Preparation of a new solid acid and its catalytic performance in di(1-naphthyl)methane hydrocracking

doi:10.1016/S1872-2067(15)61112-3

Abstract

Abstract:

A new solid acid was prepared by trifluoromethanesulfonic acid (TFMSA) impregnation into an acid-treated attapulgite (ATA). Di(1-naphthyl)methane (DNM) hydrocracking was used as the probe reaction to evaluate the catalytic performance of TFMSA/ATA for cleaving C_ar-C_alk bridged bonds in coals. The results show that DNM was specifically hydrocracked to naphthalene and 1-methylnaphthalene over TFMSA/ATA in methanol in the absence of gaseous hydrogen. In particular, TFMSA/ATA was demonstrated to be stable after four cycles with slight loss in catalytic activity. Furthermore, a proposed H⁺ transfer mechanism successfully interprets the TFMSA/ATA-catalyzed hydrocracking reaction of DNM.

Key words: Solid acid, Di(1-naphthyl)methane, Hydrocracking, H⁺ transfer

Meixia Zhao, Xianyong Wei, Zhimin Zong. Preparation of a new solid acid and its catalytic performance in di(1-naphthyl)methane hydrocracking[J]. Chinese Journal of Catalysis, 2016, 37(8): 1324-1330.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)61112-3

https://www.cjcatal.com/EN/Y2016/V37/I8/1324

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