Wheat flour-derived N-doped mesoporous carbon extrudes as an efficient support for Au catalyst in acetylene hydrochlorination

doi:10.1016/S1872-2067(18)63109-2

Chinese Journal of Catalysis ›› 2018, Vol. 39 ›› Issue (10): 1664-1671.DOI: 10.1016/S1872-2067(18)63109-2

• Articles • Previous Articles Next Articles

Wheat flour-derived N-doped mesoporous carbon extrudes as an efficient support for Au catalyst in acetylene hydrochlorination

Jie Liu, Guojun Lan, Yiyang Qiu, Xiaolong Wang, Ying Li

Institute of Industrial Catalysis, Zhejiang University of Technology, Hangzhou 310032, Zhejiang, China

Received:2018-04-06 Revised:2018-05-19 Online:2018-10-18 Published:2018-08-03
Contact: 10.1016/S1872-2067(18)63109-2
Supported by:
This work was supported by Zhejiang Provincial Natural Science Foundation of China (LY17B030010).

Abstract

Abstract:

We recently reported an N-doped mesoporous carbon (N-MC) extrudate, with major quaternary N species, prepared by a cheap and convenient method through direct carbonization of wheat flour with silica, which has excellent catalytic performance in acetylene hydrochlorination. Herein, we examined the activity of Au supported on N-MC (Au/N-MC) and compared it with that of Ausupported on nitrogen-free mesoporous carbon (Au/MC). The acetylene conversion of Au/N-MC was 50% at 180℃ with an acetylene space velocity of 600 h^-1 and V_HCl/V_C2H2 of 1.1, which was double the activity of Au/MC (25%). The introduced nitrogen atoms acted as anchor sites that stabilized the Au³⁺ species and inhibited the reduction of Au³⁺ to Au⁰ during the preparation of Au/N-MC catalysts.

Key words: Au catalyst, Mercury free catalyst, Acetylene hydrochlorination, N doped mesoporous carbon

Jie Liu, Guojun Lan, Yiyang Qiu, Xiaolong Wang, Ying Li. Wheat flour-derived N-doped mesoporous carbon extrudes as an efficient support for Au catalyst in acetylene hydrochlorination[J]. Chinese Journal of Catalysis, 2018, 39(10): 1664-1671.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(18)63109-2

https://www.cjcatal.com/EN/Y2018/V39/I10/1664

References

[1] H. Schobert, Chem. Rev., 2014, 114, 1743-1760.
[2] M. Y. Zhu, Q. Q. Wang, K. Chen, Y. Wang, C. F. Huang, H. Dai, F. Yu, L. H. Kang, B. Dai, ACS Catal., 2015, 5, 5306-5316.
[3] G. J. Hutchings, J. Catal., 1985, 96, 292-295.
[4] C. J. Davies, P. J. Miedziak, G. L. Brett, G. J. Hutchings, Chin. J. Catal., 2016, 37, 1600-1607.
[5] P. Johnston, N. Carthey, G. J. Hutchings, J. Am. Chem. Soc., 2015, 137, 14548-14557.
[6] Y. L. Cao, S. J. Mao, M. M. Li, Y. Q. Chen, Y. Wang, ACS Catal., 2017, 7, 8090-8112.
[7] X. Y. Li, M. Y. Zhu, B. Dai, Appl. Catal. B, 2013, 142, 234-240.
[8] B. Dai, X. Y. Li, J. L. Zhang, F. Yu, M. Y. Zhu, Chem. Eng. Sci., 2015, 135, 472-478.
[9] J. Zhao, J. T. Xu, J. H. Xu, T. T. Zhang, X. X. Di, J. Ni, X. N. Li, Chem. Eng. J., 2015, 262, 1152-1160.
[10] L. J. Hou, J. L. Zhang, Y. F. Pu, W. Li, RSC Adv., 2016, 6, 18026-18032.
[11] N. Xu, M. Y. Zhu, J. L. Zhang, H. Y. Zhang, B. Dai, RSC Adv., 2015, 5, 86172-86178.
[12] X. Y. Li, Y. Wang, L. H. Kang, M. Y. Zhu, B. Dai, J. Catal., 2014, 311, 288-294.
[13] Y. Yang, G. J. Lan, X. L. Wang, Y. Li, Chin. J. Catal., 2016, 37, 1242-1248.
[14] X. Y. Li, X. L. Pan, L. Yu, P. J. Ren, X. Wu, L. T. Sun, F. Jiao, X. H. Bao, Nat. Commun., 2014, 5, 3688.
[15] S. L. Chao, F. Zou, F. F. Wan, X. B. Dong, Y. L. Wang, Y. X. Wang, Q. X. Guan, G. C. Wang, W. Li, Sci. Rep., 2017, 7, 39789.
[16] G. J. Lan, Y. Wang, Y. Y. Qiu, X. L. Wang, J. Liang, W. F. Han, H. D. Tang, H. Z. Liu, J. Liu, Y. Li, Chem. Commun., 2018, 54, 623-626.
[17] Z. L. Jiang, G. J. Lan, X. Y. Liu, H. D. Tang, Y. Li, Catal. Sci. Technol., 2016, 6, 7259-7266.
[18] W. Jiang, Y. Li, W. F. Han, Y. P. Zhou, H. D. Tang, H. Z. Liu, J. Energy Chem., 2014, 23, 443-452.
[19] M. Conte, C. J. Davies, D. J. Morgan, T. E. Davies, D. J. Elias, A. F. Carley, P. Johnston, G. J. Hutchings, J. Catal., 2013, 297, 128-136.
[20] M. Conte, C. J. Davies, D. J. Morgan, A. F. Carley, P. Johnston, G. J. Hutchings, Catal. Lett., 2014, 144, 1-8.
[21] J. Zhao, B. Wang, X. Xu, Y. Yu, S. Di, H. Xu, Y. Zhai, H. He, L. Guo, Z. Pan, X. Li, J. Catal., 2017, 350, 149-158.
[22] B. Nkosi, M. D. Adams, N. J. Coville, G. J. Hutchings, J. Catal., 1991, 128, 378-386.
[23] S. G. Zhang, S. Tsuzuki, K. Ueno, K. Dokko, M. Watanabe, Angew. Chem. Int. Ed., 2015, 54, 1302-1306.
[24] C. F. Huang, M. Y. Zhu, L. H. Kang, X. Y. Li, B. Dai, Chem. Eng. J., 2014, 242, 69-75.
[25] X. Liu, M. Conte, D. Elias, L. Lu, D. J. Morgan, S. J. Freakley, P. Johnston, C. J. Kiely, G. J. Hutchings, Catal. Sci. Technol., 2016, 6, 5144-5153.
[26] G. Malta, S. A. Kondrat, S. J. Freakley, C. J. Davies, L. Lu, S. Dawson, A. Thetford, E. K. Gibson, D. J. Morgan, W. Jones, P. P. Wells, P. Johnston, C. R. A. Catlow, C. J. Kiely, G. J. Hutchings, Science, 2017, 355, 1399-1402.
[27] G. Malta, S. J. Freakley, S. A. Kondrat, G. J. Hutchings, Chem. Commun., 2017, 53, 11733-11746.

Wheat flour-derived N-doped mesoporous carbon extrudes as an efficient support for Au catalyst in acetylene hydrochlorination

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 8

Recommended Articles

Metrics

[1]	Xingzong Dong, Guangye Liu, Zhaoan Chen, Quan Zhang, Yunpeng Xu, Zhongmin Liu. Enhanced performance of Pd-[DBU][Cl]/AC mercury-free catalysts in acetylene hydrochlorination [J]. Chinese Journal of Catalysis, 2023, 46(3): 137-147.
[2]	Qing Yu, Shiyi Wang, Mengru Wang, Xiaoling Mou, Ronghe Lin, Yunjie Ding. M/C₃N₄/AC (M = Au, Pt, Ru)-catalyzed acetylene coupling with ethylene dichloride: How effective are the bifunctionalities? [J]. Chinese Journal of Catalysis, 2022, 43(3): 820-831.
[3]	Fan Wu, Lei He, Wen-Cui Li, Rao Lu, Yang Wang, An-Hui Lu. Highly dispersed boron-nitride/CuO_x-supported Au nanoparticles for catalytic CO oxidation at low temperatures [J]. Chinese Journal of Catalysis, 2021, 42(3): 388-395.
[4]	Jia Zhao, Saisai Wang, Bolin Wang, Yuxue Yue, Chunxiao Jin, Jinyue Lu, Zheng Fang, Xiangxue Pang, Feng Feng, Lingling Guo, Zhiyan Pan, Xiaonian Li. Acetylene hydrochlorination over supported ionic liquid phase (SILP) gold-based catalyst: Stabilization of cationic Au species via chemical activation of hydrogen chloride and corresponding mechanisms [J]. Chinese Journal of Catalysis, 2021, 42(2): 334-346.
[5]	Xiaolong Wang, Guojun Lan, Zaizhe Cheng, Wenfeng Han, Haodong Tang, Huazhang Liu, Ying Li. Carbon-supported ruthenium catalysts prepared by a coordination strategy for acetylene hydrochlorination [J]. Chinese Journal of Catalysis, 2020, 41(11): 1683-1691.
[6]	Jian Li, Jiangtao Fan, Sajjad Ali, Guojun Lan, Haodong Tang, Wenfeng Han, Huazhang Liu, Bo Li, Ying Li. The origin of the extraordinary stability of mercury catalysts on the carbon support: the synergy effects between oxygen groups and defects revealed from a combined experimental and DFT study [J]. Chinese Journal of Catalysis, 2019, 40(2): 141-146.
[7]	Hang Li, Botao Wu, Jianhui Wang, Fumin Wang, Xubin Zhang, Gang Wang, Haichao Li. Efficient and stable Ru(III)-choline chloride catalyst system with low Ru content for non-mercury acetylene hydrochlorination [J]. Chinese Journal of Catalysis, 2018, 39(11): 1770-1781.
[8]	Xinping Duan, Yan Yin, Xuelin Tian, Jinhuo Ke, Zhaojun Wen, Jianwei Zheng, Menglin Hu, Linmin Ye, Youzhu Yuan. C-X(X=Cl, Br, I) bond dissociation energy as a descriptor for the redispersion of sintered Au/AC catalysts [J]. Chinese Journal of Catalysis, 2016, 37(10): 1794-1803.