Host (dealuminated Y zeolite)-guest (trinuclear metal clusters of Co, Mn and Cox/Mny) as nanocomposite catalysts for the epoxidation of cyclohexene

doi:10.1016/S1872-2067(15)60908-1

Abstract

Abstract:

Trinuclear metal clusters of Co, Mn and mixtures of Co/Mn including [Mn₃(O)(CH₃COO)₆-(py)₃]-Y, [Co₃(O)(CH₃COO)₆-(py)₃], [Co₂Mn(O)(CH₃COO)₆-(py)₃]-Y and [CoMn₂(O)(CH₃COO)₆-(py)₃]-Y] were prepared inside the nanocage of dealuminated Y zeolite by the template synthesis method. These catalysts were characterized by Fourier transform infrared, Ultraviolet-visible, field scanning electron microscopy, X-ray diffraction and atomic absorption spectroscopy. The encapsulated metal clusters showed good catalytic activity in the epoxidation of cyclohexene with H₂O₂/O₂. Epoxide yields were 82.5% to 90.7%. NaBr was used as a promoter for the oxidation. The homonuclear metal clusters showed higher catalytic activity than the others and the highest efficiency was with the Mn₃(O)-DAZY compound. The catalytic activity order was Mn₃(O)-DAZY > Co₃(O)-DAZY > Mn₂Co(O)-DAZY > MnCo₂(O)-DAZY.

Key words: Cyclohexene, Epoxide, Metal clusters, Dealuminated Y Zeolite, Cobalt

Maryam Moosavifar, Alieh Navid Arbat, Zolfaghar Rezvani, Kamellia Nejati. Host (dealuminated Y zeolite)-guest (trinuclear metal clusters of Co, Mn and Co_x/Mn_y) as nanocomposite catalysts for the epoxidation of cyclohexene[J]. Chinese Journal of Catalysis, 2015, 36(10): 1719-1725.

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Host (dealuminated Y zeolite)-guest (trinuclear metal clusters of Co, Mn and Co_x/Mn_y) as nanocomposite catalysts for the epoxidation of cyclohexene

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