Four-component one-pot synthesis of unsymmetrical polyhydroquinoline derivatives using 3-methyl-1-sulfonic acid imidazolium hydrogen sulfate as a catalyst

doi:10.1016/S1872-2067(14)60038-3

Abstract

Abstract:

3-Methyl-1-sulfonic acid imidazolium hydrogen sulfate has been used as an efficient, halogen-free, and reusable Brönsted acidic ionic liquid catalyst for the synthesis of ethyl-4-aryl/heteryl-hexahydro-trimehtyl-5-oxoquinoline-3-carboxylates via the one-pot condensation of dimedone with aryl/heteryl aldehydes, ethyl acetoacetate, and ammonium acetate under solvent-free conditions. This method has the advantage of being clean and simple, as well as providing the desired product in high yield over a short reaction time. Furthermore, the catalyst could be recycled and reused four times without any discernible reduction in activity.

Key words: Unsymmetrical polyhydroquinoline, Brönsted acidic ionic liquid catalyst, Multicomponent reaction, Solvent-free condition

Nader Ghaffari Khaligh. Four-component one-pot synthesis of unsymmetrical polyhydroquinoline derivatives using 3-methyl-1-sulfonic acid imidazolium hydrogen sulfate as a catalyst[J]. Chinese Journal of Catalysis, 2014, 35(7): 1036-1042.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60038-3

https://www.cjcatal.com/EN/Y2014/V35/I7/1036

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