Glycerol Oxidation with Oxygen over Bimetallic Pt-Bi Catalysts under Atmospheric Pressure

doi:10.1016/S1872-2067(10)60289-6

Abstract

Abstract: A series of bimetallic Pt-Bi catalysts with a constant platinum content of 5.0 wt% and a varied bismuth content (3.0–7.0 wt%) supported on active carbon were prepared and used for glycerol oxidation with oxygen under atmospheric pressure. The bimetallic Pt-Bi/C was efficient for the selective oxidation of glycerol to dihydroxyacetone (DIHA) and the selectivity for DIHA reached 49.0% at a 91.5% conversion of glycerol over the 5%Pt-5%Bi/C catalyst. X-ray diffraction and transmission electron microscopy analysis revealed that the specially configured Pt-Bi nanoparticles in 5%Pt-5%Bi/C were highly dispersed (3.8 nm) over the active carbon support, which is proposed to contribute to the improved performance.

Key words: glycerol oxidation, platinum, bismuth, carbon support, dihydroxyacetone

LIANG Dan, CUI Shi-Yu, GAO Jing, WANG Jun-Hua, CHEN Ping, HOU Zhao-Yin. Glycerol Oxidation with Oxygen over Bimetallic Pt-Bi Catalysts under Atmospheric Pressure[J]. Chinese Journal of Catalysis, 2011, 32(12): 1831-1837.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(10)60289-6

https://www.cjcatal.com/EN/Y2011/V32/I12/1831

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