Oxidation of glycerol with H2O2 on Pb-promoted Pd/γ-Al2O3 catalysts

doi:10.1016/S1872-2067(16)62531-7

Chinese Journal of Catalysis ›› 2016, Vol. 37 ›› Issue (11): 1982-1990.DOI: 10.1016/S1872-2067(16)62531-7

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Oxidation of glycerol with H₂O₂ on Pb-promoted Pd/γ-Al₂O₃ catalysts

María L. Faroppa^a, Juan J. Musci^a, María E. Chiosso^a.b, Claudia G. Caggiano^a, Hernán P. Bideberripe^b,c, José L. García Fierro^d, Guillermo J. Siri^b,c, Mónica L. Casella^a,b

a CIBA (CIT UNNOBA, CONICET), Universidad Nacional del Noroeste de la Provincia de Buenos Aires, Newbery 261 (6000) Junín, Provincia de Buenos Aires, Argentina;
b CINDECA (CCT La Plata-CONICET, UNLP), Universidad Nacional de La Plata, Facultad de Ciencias Exactas, 47 N·257, 1900 La Plata, Argentina;
c PIDCAT Facultad de Ingeniería, Universidad Nacional de La Plata, 1 y 47, 1900 La Plata, Argentina;
d Instituto de Catálisis y Petroleoquímica, CSIC, Canto Blanco, E-28049 Madrid, España

Received:2016-06-01 Revised:2016-08-20 Online:2016-11-25 Published:2016-11-25
Contact: Mónica L. Casella,Tel:+542214210711; E-mail:casella@quimica.unlp.edu.ar
Supported by:
This work was supported by CONICET (PIP 0276), UNLP (Projects X 700), UNNOBA (SIB 2924/14), and Ministry of Education and Sports (Call "Jorge Sábato" Project 44-144-415), Argentina.

Abstract

Abstract:

A series of bimetallic Pd-Pb catalysts with a constant Pd content of 1 wt% and Pb/Pd atomic ratio from 0 to 1.6 supported on γ-Al₂O₃ were prepared and used for glycerol oxidation with H₂O₂ as the oxidizing agent at atmospheric pressure, 45℃ and pH=11. The morphology and dispersion of the catalysts were characterized by scanning electron microscopy-energy dispersive X-ray spectrosco-py (SEM-EDX) and transmission electron microscopy (TEM). The presence of an alloy phase in the bimetallic catalyst was detected by X-ray photoelectron spectroscopy (XPS). Glycerol conversion obtained with the monometallic Pd catalyst was 19%, which was increased to 100% with the addi-tion of Pb. The four bimetallic PdPb catalysts were able to oxidize glycerol to dihydroxyacetone (DIHA) and the selectivity to DIHA reached 59%, 58%, 34% and 25% for PdPb0.25, PdPb0.50, PdPb1.00 and PdPb1.60 catalysts, respectively.

Key words: Palladium, Bimetallic palladium-lead catalyst, Hydrogen peroxide, Glycerol oxidation, Glyceric acid, Glycolic acid

María L. Faroppa, Juan J. Musci, María E. Chiosso, Claudia G. Caggiano, Hernán P. Bideberripe, José L. García Fierro, Guillermo J. Siri, Mónica L. Casella. Oxidation of glycerol with H₂O₂ on Pb-promoted Pd/γ-Al₂O₃ catalysts[J]. Chinese Journal of Catalysis, 2016, 37(11): 1982-1990.

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Oxidation of glycerol with H₂O₂ on Pb-promoted Pd/γ-Al₂O₃ catalysts

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