Fe3O4 nanoparticles as an efficient and reusable catalyst for the solvent-free synthesis of 9,9-dimethyl-9,10-dihydro-8H-benzo-[a]xanthen-11(12H)-ones

doi:10.1016/S1872-2067(14)60238-2

Chinese Journal of Catalysis ›› 2015, Vol. 36 ›› Issue (3): 362-366.DOI: 10.1016/S1872-2067(14)60238-2

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Fe₃O₄nanoparticles as an efficient and reusable catalyst for the solvent-free synthesis of 9,9-dimethyl-9,10-dihydro-8H-benzo-[a]xanthen-11(12H)-ones

Davood Habibi^a, Sharif Kaamyabi^a, Hasan Hazarkhani^b

a Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, Iran;
b Department of Educational Chemistry, Research and Planning Organization, Tehran, Iran

Received:2014-08-12 Revised:2014-10-27 Online:2015-02-14 Published:2015-02-14
Supported by:
This work was supported by the Bu-Ali Sina University, Hamedan 6517838683, Iran.

Abstract

Abstract:

A simple and efficient method for the synthesis of 9,9-dimethyl-9,10-dihydro-8H-benzo-[α]xanthen- 11(12)-one derivatives (DDBXs) was developed by the condensation reaction of various substituted aryl aldehydes with 2-naphthol and dimedone using Fe₃O₄ magnetic nanoparticles (MNPs) as a heterogeneous catalyst under solvent-free conditions at 90-110℃. The experimental procedure is very simple, the products are formed in high yields and the catalyst is easily separated by applying an external magnetic field.

Key words: Fe₃O₄ magnetic nano-particles, Three-component condensation, 2-Naphthol, Dimedone, Xanthene

Davood Habibi, Sharif Kaamyabi, Hasan Hazarkhani. Fe₃O₄nanoparticles as an efficient and reusable catalyst for the solvent-free synthesis of 9,9-dimethyl-9,10-dihydro-8H-benzo-[a]xanthen-11(12H)-ones[J]. Chinese Journal of Catalysis, 2015, 36(3): 362-366.

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Fe₃O₄nanoparticles as an efficient and reusable catalyst for the solvent-free synthesis of 9,9-dimethyl-9,10-dihydro-8H-benzo-[a]xanthen-11(12H)-ones

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