Transesterification of glycerol with dimethyl carbonate over calcined Ca-Al hydrocalumite

doi:10.1016/S1872-2067(15)60915-9

Abstract

Abstract:

A series of Ca-Al hydrocalumite with different Ca/Al ratios (1-6) were synthesized and used in the transesterification of glycerol with dimethyl carbonate (DMC) to glycerol carbonate (GC) under mild conditions. The calcined Ca-Al hydrocalumites were active with a selectivity toward GC that reached 97% at 93% conversion of glycerol over the sample with Ca/Al = 2 at 70 ℃, 3 h, and DMC/glycerol = 3. The glycerol conversion depended mainly on the proportion of strong basic sites in the calcined Ca-Al catalysts. The Ca₁₂Al₁₄O₃₃ phase in the calcined catalysts was stable, but CaO was lost in recycle experiments and thus brought deactivation.

Key words: Glycerol, Dimethyl carbonate, Transesterification, Glycerol carbonate, Calcium-aluminum hydrocalumite

Liping Zheng, Shuixin Xia, Xiuyang Lu, Zhaoyin Hou. Transesterification of glycerol with dimethyl carbonate over calcined Ca-Al hydrocalumite[J]. Chinese Journal of Catalysis, 2015, 36(10): 1759-1765.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)60915-9

https://www.cjcatal.com/EN/Y2015/V36/I10/1759

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