Chinese Journal of Catalysis ›› 2009, Vol. 30 ›› Issue (7): 697-703.

• Articles • Previous Articles    

Optimization of Metal Ratio and CO Desorption Behavior of Rh-Mn-Li/SiO2 Catalyst for CO Hydrogenation

JIANG Dahao 1,2, DING Yunjie 1,*, L?Yuan 1, ZHU Hejun 1, CHEN Weimiao 1, WANG Tao 1, YAN Li 1, LUO Hongyuan 1   

  1. 1 Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China 2 Graduate University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2009-07-25 Online:2009-07-25 Published:2013-04-24

Abstract: A highly efficient Rh-Mn-Li/SiO2 catalyst was developed by optimization of its metal ratio when Rh loading was fixed at 1.5%, which proved to be the optimum Rh loading. CO-TPD and TPSR were employed to characterize the effects of Mn and Li with various loadings on the catalytic performance of the Rh-based catalyst for CO hydrogenation.

Key words: manganese, lithium, rhodium efficiency, promoter effect, two-carbon-containing oxygenate, carbon monoxide, hydrogenation