In2O3-modified Cu/SiO2 as an active and stable catalyst for the hydrogenation of methyl acetate to ethanol

doi:10.1016/S1872-2067(17)62932-2

Abstract

Abstract:

A series of indium oxide-modified Cu/SiO₂ catalysts were synthesized and used to produce ethanol via methyl acetate hydrogenation. In-Cu/SiO₂ catalyst containing 1.0 wt% In₂O₃ exhibited the best catalytic activity and stability. The physicochemical properties of the synthesized catalysts were investigated using several characterization methods and the results showed that introducing suitable indium to Cu/SiO₂ increased the copper dispersion, diminished the copper crystallite size, and enriched the surface Cu⁺ concentration. Furthermore, the Cu/SiO₂ catalyst gradually deactivated during the stability test, which was mainly attributed to copper sintering and the valence change in surface copper species. In contrast, indium addition can inhibit the thermal transmigration and accumulation of copper nanoparticles to stabilize the catalyst.

Key words: Methyl acetate, Hydrogenation, Indium, Cu/SiO₂ catalyst, Ethanol

Yu Zhang, Chenliang Ye, Cuili Guo, Changna Gan, Xinmeng Tong. In₂O₃-modified Cu/SiO₂ as an active and stable catalyst for the hydrogenation of methyl acetate to ethanol[J]. Chinese Journal of Catalysis, 2018, 39(1): 99-108.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(17)62932-2

https://www.cjcatal.com/EN/Y2018/V39/I1/99

References

[1] J. Pelley, Environ. Sci. Technol., 2002, 35, 405A.
[2] D. Keeney, Environ. Sci. Technol., 2008, 43, 8-11.
[3] J. Goldemberg, Science, 2007, 315, 808-810.
[4] Y. H. Liu, N. Zhao, H. Xian, Q. P. Cheng, Y. S. Tan, N. Tsubaki, X. G. Li, ACS Appl. Mater. Interfaces, 2015, 7, 8398-8403.
[5] C. L. Ye, C. L. Guo, C. W. Sun, Y. Zhang, RSC Adv., 2016, 6, 113796-113802.
[6] Y. F. Zhu, Y. L. Zhu, G. Q. Ding, S. H. Zhu, H. Y. Zheng, Y. W. Li, Appl. Catal. A, 2013, 468, 296-304.
[7] T. Turek, D. L. Trimm, N. W. Cant, Catal. Rev. Sci. Eng., 1994, 36, 645-683.
[8] J. Ding, J. Zhang, C. Zhang, K. F. Liu, H. C. Xiao, F. H. Kong, J. G. Chen, Appl. Catal. A, 2015, 508, 68-79.
[9] H. Y. Qin, C. L. Guo, C. W. Sun, J. L. Zhang, J. Mol. Catal. A, 2015, 409, 79-84.
[10] C. Wen, A. Y. Yin, Y. Y. Cui, X. L. Yang, W. L. Dai, K. N. Fan, Appl. Catal. A, 2013, 458, 82-89.
[11] X. H. Dong, X. G. Ma, H. Y. Xu, Q. J. Ge, Catal. Sci. Technol., 2016, 6, 4151-4158.
[12] Y. N. Wang, X. P. Duan, J. W. Zheng, H. Q. Lin, Y. Z. Yuan, H. Ariga, S. Takakusagi, K. Asakura, Catal. Sci. Technol., 2012, 2, 1637-1639.
[13] X. L. Zheng, H. Q. Lin, J. W. Zheng, H. Ariga, K. Asakura, Y. Z. Yuan, Top. Catal., 2014, 57, 1015-1025.
[14] Z. He, H. Q. Lin, P. He, Y. Z. Yuan, J. Catal., 2011, 277, 54-63.
[15] A. Y. Yin, C. Wen, X. Y. Guo, W. L. Dai, K. N. Fan, J. Catal., 2011, 280, 77-88.
[16] X. L. Zheng, H. Q. Lin, J. W. Zheng, X. P. Duan, Y. Z. Yuan, ACS Catal., 2013, 3, 2738-2749.
[17] Y. Matsumura, H. Ishibe, J. Power Sources, 2012, 209, 72-80.
[18] G. Onyestyák, S. Harnos, D. Kalló, Catal. Commun., 2012, 26, 19-24.
[19] S. Harnos, G. Onyestyák, D. Kalló, Microporous Mesoporous Mater., 2013, 167, 109-116.
[20] C. L. Ye, C. L. Guo, J. L. Zhang, Fuel Process. Technol., 2016, 143, 219-224.
[21] Q. Hu, G. L. Fan, S. Y. Zhang, L. Yang, F. Li, J. Mol. Catal. A, 2015, 397, 134-141.
[22] A. Dandekar, M. A. Vannice, J. Catal., 1998, 178, 621-639.
[23] T. Popa, Y. Zhang, E. Jin, M. Fan, Appl. Catal. A, 2015, 505, 52-61.
[24] S. F. Ji, T. Jiang, K. Xu, S. B. Li, Appl. Surf. Sci., 1998, 133, 231-238.
[25] A. Y. Yin, X. Y. Guo, W. L. Dai, K. N. Fan, J. Phys. Chem. C, 2009, 113, 11003-11013.
[26] K. R. Devi, S. D. Meetei, S. D. Singh, Mater. Charact., 2016, 114, 197-203.
[27] T. M. Ding, H. S. Tian, J. C. Liu, W. B. Wu, J. T. Yu, Chin. J. Catal., 2016, 37, 484-493.
[28] R. Van den Berg, C. F. Elkjaer, C. J. Gommes, I. Chorkendorff, J. Sehested, P. E. de Jongh, K. P. de Jong, S. Helveg, J. Am. Chem. Soc., 2016, 138, 3433-3442.
[29] L. M. He, H. Y. Cheng, G. F. Liang, Y. C. Yu, F. Y. Zhao, Appl. Catal. A, 2013, 452, 88-93.
[30] Y. Y. Zhu, S. R. Wang, L. J. Zhu, X. L. Ge, X. B. Li, Z. Y. Luo, Catal. Lett., 2010, 135, 275-281.
[31] Y. J. Zhao, S. Zhao, Y. C. Geng, Y. L. Shen, H. R. Yue, J. Lv, S. D. Wang, X. B. Ma, Catal. Today, 2016, 276, 28-35.
[32] X. Yu, S. B. Zhai, W. C. Zhu, S. Gao, J. B. Yan, H. J. Yuan, L. L. Chen, J. H. Luo, W. X. Zhang, Z. L. Wang, J. Chem. Sci., 2014, 126, 1013-1020.
[33] L. F. Chen, P. J. Guo, M. H. Qiao, S. R. Yan, H. X. Li, W. Shen, H. L. Xu, K. N. Fan, J. Catal., 2008, 257, 172-180.
[34] M. Tahir, B. Tahir, N. A. Saidina Amin, H. Alias, Appl. Surf. Sci., 2016, 389, 46-55.
[35] R. K. Chava, M. Kang, J. Alloys Compd., 2017, 692, 67-76.
[36] A. Y. Yin, X. Y. Guo, K. N. Fan, W. L. Dai, Appl. Catal. A, 2010, 377, 128-133.
[37] W. Di, J. H. Cheng, S. X. Tian, J. Li, J. Y. Chen, Q. Sun, Appl. Catal. A, 2016, 510, 244-259.
[38] C. J. G. Van Der Grift, A. F. H. Wielers, A. Mulder, J. W. Geus, Thermochim. Acta, 1990, 171, 95-113.
[39] E. Poels, D. Brands, Appl. Catal. A, 2000, 191, 83-96.
[40] J. D. Lin, X. Q. Zhao, Y. H. Cui, H. B. Zhang, D. W. Liao, Chem. Commun., 2012, 48, 1177-1179.
[41] K. H. Sun, Z. G. Fan, J. Y. Ye, J. M. Yan, Q. F. Ge, Y. N. Li, W. J. He, W. M. Yang, C. J. Liu, J. CO₂ Util., 2015, 12, 1-6.

In₂O₃-modified Cu/SiO₂ as an active and stable catalyst for the hydrogenation of methyl acetate to ethanol

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

[1]	Jiachen Sun, Sai Chen, Donglong Fu, Wei Wang, Xianhui Wang, Guodong Sun, Chunlei Pei, Zhi-Jian Zhao, Jinlong Gong. Role of oxygen transfer and surface reaction in catalytic performance of VO_x-Ce_1‒_xZr_xO₂ for propane dehydrogenation [J]. Chinese Journal of Catalysis, 2023, 52(9): 217-227.
[2]	Shuanglong Zhou, Liang Zhao, Zheng Lv, Yu Dai, Qi Zhang, Jianping Lai, Lei Wang. The nature of local oxygen radical boosts electrocatalytic ethanol to selectively generate CO₂ [J]. Chinese Journal of Catalysis, 2023, 52(9): 154-163.
[3]	Xin Liu, Maodi Wang, Yiqi Ren, Jiali Liu, Huicong Dai, Qihua Yang. Construction of modularized catalytic system for transfer hydrogenation: Promotion effect of hydrogen bonds [J]. Chinese Journal of Catalysis, 2023, 52(9): 207-216.
[4]	Wei Qiao, Lice Yu, Jinfa Chang, Fulin Yang, Ligang Feng. Efficient bi-functional catalysis of coupled MoSe₂ nanosheet/Pt nanoparticles for methanol-assisted water splitting [J]. Chinese Journal of Catalysis, 2023, 51(8): 113-123.
[5]	Lu Cheng, Xuning Chen, P. Hu, Xiao-Ming Cao. Advantages and limitations of hydrogen peroxide for direct oxidation of methane to methanol at mono-copper active sites in Cu-exchanged zeolites [J]. Chinese Journal of Catalysis, 2023, 51(8): 135-144.
[6]	Bo Zhou, Jianqiao Shi, Yimin Jiang, Lei Xiao, Yuxuan Lu, Fan Dong, Chen Chen, Tehua Wang, Shuangyin Wang, Yuqin Zou. Enhanced dehydrogenation kinetics for ascorbic acid electrooxidation with ultra-low cell voltage and large current density [J]. Chinese Journal of Catalysis, 2023, 50(7): 372-380.
[7]	Xuan Li, Xingxing Jiang, Yan Kong, Jianju Sun, Qi Hu, Xiaoyan Chai, Hengpan Yang, Chuanxin He. Interface engineering of a GaN/In₂O₃ heterostructure for highly efficient electrocatalytic CO₂ reduction to formate [J]. Chinese Journal of Catalysis, 2023, 50(7): 314-323.
[8]	Shiyao Liu, Yutong Gong, Xiao Yang, Nannan Zhang, Huibin Liu, Changhai Liang, Xiao Chen. Acid-durable intermetallic CaNi₂Si₂ catalyst with electron-rich Ni sites for aqueous phase hydrogenation of unsaturated organic anhydrides/acids [J]. Chinese Journal of Catalysis, 2023, 50(7): 260-272.
[9]	Xianquan Li, Jifeng Pang, Yujia Zhao, Pengfei Wu, Wenguang Yu, Peifang Yan, Yang Su, Mingyuan Zheng. Ethanol dehydrogenation to acetaldehyde over a Cu^δ⁺-based Cu-MFI catalyst [J]. Chinese Journal of Catalysis, 2023, 49(6): 91-101.
[10]	Si-Yuan Xia, Qi-Yuan Li, Shi-Nan Zhang, Dong Xu, Xiu Lin, Lu-Han Sun, Jingsan Xu, Jie-Sheng Chen, Guo-Dong Li, Xin-Hao Li. Size-dependent electronic interface effect of Pd nanocube-based heterojunctions on universally boosting phenol hydrogenation reactions [J]. Chinese Journal of Catalysis, 2023, 49(6): 180-187.
[11]	Yanan Xing, Leilei Kang, Jingyuan Ma, Qike Jiang, Yang Su, Shengxin Zhang, Xiaoyan Xu, Lin Li, Aiqin Wang, Zhi-Pan Liu, Sicong Ma, Xiao Yan Liu, Tao Zhang. Sn₁Pt single-atom alloy evolved stable PtSn/nano-Al₂O₃ catalyst for propane dehydrogenation [J]. Chinese Journal of Catalysis, 2023, 48(5): 164-174.
[12]	Fengwei Zhang, Hefang Guo, Mengmeng Liu, Yang Zhao, Feng Hong, Jingjing Li, Zhengping Dong, Botao Qiao. Enhancing the chemoselective hydrogenation of nitroarenes: Designing a novel surface-strained carbon-based Pt nanocatalyst [J]. Chinese Journal of Catalysis, 2023, 48(5): 195-204.
[13]	Runze Liu, Xue Shao, Chang Wang, Weili Dai, Naijia Guan. Reaction mechanism of methanol-to-hydrocarbons conversion: Fundamental and application [J]. Chinese Journal of Catalysis, 2023, 47(4): 67-92.
[14]	Eun Hyup Kim, Min Hee Lee, Jeehye Kim, Eun Cheol Ra, Ju Hyeong Lee, Jae Sung Lee. Synergy between single atoms and nanoclusters of Pd/g-C₃N₄ catalysts for efficient base-free CO₂ hydro-genation to formic acid [J]. Chinese Journal of Catalysis, 2023, 47(4): 214-221.
[15]	Chenggong Yang, Donge Wang, Rong Huang, Jianqiang Han, Na Ta, Huaijun Ma, Wei Qu, Zhendong Pan, Congxin Wang, Zhijian Tian. Highly active and stable MoS₂-TiO₂ nanocomposite catalyst for slurry-phase phenanthrene hydrogenation [J]. Chinese Journal of Catalysis, 2023, 46(3): 125-136.