Coordination of manganese porphyrins on amino-functionalized MCM-41 for heterogeneous catalysis of naphthalene hydroxylation

doi:10.1016/S1872-2067(15)60836-1

Abstract

Abstract:

The different amounts of [5,10,15,20-tetrakis-(pentafluorophenyl)porphyrin] manganese chloride (TF₂₀PPMnCl) were immobilized on amino-functionalized MCM-41 for catalysis of the hydroxylation of naphthalene. The samples were characterized by X-ray powder diffraction, N₂ adsorption/ desorption isotherms, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, diffuse reflectance ultraviolet-visible spectroscopy, thermogravimetric and differential scanning calorimetry, and inductively coupled plasma mass spectrometry. The results indicated that the manganese porphyrins were axially coordinated on amino-functionalized MCM-41. The prepared samples showed remarkable catalytic activity in the hydroxylation of naphthalene with meta-chloroperbenzoic acid as the oxidant. The catalyst could be reused several times without loss of its activity.

Key words: Manganese porphyrin, Immobilization, Axial coordination, Naphthalene hydroxylation, Heterogeneous catalysis

Fu Yang, Shuying Gao, Cuirong Xiong, Haiqing Wang, Jin Chen, Yan Kong. Coordination of manganese porphyrins on amino-functionalized MCM-41 for heterogeneous catalysis of naphthalene hydroxylation[J]. Chinese Journal of Catalysis, 2015, 36(7): 1035-1041.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)60836-1

https://www.cjcatal.com/EN/Y2015/V36/I7/1035

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