synth Catal, 2011, 353: 1260
[3] Liu H, Li R Y, Zhang M, Li W, Zhang M H, Tao K Y. Chin J Catal (刘皓, 李若愚, 张濛, 李伟, 张明慧, 陶克毅. 催化学报), 2009, 30: 606
[4] Corma A, Serna P. Science, 2006, 313: 332
[5] Chen Y Y, Qiu J S, Wang X K, Xiu J H. J Catal, 2006, 242: 227
[6] Chen Y Y, Wang C, Liu H Y, Qiu J S, Bao X H. Chem Commun, 2005: 5298
[7] Shimizu K I, Miyamoto Y, Satsuma A. J Catal, 2010, 270: 86
[8] He L, Ni J, Sun H, Cao Y. Chin J Catal (何林, 倪吉, 孙浩, 曹勇. 催化学报), 2009, 30: 958
[9] Shimizu K I, Miyamoto Y, Kawasaki T, Tanji T, Tai Y, Satsuma A. J Phys Chem C, 2009, 113: 17803
[10] Mitsudome T, Mikami Y, Matoba M, Mizugaki T, Jitsukawa K, Kaneda K. Angew Chem Int Ed, 2012, 51: 136
[11] Boronat M, Concepción P, Corma A, González S, Illas F, Serna P. J Am Chem Soc, 2007, 129: 16230
[12] Cárdenas-Lizana F, Gómez-Quero S, Keane M A. ChemSusChem, 2008, 1: 215
[13] Serna P, Concepción P, Corma A. J Catal, 2009, 265: 19
[14] Corma A, Boronat M, González S, Illas F. Chem Commun, 2007: 3371
[15] He D P, Jiao X D, Jiang P, Wang J, Xu B Q. Green Chem, 2012, 14: 111
[16] Cárdenas-Lizana F, Gómez-Quero S, Hugon A, Delannoy L, Louis C, Keane M A. J Catal, 2009, 262: 235
[17] Cárdenas-Lizana F, Gómez-Quero S, Baddeley C J, Keane M A. Appl Catal A, 2010, 387: 155
[18] Wang A Q, Liu X Y, Mou C Y, Zhang T. J Catal, 2013, 308: 258
[19] Liu X Y, Wang A Q, Yang X F, Zhang T, Mou C Y, Su D S, Li J. Chem Mater, 2009, 21: 410
[20] Wang A Q, Liu J H, Lin S D, Lin T S, Mou C Y. J Catal, 2005, 233: 186
[21] Wang A Q, Hsieh Y P, Chen Y F, Mou C Y. J Catal, 2006, 237: 197
[22] Wang A Q, Chang C M, Mou C Y. J Phys Chem B, 2005, 109: 18860
[23] Liu X Y, Wang A Q, Wang X D, Mou C Y, Zhang T. Chem Commun, 2008: 3187
[24] Li W J, Wang A Q, Liu X Y, Zhang T. Appl Catal A, 2012, 433: 146
[25] Zhang L L, Wang A Q, Miller J T, Liu X Y, Yang X F, Wang W T, Li L, Huang Y Q, Mou C Y, Zhang T. ACS Catal, 2014, 4: 1546
[26] Pei G X, Liu X Y, Wang A Q, Li L, Huang Y Q, Zhang T, Lee J W, Jang B W-L, Mou C Y. New J Chem, 2014, 38: 2043
[27] Wei X, Yang X F, Wang A Q, Li L, Liu X Y, Zhang T, Mou C Y, Li J. J Phys Chem C, 2012, 116: 6222
[28] Xu X J, Fu Q, Wei M M, Wu X, Bao X H. Catal Sci Technol, 2014, 4: 3151
[29] Xu X J, Fu Q, Guo X G, Bao X H. ACS Catal, 2013, 3: 1810
[30] Sun K Q, Hong Y C, Zhang G R, Xu B Q. ACS Catal, 2011, 1: 1336
[31] Bienzle M, Oishi T, Sommer F. J Alloys Compd, 1995, 220: 182
[32] Zhou S H, Yin H F, Schwartz V, Wu Z L, Mullins D, Eichhorn B, Overbury S H, Dai S. ChemPhysChem 2008, 9: 2475
[33] Molenbroek A M, Nørskov J K, Clausen B S. J Phys Chem B, 2001, 105: 5450
[34] Wang D S, Li Y D. J Am Chem Soc, 2010, 132: 6280
[35] Xu J, White T, Li P, He C H, Yu J G, Yuan W K, Han Y F. J Am Chem Soc, 2010, 132: 10398
[36] Russier-Antoine I, Bachelier G, Sablonière V, Duboisset J, Benichou E, Jonin C, Bertorelle F, Brevet P F. Phys Rev B, 2008, 78: 035436
[37] Bulushev D A, Beloshapkin S, Plyusnin P E, Shubin Y V, Bukhtiyarov V I, Korenev S V, Ross J R H. J Catal, 2013, 299: 171
[38] Liu X Y, Wang A Q, Li L, Zhang T, Mou C Y, Lee J F. Prog Nat Sci, 2013, 23: 317
[39] Yen C W, Lin M L, Wang A Q, Chen S A, Chen J M, Mou C Y. J Phys Chem C, 2009, 113: 17831
[40] Liu X Y, Wang A Q, Li L, Zhang T, Mou C Y, Lee J F. J Catal, 2011, 278: 288
[41] Jiang H L, Umegaki T, Akita T, Zhang X B, Haruta M, Xu Q. Chem Eur J, 2010, 16: 3132