Influence of Zn species in HZSM-5 on ethylene aromatization

doi:10.1016/S1872-2067(14)60289-8

Abstract

Abstract:

Zn-containing HZSM-5 zeolites with different Zn contents were prepared by ion exchange and physically mixing methods, and were characterized by X-ray diffraction, scanning electron microscope, N₂ adsorption-desorption, NH₃temperature programmed desorption, pyridine adsorption infrared spectroscopy, ultraviolet-visible diffuse reflectance spectroscopy and X-ray photoelectron spectroscopy. Zn species introduced into HZSM-5 were identified as ZnO crystals, ZnO clusters in the zeolite channel and Zn(OH)⁺ species formed from a solid state reaction between dispersed ZnO and the protons in the zeolite. The preparation method has a significant influence on the distribution of the Zn species. The catalytic behavior of Zn-containing HZSM-5 with different Zn contents showed that the Zn(OH)⁺ and ZnO species were responsible for aromatic formation from ethylene.

Key words: Ethylene, Aromatization, Zn species, HZSM-5, Dehydrogenation

Xuchuan Chen, Mei Dong, Xianjun Niu, Kai Wang, Gang Chen, Weibin Fan, Jianguo Wang, Zhangfeng Qin. Influence of Zn species in HZSM-5 on ethylene aromatization[J]. Chinese Journal of Catalysis, 2015, 36(6): 880-888.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60289-8

https://www.cjcatal.com/EN/Y2015/V36/I6/880

References

[1] Liu H M, Li Y, Shen W J, Bao X H, Xu Y D. Catal Today, 2004, 93-95: 65
[2] Ai Sha N L H, Liu J X, He N, Guo H C. Chin J Catal (艾沙·努拉洪, 刘家旭, 贺宁, 郭洪臣. 催化学报), 2013, 34: 1262
[3] Song Y Q, Zhu X X, Xie S J, Wang Q X, Xu L Y. Catal Lett, 2004, 97: 31
[4] Song Y Q, Zhu X X, Xu L Y. Catal Comm, 2006, 7: 218
[5] Choudhary V R, Panjala D, Banerjee S, Kinage A K. Microporous Mesoporous Mater, 2001, 47: 253
[6] Choudhary V R, Banerjee S, Panjala D. J Catal, 2002, 205: 398
[7] Yakovlev A L, Shubin A A, Zhidomirov G M, Van Santen R A. Catal Lett, 2000, 70: 175
[8] Lubango L M, Scurrell M S. Appl Catal A, 2002, 235: 265
[9] Yin S F, Lin J, Yu Z W. Chin J Catal (尹双凤, 林洁, 于中伟. 催化学报), 2001, 22: 57
[10] Chen J, Zhang L, Kang H M, Ding F X. Chin J Catal (陈军, 张鎏, 康慧敏, 丁富新. 催化学报), 2001, 22: 229
[11] Ni Y M, Sun A M, Wu X L, Hu J L, Li T, Li G X. Chin J Chem Eng (倪友明, 孙爱明, 吴小岭, 胡江林, 李涛, 李光兴. 中国化学工程学报), 2011, 19: 439
[12] Xin Y B, Qi P Y, Duan X P, Lin H Q, Yuan Y Z. Catal Lett, 2013, 143: 798
[13] Chen J, Zhang L, Kang H M, Ding F X. Acta Petrol Sin (Petrol Process Section (陈军, 张鎏, 康慧敏, 丁富新. 石油学报石油加工), 2000, 16(5): 8
[14] Berndt H, Lietz G, Vöiter J. Appl Catal A, 1996, 146: 365
[15] Kolyagin Y G, Ordomsky V V, Khimyak Y Z, Rebrov A I, Fajula F, Ivanova I I, J Catal, 2006, 238: 122
[16] Biscardi J A, Meitzner G D, Iglesia E. J Catal, 1998, 179: 192
[17] Yakerson V I, Vasina T V, Lafer L I, Sytnyk V P, Dykh G L, Mokhov A V, Bragin O V, Minachev K M. Catal Lett, 1989, 3: 339
[18] Li Q H, Mihailova B, Creaser D, Sterte J. Microporous Mesoporous Mater, 2000, 40: 53
[19] Maderia F F, Tayeb K B, Pinard L, Vezin H, Maury S, Cadran N. Appl Catal A, 2012, 443-444: 171
[20] Ni Y M, Sun A M, Wu X L, Hai G L, Hu J L, Li T, Li G X. Microporous Mesoporous Mater, 2011, 143: 435
[21] El-Malki El-M, Van Santen R A, Sachtler W M H, J Phys Chem B, 1999, 103: 4611
[22] Kolyagin Y G, Ordomsky V V, Khimyak Y Z, Rebrov A I, Fajula F, Ivanova I I, J Catal, 2006, 238: 122
[23] Niu X J, Gao J, Miao Q, Dong M, Wang G F, Fan W B, Qin Z F, Wang J G. Microporous Mesoporous Mater, 2014, 197: 252
[24] Bordiga S, Lamberti C, Ricchiardi G, Regli L, Bonino F, Damin A, Lillerud K P, Bjorgen M, Zecchina A. Chem Commun, 2004, 20: 2300
[25] Haase M, Weller H, Henglein A. J Phys Chem, 1988, 92: 482
[26] Liu J X, Ai Sha N L H, He N, Liu G D, Liang C C, Zhang X F, Guo H C. Chem Eng J, 2013, 218: 1
[27] Tholkappiyan R, Vishista K. Physical B, 2014, 448: 177
[28] Qiu P, Lunsford J H, Rosynek M P. Catal Lett, 1998, 52: 37
[29] Bi Y, Wang Y L, Chen X, Yu Z X, Xu L. Chin J Catal (毕怡, 王莹利, 陈欣, 于政锡, 许磊. 催化学报), 2014, 35: 1740
[30] Choudhary V R, Panjala D, Banerjee S. Appl Catal A, 2002, 231: 243