Synthesis of Ni2+ cation modified TS-1 molecular sieve nanosheets as effective photocatalysts for alcohol oxidation and pollutant degradation

doi:10.1016/S1872-2067(20)63555-0

Abstract

Abstract: Improvement of the charge separation of titanosilicate molecular sieves is critical to their use as photocatalysts for oxidative organic transformations. In this work, MFI TS-1 molecular sieve nanosheets (TS-1 NS) were synthesized by a low-temperature hydrothermal method using a tailored diquaternary ammonium surfactant as the structure-directing agent. Introducing Ni²⁺ cations at the ion-exchange sites of the TS-1 NS framework signi?cantly enhanced its photoactivity in aerobic alcohol oxidation. The optimized Ni cation-functionalized TS-1 NS (Ni/TS-1 NS) provide impressive photoactivity, with a benzyl alcohol (BA) conversion of 78.9% and benzyl aldehyde (BAD) selectivity of 98.8% using O₂ as the only oxidant under full light irradiation; this BAD yield is approximately six times greater than that obtained for bulk TS-1, and is maintained for five runs. The excellent photoactivity of Ni/TS-1 NS is attributed to the significantly enlarged surface area of the two-dimensional morphology TS-1 NS, extra mesopores, and greatly improved charge separation. Compared with bulk TS-1, Ni/TS-1 NS has a much shorter charge transfer distance. The as-introduced Ni species could capture the photoelectrons to further improve the charge separation. This work opens the way to a class of highly selective, robust, and low-cost titanosilicate molecular sieve-based photocatalysts with industrial potential for selective oxidative transformations and pollutant degradation.

Key words: TS-1 nanosheet, Photocatalytic alcohol oxidation, Charge separation, Ni species as electron capturer, O₂ activation

Imran Khan, Xiaoyu Chu, Yanduo Liu, Salman Khan, Linlu Bai, Liqiang Jing. Synthesis of Ni²⁺ cation modified TS-1 molecular sieve nanosheets as effective photocatalysts for alcohol oxidation and pollutant degradation[J]. Chinese Journal of Catalysis, 2020, 41(10): 1589-1602.

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References

[1] L. H. Chen, X. Y. Li, G. Tian, Y. Li, J. C. Rooke, G. S. Zhu, S. L. Qiu, X. Y. Yang, B. L. Su, Angew. Chem. Int. Ed., 2011, 50, 11156-11161.
[2] J. Liang, Z. Liang, R. Zou, Y. Zhao, Adv. Mater., 2017, 29, 1701139.
[3] S. Hoang, P. X. Gao, Adv. Energy Mater., 2016, 6, 1600683.
[4] J. Li, J. Wang, G. K. Zhang, Y. Li, K. Wang, Appl. Catal. B Environ., 2018, 234, 167-177.
[5] F. X. Llabrés i Xamena, P. Calza, C. Lamberti, C. Prestipino, A. Damin, S. Bordiga, E. Pelizzetti, A. Zecchina, J. Am. Chem. Soc., 2003, 125, 2264-2271.
[6] M. Zanjanchi, A. Ebrahimian, M. Arvand, J. Hazard. Mater., 2010, 175, 992-1000.
[7] N. Rangnekar, M. Shete, K. V. Agrawal, B. Topuz, P. Kumar, Q. Guo, I. Ismail, A. Alyoubi, S. Basahel, K. Narasimharao, Angew. Chem. Int. Ed., 2015, 54, 6571-6575.
[8] W. Dai, X. Chen, X. Zheng, Z. Ding, X. Wang, P. Liu, X. Fu, ChemPhysChem., 2009, 10, 411-419.
[9] M. Jakob, H. Levanon, P. V. Kamat, Nano Lett., 2003, 3, 353-358.
[10] M. Farnesi Camellone, J. Zhao, L. Jin, Y. Wang, M. Muhler, D. Marx, Angew. Chem. Int. Ed., 2013, 52, 5780-5784.
[11] N. Kosinov, C. Liu, E. J. Hensen, E. A. Pidko, Chem. Mater., 2018, 30, 3177-3198.
[12] N. Zou, Q. Nie, X. R. Zhang, G. K. Zhang, J. L. Wang, P. Y. Zhang, Chem. Eng. J., 2019, 357, 1-10.
[13] M. Liu, Z. Xiao, J. Dai, W. Zhong, Q. Xu, L. Mao, D. Yin, Chem. Eng. J., 2017, 313, 1382-1395.
[14] D. Serrano, R. Sanz, P. Pizarro, I. Moreno, Appl. Catal. A Gen., 2012, 435, 32-42.
[15] J. Li, X. Y. Wu, Z. Wan, H. Chen, G. K. Zhang, Appl. Catal. B Environ., 2019, 243, 667-677.
[16] H. Xin, J. Zhao, S. Xu, J. Li, W. Zhang, X. Guo, E. J. Hensen, Q. Yang, C. Li, J. Phys. Chem. C, 2010, 114, 6553-6559.
[17] Y. Tian, T. Tatsuma, J. Am. Chem. Soc., 2005, 127, 7632-7637.
[18] F. Z. Zhang, X. W. Guo, X. S. Wang, G. Li, J. C. Zhou, J. Q. Yu, C. Li, Catal. Lett., 2001, 72, 235-239.
[19] C. J. Shearer, A. Cherevan, D. Eder, Adv. Mater., 2014, 26, 2295-2318.
[20] J. C. Groen, T. Bach, U. Ziese, A. M. Paulaime-van Donk, K. P. De Jong, J. A. Moulijn, J. Pérez-Ramírez, J. Am. Chem. Soc., 2005, 127, 10792-10793.
[21] K. Na, C. Jo, J. Kim, W. S. Ahn, R. Ryoo, ACS Catal., 2011, 1, 901-907.
[22] P. T. Tanev, M. Chibwe, T. J. Pinnavaia, Nature, 1994, 368, 321.
[23] T. Blasco, A. Corma, M. Navarro, J. P. Pariente, J. Catal., 1995, 156, 65-74.
[24] M. Zanjanchi, A. Ebrahimian, M. Arvand, J. Hazard. Mater., 2010, 175, 992-1000.
[25] D. P. Serrano, G. Calleja, J. A. Botas, F. J. Gutierrez, Ind. Eng. Chem. Res., 2004, 43, 7010-7018.
[26] C. C. Wang, J. R. Li, X. L. Lv, Y. Q. Zhang, G. Guo, Energy Environ. Sci., 2014, 7, 2831-2867.
[27] J. Wang, L. Xu, K. Zhang, H. Peng, H. Wu, J. G. Jiang, Y. Liu, P. Wu, J. Catal., 2012, 288, 16-23.
[28] M. Choi, K. Na, J. Kim, Y. Sakamoto, O. Terasaki, R. Ryoo, Nature, 2009, 461, 246.
[29] Q. Sun, N. Wang, Q. Bing, R. Si, J. Liu, R. Bai, P. Zhang, M. Jia, J. Yu, Chem, 2017, 3, 477-493.
[30] C. Yu, G. Li, S. Kumar, K. Yang, R. Jin, Adv. Mater., 2014, 26, 892-898.
[31] X. Ye, Y. Cui, X. Qiu, X. Wang, Appl. Catal. B Environ., 2014, 152, 383-389.
[32] Y. Jiao, A. L. Adedigba, Q. He, P. Miedziak, G. Brett, N. F. Dummer, M. Perdjon, J. Liu, G. J. Hutchings, Catal. Sci. Technol., 2018, 8, 2211-2217.
[33] W. Zhong, T. Qiao, J. Dai, L. Mao, Q. Xu, G. Zou, X. Liu, D. Yin, F. Zhao, J. Catal., 2015, 330, 208-221.
[34] M. Wu, L. Chou, H. Song, Catal. Lett., 2012, 142, 627-636.
[35] S. Hu, D. Liu, C. Wang, Y. Chen, Z. Guo, A. Borgna, Y. Yang, Appl. Catal. A Gen., 2010, 386, 74-82.
[36] H. Song, J. Wang, Z. Wang, H. Song, F. Li, Z. Jin, J. Catal., 2014, 311, 257-265.
[37] S. A. Rawool, M. R. Pai, A. M. Banerjee, A. Arya, R. Ningthoujam, R. Tewari, R. Rao, B. Chalke, P. Ayyub, A. Tripathi, Appl. Catal. B Environ., 2018, 221, 443-458.
[38] A. Zada, M. Humayun, F. Raziq, X. Zhang, Y. Qu, L. Bai, C. Qin, L. Jing, H. Fu, Adv. Energy Mater., 2016, 6, 1601190.
[39] Z. Hong, B. Shen, Y. Chen, B. Lin, B. Gao, J. Mater. Chem. A, 2013, 1, 11754-11761.
[40] M. Haruta, M. Daté, Appl. Catal. A Gen., 2001, 222, 427-437.
[41] T. Blasco, M. Camblor, J. Fierro, J. Perez-Pariente, Microporous Mater., 1994, 3, 259.
[42] M. Capel-Sanchez, J. Campos-Martin, J. Fierro, M. De Frutos, A. P. Polo, Chem. Commun., 2000, 10, 855-856.
[43] C. Li, G. Xiong, J. Liu, P. Ying, Q. Xin, Z. Feng, J. Phys. Chem. B, 2001, 105, 2993-2997.
[44] E. Astorino, J. B. Peri, R. J. Willey, G. Busca, J. Catal., 1995, 157, 482-500.
[45] C. I. Odenbrand, S. Lars, T. Andersson, L. A. Andersson, J. G. Brandin, G. Busca, J. Catal., 1990, 125, 541-553.
[46] J. M. GallardoáAmores, V. SanchezáEscribano, J. Chem. Soc. Faraday Trans., 1994, 90, 3181-3190.
[47] D. Scarano, A. Zecchina, S. Bordiga, F. Geobaldo, G. Spoto, G. Petrini, G. Leofanti, M. Padovan, G. Tozzola, J. Chem. Soc. Faraday Trans., 1993, 89, 4123-4130.
[48] A. Zecchina, G. Spoto, S. Bordiga, A. Ferrero, G. Petrini, G. Leofanti, M. Padovan, Stud. Surf. Sci. Catal., 1991, 69, 251-258.
[49] S. Jin, Z. Feng, F. Fan, C. Li, Catal. Lett., 2015, 145, 468-481.
[50] F. Fan, Z. Feng, C. Li, Chem. Rev., 2010, 39, 4794-4801.
[51] H. Lu, Y. Qu, L. Sun, X. Chu, J. Li, Y. Liu, L. Bai, L. Jing, ACS Sustain. Chem. Eng., 2018, 6, 14652-14659.

Synthesis of Ni²⁺ cation modified TS-1 molecular sieve nanosheets as effective photocatalysts for alcohol oxidation and pollutant degradation

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