Efficient approach for the chemoselective acetylation of alcohols catalyzed by a novel metal oxide nanocatalyst CuO-ZnO

doi:10.1016/S1872-2067(14)60259-X

Abstract

Abstract:

A new method has been developed for the chemoselective acetylation of alcohols with acetic anhydride in the presence of phenols using a novel, recyclable CuO-ZnO nanocatalyst. The catalyst was synthesized using the co-precipitation method and characterized by N₂ adsorption-desorption, X-ray diffraction, scanning electron microscopy, transmission electron microscopy and energy dispersion scanning analyses. Furthermore, this catalyst could be recycled up to six times without significant loss in its activity.

Key words: CuO-ZnO nanocatalyst, Alcohol, Chemoselective acetylation, Acetic anhydride

Jalal Albadi, Amir Alihosseinzadeh, Mehdi Mardani. Efficient approach for the chemoselective acetylation of alcohols catalyzed by a novel metal oxide nanocatalyst CuO-ZnO[J]. Chinese Journal of Catalysis, 2015, 36(3): 308-313.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60259-X

https://www.cjcatal.com/EN/Y2015/V36/I3/308

References

[1] Ghosh R, Maiti S, Chakraborty A. Tetrahedron Lett, 2005, 46: 147
[2] Humphrey J M, Chamberlin A R. Chem Rev, 1997, 97: 2243
[3] Shirini F, Zolfigol M A, Abedini M. Monatsh Chem, 2009, 140: 1495
[4] Leclercq L, Suisse I, Agbossou-Niedercorn F. Eur J Org Chem, 2010: 2696
[5] Singh S J, Kale S R, Gawande M B, Velhinho A, Jayaram R V. Catal Commun, 2014, 44: 24
[6] Tamaddon F, Amrollahi M A, Shrafat L. Tetrahedron Lett, 2005, 46: 7841
[7] Lopez I, Bravo J L, Caraballo M, Barneto J L, Silvero G. Tetrahe-dron Lett, 2011, 52: 3339
[8] Moghadam M, Tangestaninejad S, Mirkhani V, Mohammadpoor- Baltork I, Gharaati S. C R Chim, 2011, 14: 1080
[9] Osiglio L, Romanelli G, Blanco M. J Mol Catal A, 2010, 316: 52
[10] Khazaie A, Rostami A, Mantashlo F. Chin Chem Lett, 2010, 21: 1430
[11] Farhadi S, Panahandehjoo S. Appl Catal A, 2010, 382: 293
[12] Rajabi F, Luque R. Catal Commun, 2014, 45: 129
[13] Ghorbani-Choghamarani A, Pourbaharan N. Chin J Catal (催化学报), 2012, 33: 1470
[14] Shirini F, Khaligh N G. Chin J Catal (催化学报), 2013, 34: 695
[15] Hajjami M, Ghorbani-Choghamarani A, Norouzi M. Chin J Catal (催化学报), 2012, 33: 1661
[16] Javaherian M, Sabzi H E. Ind J Chem, 2014, 53B: 631
[17] Astruc D. Nanoparticles and Catalysis. Weinheim: Wiley-VCH, 2008
[18] Samantaray S, Pradhan D K, Hota G, Mishra B G. Chem Eng J, 2012, 193: 1
[19] Li S, Zhang W, So M H, Che H M, Wang C M, Chen R. J Mol Catal A, 2012, 359: 81
[20] Pinaka A, Vougioukalakis G C, Dimotikali D, Psyharis V, Papado-poulos K. Synthesis, 2012, 44: 1057
[21] Sarvari M H, Sharghi H. J Org Chem, 2004, 69: 6953
[22] Yin S F, Xu B Q, Wang S J, Ng C F, Au C T. Catal Lett, 2004, 96: 113
[23] Drexler M T, Amiridis M D. Catal Lett, 2002, 79: 175
[24] Albadi J, Razeghi A, Abbaszadeh H, Mansournezhad A. J Nanoparticles, 2013, 2013: 546194
[25] Albadi J, Mansournezhad A, Abbaszadeh H. J Chin Chem Soc, 2013, 60: 1193
[26] Albadi J, Mansournezhad A, Derakhshandeh Z. Chin Chem Lett, 2013, 24: 821
[27] Albadi J, Mansournezhad A, Azarian Z. Iran J Org Chem, 2013, 5: 693
[28] Albadi J, Razeghi A, Mansournezhad A, Azarian Z. J Nanostructure Chem, 2013, 3: 85
[29] Albadi J, Shiran J A, Mansournezhad A. J Chem Sci, 2014, 126: 147
[30] Albadi J, Razeghi A, Alihoseinzadeh A. Catal Commun, 2014, 49: 1
[31] Sheldon R A. Catal Today, 1987, 1: 351