Rh2O3/mesoporous MOx-Al2O3 (M = Mn, Fe, Co, Ni, Cu, Ba) catalysts: Synthesis, characterization, and catalytic applications

doi:10.1016/S1872-2067(15)60951-2

Abstract

Abstract:

Recently, a one-pot self-assembly method was proposed for the synthesis of mesoporous Al₂O₃ and MO_x-Al₂O₃ composite materials. However, few attempts have been made to use mesoporous MO_x-Al₂O₃ composites to support metal oxides for catalysis. In the present work, mesoporous MO_x-Al₂O₃ (M = Mn, Fe, Co, Ni, Cu, Ba) materials were prepared by a one-pot self-assembly method using Pluronic P123 as a structure-directing agent. The obtained mesoporous materials were loaded with Rh₂O₃ nanoparticles via impregnation with Rh(NO₃)₃ followed by calcination in air at 500 ℃. The resulting catalysts were characterized by X-ray diffraction, N₂ adsorption-desorption measurements, transmission electron microscopy, inductively coupled plasma optical emission spectrometry, X-ray photoelectron spectroscopy, and their catalytic activity and stability for CO oxidation and N₂O decomposition were tested. The Rh₂O₃ nanoparticles were found to be on the order of 1 nm in size and were highly dispersed on the high surface area mesoporous MO_x-Al₂O₃ supports. A number of the Rh₂O₃/mesoporous MO_x-Al₂O₃ catalysts exhibited higher catalytic activity than the Rh₂O₃/mesoporous Al₂O₃ prepared for comparison.

Key words: One-pot synthesis, Mesoporous alumina, Metal oxide, CO oxidation, N₂O decomposition

Huan Liu, Yi Lin, Zhen Ma. Rh₂O₃/mesoporous MO_x-Al₂O₃ (M = Mn, Fe, Co, Ni, Cu, Ba) catalysts: Synthesis, characterization, and catalytic applications[J]. Chinese Journal of Catalysis, 2016, 37(1): 73-82.

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Rh₂O₃/mesoporous MO_x-Al₂O₃ (M = Mn, Fe, Co, Ni, Cu, Ba) catalysts: Synthesis, characterization, and catalytic applications

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