An investigation of the effects of CeO2 crystal planes on the aerobic oxidative synthesis of imines from alcohols and amines

doi:10.1016/S1872-2067(15)60869-5

Chinese Journal of Catalysis ›› 2015, Vol. 36 ›› Issue (9): 1623-1630.DOI: 10.1016/S1872-2067(15)60869-5

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An investigation of the effects of CeO₂ crystal planes on the aerobic oxidative synthesis of imines from alcohols and amines

Zhixin Zhang^a,b, Yehong Wang^b, Min Wang^b, Jianmin Lü^b, Lihua Li^b, Zhe Zhang^b, Mingrun Li^b, Jingyang Jiang^a, Feng Wang^b

a State Key Laboratory of Fine Chemicals, College of Chemistry, Faculty of Chemical Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024, Liaoning, China;
b State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Received:2015-03-27 Revised:2015-04-19 Online:2015-08-28 Published:2015-09-26
Supported by:
This work was supported by the National Natural Science Foundation of China (21403216, 21303189, 21422308), and Hundred Person Project of the Chinese Academy of Sciences.

Abstract

Abstract:

We herein report the effects of CeO₂ crystal planes on the oxidative coupling of alcohols and amines to form imines. CeO₂ exhibits significant catalytic activity under mild reaction conditions (60℃) during the synthesis of 13 different imines, giving >89% conversions and >90% selectivities. The crystal planes of CeO₂ greatly affect the catalytic performance. Among the crystal planes investigated (the (110), (100) and (111) planes), the (110) plane shows the strongest redox ability and thus the best catalytic activity, generating a 97% yield of the imine at 60℃ in 2 h, because it contains the highest concentration of oxygen vacancies.

Key words: Ceria, Crystal plane effect, Oxidative coupling, Imine, Defect site

Zhixin Zhang, Yehong Wang, Min Wang, Jianmin Lü, Lihua Li, Zhe Zhang, Mingrun Li, Jingyang Jiang, Feng Wang. An investigation of the effects of CeO₂ crystal planes on the aerobic oxidative synthesis of imines from alcohols and amines[J]. Chinese Journal of Catalysis, 2015, 36(9): 1623-1630.

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An investigation of the effects of CeO₂ crystal planes on the aerobic oxidative synthesis of imines from alcohols and amines

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