Hierarchical 0D/2D Co3O4 hybrids rich in oxygen vacancies as catalysts towards styrene epoxidation reaction

doi:10.1016/S1872-2067(18)63133-X

Abstract

Abstract:

Great efforts have been devoted to the developing of simple, efficient and stable heterogeneous catalysts for the styrene epoxidation reaction (SER). Metal oxides can be of industrial importance by offering an economic and green route for selectively converting styrene into styrene oxide (SO). Herein, by treating the pristine porous 2D Co₃O₄ sheets with NaBH₄ solution, a novel hierarchical structure, i.e., 0D Co₃O₄ nanoparticles decorated on 2D porous Co₃O₄ sheets, was obtained. This simple solution reduction strategy not only realizes the morphology evolution, but also induces the modification of the valence states of metal ions and the simultaneous generation of surface oxygen vacancies. The hierarchical 0D/2D Co₃O₄ hybrids rich in oxygen vacancies (OV-Co₃O₄) exhibit a much better SER performance than the Co₃O₄ sheets (P-Co₃O₄), with the yield of SO more than doubled. The excellent catalytic performance of the OV-Co₃O₄ can be ascribed to the synergistic effects regarding the hierarchical porous structure, the modification of surface chemical composition and the creation of surface oxygen vacancies.

Key words: Co₃O₄, Reduction, Oxygen vacancies, Styrene, Epoxidation

Jiangyong Liu, Tingting Chen, Panming Jian, Lixia Wang. Hierarchical 0D/2D Co₃O₄ hybrids rich in oxygen vacancies as catalysts towards styrene epoxidation reaction[J]. Chinese Journal of Catalysis, 2018, 39(12): 1942-1950.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(18)63133-X

https://www.cjcatal.com/EN/Y2018/V39/I12/1942

References

[1] S. C. Hammer, G. Kubik, E. Watkins, S. Huang, H. Minges, F. H. Arnold, Science, 2017, 358, 215-218.
[2] J. Liu, Z. Wang, P. Jian, R. Jian, J. Colloid Interface Sci., 2018, 517, 144-154.
[3] G. Zhang, D. E. Wang, P. Feng, S. Shi, C. Wang, A. Zheng, G. Lü, Z. Tian, Chin. J. Catal., 2017, 38, 1207-1215.
[4] J. Liu, T. Chen, X. Yan, Z. Wang, R. Jian, P. Jian, E. Yuan, Catal. Commun., 2018, 109, 71-75.
[5] J. Liu, Y. Zhang, X. Yan, Z. Wang, F. Wu, S. Fang, P. Jian, Can. J. Chem. Eng., 2018, http://dx.doi.org/10.1002/cjce.23116.
[6] M. Turner, V. B. Golovko, O. P. H. Vaughan, P. Abdulkin, A. Berenguer-Murcia, M. S. Tikhov, B. F. G. Johnson, R. M. Lambert, Nature, 2008, 454, 981-983.
[7] M. S. C. Chan, E. Marek, S. A. Scott, J. S. Dennis, J. Catal., 2018, 359, 1-7.
[8] Q. Zhang, Y. Guo, W. Zhan, Y. Guo, L. Wang, Y. Wang, G. Lu, Chin. J. Catal., 2017, 38, 65-72.
[9] K. Yuan, T. Song, D. Wang, Y. Zou, J. Li, X. Zhang, Z. Tang, W. Hu, Nanoscale, 2018, 10, 1591-1597.
[10] N. Li, B. Yang, M. Liu, Y. Chen, J. Zhou, Chin. J. Catal., 2017, 38, 831-843.
[11] Y. Fang, Y. Chen, X. Li, X. Zhou, J. Li, W. Tang, J. Huang, J. Jin, J. Ma, J. Mol. Catal. A, 2014, 392, 16-21.
[12] J. Liu, S. Fang, R. Jian, F. Wu, P. Jian, Powder Technol., 2018, 329, 19-24.
[13] F. Pan, B. Zhang, W. Cai, Catal. Commun., 2017, 98, 121-125.
[14] B. Li, X. Luo, J. Huang, X. Wang, Z. Liang, Chin. J. Catal., 2017, 38, 518-528.
[15] J. Liu, T. Chen, P. Jian, L. Wang, X. Yan, J. Colloid Interface Sci., 2018, 526, 295-301.
[16] J. Sebastian, K. M. Jinka, R. V. Jasra, J. Catal., 2006, 244, 208-218.
[17] G. Xu, Q. H. Xia, X. H. Lu, Q. Zhang, H. J. Zhan, J. Mol. Catal. A, 2007, 266, 180-187.
[18] D. E. Hamilton, R. S. Drago, A. Zombeck, J. Am. Chem. Soc., 1987, 109, 374-379.
[19] B. Rhodes, S. Rowling, P. Tidswell, S. Woodward, S. M. Brown, J. Mol. Catal. A, 1997, 116, 375-384.
[20] Q. Tang, Y. Wang, J. Liang, P. Wang, Q. Zhang, H. Wan, Chem. Commun., 2004, 440-441.
[21] Y. Luo, J. Lin, Microporous Mesoporous Mater., 2005, 86, 23-30.
[22] Y. Li, S. Zhao, Q. Hu, Z. Gao, Y. Liu, J. Zhang, Y. Qin, Catal. Sci. Technol., 2017, 7, 2032-2038.
[23] A. P. S. Oliveira, I. S. Gomes, A. S. B. Neto, A. C. Oliveira, J. M. Filho, G. D. Saraiva, J. M. Soares, S. Tehuacanero-Cuapa, Mol. Catal., 2017, 436, 29-42.
[24] F. Yang, S. Zhou, S. Gao, X. Liu, S. Long, Y. Kong, Microporous Mesoporous Mater., 2017, 238, 69-77.
[25] A. de Brito S. Neto, L. G. Pinheiro, J. M. Filho, A. C. Oliveira, Fuel, 2015, 150, 305-317.
[26] S. Mandal, A. SinhaMahapatra, B. Rakesh, R. Kumar, A. Panda, B. Chowdhury, Catal. Commun., 2011, 12, 734-738.
[27] A. Askarinejad, M. Bagherzadeh, A. Morsali, Appl. Surf. Sci., 2010, 256, 6678-6682.
[28] N. S. Patil, B. S. Uphade, P. Jana, S. K. Bharagava, V. R. Choudhary, J. Catal., 2004, 223, 236-239.
[29] S. B. Kumar, S. P. Mirajkar, G. C. G. Pais, P. Kumar, R. Kumar, J. Catal., 1995, 156, 163-166.
[30] Q. Tang, Q. Zhang, H. Wu, Y. Wang, J. Catal., 2005, 230, 384-397.
[31] N. Masunga, G. S. Tito, R. Meijboom, Appl. Catal. A, 2018, 552, 154-167.
[32] C. Weerakkody, S. Biswas, W. Song, J. He, N. Wasalathanthri, S. Dissanayake, D. A. Kriz, B. Dutta, S. L. Suib, Appl. Catal. B, 2018, 221, 681-690.
[33] C. Zhu, S. Fu, D. Du, Y. Lin, Chem. Eur. J., 2016, 22, 4000-4007.
[34] H. Chen, M. Yang, S. Tao, G. Chen, Appl. Catal. B, 2017, 209, 648-656.
[35] H. Sun, Y. Zhao, K. Molhave, M. Zhang, J. Zhang, Nanoscale, 2017, 9, 14431-14441.
[36] J. Liu, D. Wang, M. Wang, D. Kong, Y. Zhang, J. F. Chen, L. Dai, Chem. Eng. Technol., 2016, 39, 891-898.
[37] Y. Lou, L. Wang, Z. Zhao, Y. Zhang, Z. Zhang, G. Lu, Y. Guo, Y. Guo, Appl. Catal. B, 2014, 146, 43-49.
[38] L. Li, J. Yan, T. Wang, Z. J. Zhao, J. Zhang, J. Gong, N. Guan, Nat. Commun., 2015, 6, 5881.
[39] Z. Xiao, Y. Wang, Y. C. Huang, Z. Wei, C. L. Dong, J. Ma, S. Shen, Y. Li, S. Wang, Energy Environ. Sci., 2017, 10, 2563-2569.
[40] Z. Wang, W. Wang, L. Zhang, D. Jiang, Catal. Sci. Technol., 2016, 6, 3845-3853.
[41] J. Liu, X. Yan, L. Wang, L. Kong, P. Jian, J. Colloid Interface Sci., 2017, 497, 102-107.
[42] D. Wang, Z. Y. Wang, Q. Q. Zhan, Y. Pu, J. X. Wang, N. R. Foster, L. M. Dai, Engineering, 2017, 3, 402-408.
[43] Y. P. Zhu, T. Y. Ma, M. Jaroniec, S. Z. Qiao, Angew. Chem. Int. Ed., 2017, 56, 1324-1328.
[44] Y. Wang, T. Zhou, K. Jiang, P. Da, Z. Peng, J. Tang, B. Kong, W. B. Cai, Z. Yang, G. Zheng, Adv. Energy Mater., 2014, 4, 201400696.
[45] L. Xu, Q. Jiang, Z. Xiao, X. Li, J. Huo, S. Wang, L. Dai, Angew. Chem. Int. Ed., 2016, 55, 5277-5281.
[46] L. Li, Y. Li, S. Gao, N. Koshizaki, J. Mater. Chem., 2009, 19, 8366-8371.
[47] S. K. Pardeshi, R. Y. Pawar, J. Mol. Catal. A, 2011, 334, 35-43.
[48] J. Sun, Q. Kan, Z. Li, G. Yu, H. Liu, X. Yang, Q. Huo, J. Guan, RSC Adv., 2014, 4, 2310-2317.
[49] V. R. Choudhary, R. Jha, P. Jana, Catal. Commun., 2008, 10, 205-207.
[50] R. Hu, P. Yang, Y. Pan, Y. Li, Y. He, J. Feng, D. Li, Dalton Trans., 2017, 46, 13463-13471.
[51] J. Liu, Z. Wang, X. Yan, P. Jian, J. Colloid Interface Sci., 2017, 505, 789-795.
[52] J. Liu, C. Ran, Y. Pu, J. X. Wang, D. Wang, J. F. Chen, Can. J. Chem. Eng., 2017, 95, 1297-1304.
[53] H. Su, Z. Li, Q. Huo, J. Guan, Q. Kan, RSC Adv., 2014, 4, 9990-9996.
[54] P. Zhou, Y. Wang, C. Xie, C. Chen, H. Liu, R. Chen, J. Huo, S. Wang, Chem. Commun., 2017, 53, 11778-11781.
[55] D. Chen, C. L. Dong, Y. Zou, D. Su, Y. C. Huang, L. Tao, S. Dou, S. Shen, S. Wang, Nanoscale, 2017, 9, 11969-11975.
[56] Y. Wang, M. Qiao, Y. Li, S. Wang, Small, 2018, 14, 201800136.
[57] E. W. McFarland, H. Metiu, Chem. Rev., 2013, 113, 4391-4427.
[58] J. M. López, A. L. Gilbank, T. García, B. Solsona, S. Agouram, L. Torrente-Murciano, Appl. Catal. B, 2015, 174-175, 403-412.

Hierarchical 0D/2D Co₃O₄ hybrids rich in oxygen vacancies as catalysts towards styrene epoxidation reaction

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

[1]	Ji Zhang, Aimin Yu, Chenghua Sun. Theoretical insights into heteronuclear dual metals on non-metal doped graphene for nitrogen reduction reaction [J]. Chinese Journal of Catalysis, 2023, 52(9): 263-270.
[2]	Jin-Nian Hu, Ling-Chan Tian, Haiyan Wang, Yang Meng, Jin-Xia Liang, Chun Zhu, Jun Li. Theoretical screening of single-atom electrocatalysts of MXene-supported 3d-metals for efficient nitrogen reduction [J]. Chinese Journal of Catalysis, 2023, 52(9): 252-262.
[3]	Yan Hong, Qi Wang, Ziwang Kan, Yushuo Zhang, Jing Guo, Siqi Li, Song Liu, Bin Li. Recent progress in advanced catalysts for electrochemical nitrogen reduction reaction to ammonia [J]. Chinese Journal of Catalysis, 2023, 52(9): 50-78.
[4]	Yong Liu, Xiaoli Zhao, Chang Long, Xiaoyan Wang, Bangwei Deng, Kanglu Li, Yanjuan Sun, Fan Dong. In situ constructed dynamic Cu/Ce(OH)_x interface for nitrate reduction to ammonia with high activity, selectivity and stability [J]. Chinese Journal of Catalysis, 2023, 52(9): 196-206.
[5]	Hui Gao, Gong Zhang, Dongfang Cheng, Yongtao Wang, Jing Zhao, Xiaozhi Li, Xiaowei Du, Zhi-Jian Zhao, Tuo Wang, Peng Zhang, Jinlong Gong. Steering electrochemical carbon dioxide reduction to alcohol production on Cu step sites [J]. Chinese Journal of Catalysis, 2023, 52(9): 187-195.
[6]	Sikai Wang, Xiang-Ting Min, Botao Qiao, Ning Yan, Tao Zhang. Single-atom catalysts: In search of the holy grails in catalysis [J]. Chinese Journal of Catalysis, 2023, 52(9): 1-13.
[7]	Wen Zhang, Cai-Cai Song, Jia-Wei Wang, Shu-Ting Cai, Meng-Yu Gao, You-Xiang Feng, Tong-Bu Lu. Bidirectional host-guest interactions promote selective photocatalytic CO₂ reduction coupled with alcohol oxidation in aqueous solution [J]. Chinese Journal of Catalysis, 2023, 52(9): 176-186.
[8]	Xinyi Zou, Jun Gu. Strategies for efficient CO₂ electroreduction in acidic conditions [J]. Chinese Journal of Catalysis, 2023, 52(9): 14-31.
[9]	Lei Zhao, Zhen Zhang, Zhaozhao Zhu, Pingbo Li, Jinxia Jiang, Tingting Yang, Pei Xiong, Xuguang An, Xiaobin Niu, Xueqiang Qi, Jun Song Chen, Rui Wu. Integration of atomic Co-N₅ sites with defective N-doped carbon for efficient zinc-air batteries [J]. Chinese Journal of Catalysis, 2023, 51(8): 216-224.
[10]	Mingming Song, Xianghai Song, Xin Liu, Weiqiang Zhou, Pengwei Huo. Enhancing photocatalytic CO₂ reduction activity of ZnIn₂S₄/MOF-808 microsphere with S-scheme heterojunction by in situ synthesis method [J]. Chinese Journal of Catalysis, 2023, 51(8): 180-192.
[11]	Xiuli Shao, Ke Li, Jingping Li, Qiang Cheng, Guohong Wang, Kai Wang. Investigating S-scheme charge transfer pathways in NiS@Ta₂O₅ hybrid nanofibers for photocatalytic CO₂ conversion [J]. Chinese Journal of Catalysis, 2023, 51(8): 193-203.
[12]	Nan Yin, Weibin Chen, Yong Yang, Zheng Tang, Panjie Li, Xiaoyue Zhang, Lanqin Tang, Tianyu Wang, Yang Wang, Yong Zhou, Zhigang Zou. Tröger’s base derived 3D-porous aromatic frameworks with efficient exciton dissociation and well-defined reactive site for near-unity selectivity of CO₂ photo-conversion [J]. Chinese Journal of Catalysis, 2023, 51(8): 168-179.
[13]	Shijie Li, Chunchun Wang, Kexin Dong, Peng Zhang, Xiaobo Chen, Xin Li. MIL-101(Fe)/BiOBr S-scheme photocatalyst for promoting photocatalytic abatement of Cr(VI) and enrofloxacin antibiotic: Performance and mechanism [J]. Chinese Journal of Catalysis, 2023, 51(8): 101-112.
[14]	Jiaming Li, Yuan Li, Xiaotian Wang, Zhixiong Yang, Gaoke Zhang. Atomically dispersed Fe sites on TiO₂ for boosting photocatalytic CO₂ reduction: Enhanced catalytic activity, DFT calculations and mechanistic insight [J]. Chinese Journal of Catalysis, 2023, 51(8): 145-156.
[15]	Zhaochun Liu, Xue Zong, Dionisios G. Vlachos, Ivo A. W. Filot, Emiel J. M. Hensen. A computational study of electrochemical CO₂ reduction to formic acid on metal-doped SnO₂ [J]. Chinese Journal of Catalysis, 2023, 50(7): 249-259.