Chinese Journal of Catalysis ›› 2017, Vol. 38 ›› Issue (9): 1574-1580.DOI: 10.1016/S1872-2067(17)62784-0

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Photochemical route for preparing atomically dispersed Pd1/TiO2 catalysts on (001)-exposed anatase nanocrystals and P25

Pengxin Liu, Jie Chen, Nanfeng Zheng   

  1. State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China
  • Received:2016-11-29 Revised:2017-01-05 Online:2017-09-18 Published:2017-09-06
  • Contact: 10.1016/S1872-2067(17)62784-0
  • Supported by:

    This work was supported by the Ministry of Science and Technology of nano major research projects (2015CB932303), and the National Natural Science Foundation of China (21420102001, 21131005, 21333008, 21390390).

Abstract:

Atomically dispersed catalysts have shown promising prospects in catalysis studies. Among all of the developed methods for synthesizing atomically dispersed catalysts, the photochemical approach has recently aroused much attention owing to its simple procedure and mild preparation conditions involved. In the present study, we demonstrate the application of the photochemical method to synthesize atomically dispersed Pd catalysts on (001)-exposed anatase nanocrystals and commer-cial TiO2 (P25). The as-prepared catalysts exhibit both high activity and stability in the hydrogena-tion of styrene and catalytic oxidation of CO.

Key words: Single-atom catalyst, Photochemical preparation, Ultraviolet-assisted preparation, Styrene hydrogenation, Carbon monoxide oxidation