Effects of surface physicochemical properties on NH3-SCR activity of MnO2 catalysts with different crystal structures

doi:10.1016/S1872-2067(17)62922-X

Abstract

Abstract:

α-, β-, δ-, and γ-MnO₂ nanocrystals are successfully prepared. We then evaluated the NH₃ selective catalytic reduction (SCR) performance of the MnO₂ catalysts with different phases. The NO_x conversion efficiency decreased in the order:γ-MnO₂ > α-MnO₂ > δ-MnO₂ > β-MnO₂. The NO_x conversion with the use of γ-MnO₂ and α-MnO₂ catalysts reached 90% in the temperature range of 140-200℃, while that based on β-MnO₂ reached only 40% at 200℃. The γ-MnO₂ and α-MnO₂ nanowire crystal morphologies enabled good dispersion of the catalysts and resulted in a relatively high specific surface area. We found that γ-MnO₂ and α-MnO₂ possessed stronger reducing abilities and more and stronger acidic sites than the other catalysts. In addition, more chemisorbed oxygen existed on the surface of the γ-MnO₂ and α-MnO₂ catalysts. The γ-MnO₂ and α-MnO₂ catalysts showed excellent performance in the low-temperature SCR of NO to N₂ with NH₃.

Key words: MnO₂, Crystal structure, Surface-active oxygen, Selective catalytic reduction, Physicochemical property

PiJun Gong, JunLin Xie, De Fang, Da Han, Feng He, FengXiang Li, Kai Qi. Effects of surface physicochemical properties on NH₃-SCR activity of MnO₂ catalysts with different crystal structures[J]. Chinese Journal of Catalysis, 2017, 38(11): 1925-1934.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(17)62922-X

https://www.cjcatal.com/EN/Y2017/V38/I11/1925

References

[1] X. Y. Shi, F. D. Liu, L. J. Xie, W. P. Shan, H. He, Environ. Sci. Technol., 2013, 47, 3293-3298.
[2] H. Y. Chen, E. M. EI-Malki, X. Wang, R. A. van Santen, W. M. H. Sachtler, J. Mol. Catal. A, 2000, 162, 159-174.
[3] S. Roy, M. S. Hegde, G. Madras, Appl. Energy, 2009, 86, 2283-2297.
[4] W. P. Shan, F. D. Liu, H. He, X. Y. Shi, C. B. Zhang, ChemCatChem, 2011, 3, 1286-1289.
[5] J. H. Li, R. H. Zhu, Y. S. Cheng, C. K. Lambert, R. T. Yang, Environ. Sci. Technol., 2010, 44, 1799-1805.
[6] M. V. Twigg, Appl. Catal. B, 2007, 70, 2-15.
[7] X. S. Liu, X. D. Wu, T. F. Xu, D. Weng, Z. C. Si, R. Ran, Chin. J. Catal., 2016, 37, 1340-1346.
[8] W. C. Yua, X. D. Wu, Z. C. Si, D. Weng, Appl. Surf. Sci., 2013, 283, 209-214.
[9] J. A. Dumesic, H. Topsøe, Y. Chen, T. Slabiak, J. Catal., 1996, 163, 409-417.
[10] G. Busca, L. Lietti, G. Ramis, F. Berti, Appl. Catal. B, 1998, 18, 21-36.
[11] T. H. Vuong, J. Radnik, E. Kondratenko, M. Schneider, U. Armbrust-er, A. Brückner, Appl. Catal. B, 2016, 197, 159-167.
[12] H. Z. Chang, X. Y. Chen, J. H. Li, L. Ma, C. Z. Wang, C. X. Liu, J. W. Schwank, J. M. Hao, Environ. Sci. Technol., 2013, 47, 5294-5301.
[13] Z. X. Ma, H. S. Yang, F. Liu, X. B. Zhang, Appl. Catal. A. 2013, 467, 450-455.
[14] L. J. Zhang, S. P. Cui, H. X. Guo, X. Y. Ma, X. G. Luo, J. Mol. Catal. A, 2014, 390, 14-21.
[15] G. S. Qi, R. T. Yang, R. Chang, Appl. Catal. B, 2004, 51, 93-106.
[16] R. H. Gao, D. S. Zhang, P. Maitarad, L. Y. Shi, T. Rungrotmongkol, H. R. Li, J. P. Zhang, W. G. Cao, J. Phys. Chem. C, 2013, 117, 10502-10511.
[17] X. Xiang, P. F. Wu, Y. Cao, L. Cao, Q. Y. Wang, S. T. Xu, P. Tian, Z. M. Liu, Chin. J. Catal., 2017, 38, 918-927.
[18] M. Wallin, S. Forser, P. Thormählen, M. Skoglundh, Ind. Eng. Chem. Res., 2004, 43, 7723-7731.
[19] D. A. Peña, B. S. Uphade, P. G. Smirniotis, J. Catal., 2004, 221, 421-431.
[20] F. Kapteijn, L. Singoredjo, A. Andreini, J. A. Moulijn, Appl. Catal. B, 1994, 3, 173-189.
[21] D. Fang, F. He, D. Mei, Z. Zhang. J. L. Xie, H. Hu, Catal. Commun., 2014, 52, 45-48.
[22] D. Fang, F. He, X. Q. Liu, K. Qi, J. L. Xie, F. X. Li, C. Q. Yu, Appl. Surf. Sci., 2018, 427, 45-55.
[23] D. Fang, J. L. Xie, H. Hu, Z. Zhang, F. He, Y. Zheng, Q. Zhang, Fuel Process. Technol., 2015, 134, 465-472.
[24] D. S. Zheng, S. X. Sun, W. L. Fan, H. Y. Yu, C. H. Fan, G. X. Cao, Z. L. Yin, X. Y. Song, J. Phys. Chem. B, 2005, 109, 16439-16443.
[25] T. Uematsu, Y. Miyamoto, Y. Ogasawara, K. Suzuki, K. Yamaguchi, N. Mizuno, Catal. Sci. Technol., 2016, 6, 222-233.
[26] Y. H. Dai, L. Chen, V. Babayan, Q. L. Cheng, P. Saha, H. Jiang, C. Z. Li, J. Mater. Chem. A, 2015, 3, 21337-21342.
[27] Y. X. Wang, S. Indrawirawan, X. G. Duan, H. Q. Sun, H. M. Ang, M. O. Tadé, S. B. Wang, Chem. Eng. J., 2015, 266, 12-20.
[28] B. Y. Bai, Q. Qiao, J. H. Li, J. M. Hao, Chin. J. Catal., 2016, 37, 27-31.
[29] Y. Liu, C. Luo, J. Sun, H. Z. Li, Z. B. Sun, S. Q. Yan, J. Mater. Chem. A, 2015, 3, 5674-5682.
[30] J. H. Zhang, Y. B. Li, L. Wang, C. B. Zhang, H. He, Catal. Sci. Technol., 2015, 5, 2305-2313.
[31] X. F. Tang, J. H. Li, L. Sun, J. M. Hao, Appl. Catal. B, 2010, 99, 156-162.
[32] W. F. Wei, X. W. Cui, W. X. Chen, D. G. Ivey, Chem. Soc. Rev., 2011, 40, 1697-1721.
[33] J. B. Jia, P. Y. Zhang, L. Chen, Catal. Sci. Technol., 2016, 6, 5841-5847.
[34] D. Zhan, Q. G. Zhang, X. H. Hu, T. Y. Peng, RSC Adv., 2013, 3, 5141-5147.
[35] M. Huang, F. Li, F. Dong, Y. X. Zhang, L. L. Zhang, J. Mater. Chem. A, 2015, 3, 21380-21423.
[36] X. F. Hu, X. P. Han, Y. X. Hu, F. Y. Cheng, J. Chen, Nanoscale, 2014, 6, 3522-3525
[37] Q. Li, Z. L. Wang, G. R. Li, R. Guo, L. X. Ding, Y. X. Tong, Nano Lett., 2012, 12, 3803-3807.
[38] W Tian, H. S. Yang, X. Y. Fan, X. B. Zhang, J. Hazard. Mater., 2011, 188, 105-109.
[39] X. L. Tang, J. M. Hao, H. H. Yi, J. H. Li, Catal. Today, 2007, 126, 406-411.
[40] Y. S. Wu, S. Li, Y. Cao, S. T. Xing, Z. C. Ma, Y. Z. Gao, Mater. Lett., 2013, 97, 1-3.
[41] J. Y. Luo, J. J. Zhang, Y. Y. Xia, Chem. Mater., 2006, 18, 5618-5623.
[42] Q. J. Wang, H. P. Zhang, L. J. Fu, B. Wang, Y. P. Wu, Electrochem. Commun., 2007, 9, 1873-1876.
[43] H. T. Guan, G. Chen, S. B. Zhang, Y. D. Wang, Mater. Chem. Phys., 2010, 124, 639-645.
[44] J. G. Zhao, J. Z. Yin, S. G. Yang, Mater. Res. Bull., 2012, 47, 896-900.
[45] Y. M. Dong, H. X. Yang, K. He, S. Q. Song, A. M. Zhang, Appl. Catal. B, 2009, 85, 155-161.
[46] T. Gao, H. Fjellvag, P. Norby, Anal. Chim. Acta., 2009, 648, 235-239.
[47] E. Widjaja, J. T. Sampanthar, Anal. Chim. Acta., 2007, 585, 241-245.
[48] S. L. Suib, Acc. Chem. Res., 2008, 41, 479-487.
[49] E. R. Stobbe, B. A. de Boer, J. W. Geus, Catal. Today, 1999, 47, 161-167.
[50] Z. M. Wang, S. Tezuka, H. Kanoh, Catal. Today, 2001, 68, 111-118.
[51] C. Wang, L. Sun, Q. Q. Cao, B. Q. Hu, Z. W. Huang, X. F. Tang, Appl. Catal. B, 2011, 101,598-605.
[52] J. L. Xie, D. Fang, F. He, J. F. Chen, Z. B. Fu, X. L. Chen, Catal. Com-mun., 2012, 28, 77-81.
[53] W. Xiao, D. C. Wang, X. W. Lou, J. Phys. Chem C, 2010, 114, 1694-1700.
[54] R. D. Zhang, W. Yang, N. Luo, P. X. Li, Z. G. Lei, B. H. Chen, Appl. Catal. B, 2014, 146, 94-104.
[55] S. Roy, B. Viswanath, M. S. Hegde, G. Madras, J. Phys. Chem. C, 2008, 112, 6002-6012.
[56] S. J. Lee, A. Gavriilidis, Q. A. Pankhurst, A. Kyek, F. E. Wagner, P. C. L Wong, K. L. Yeung, J. Catal., 2001, 200, 298-308.
[57] F. Larachi, J. Pierre, A. Adnot, A. Bernis, Appl. Surf. Sci., 2002, 195, 236-250.
[58] H. Chen, A. Sayari, A. Adnot, F. V. Larachi, Appl. Catal. B, 2001, 32, 195-204.
[59] Z. B. Wu, R. B. Jin, Y. Liu, H. Q. Wang, Catal. Commun., 2008, 9, 2217-2220.
[60] M. Kang, E. D. Park, J. M. Kim, J. E. Yie, Appl. Catal. A, 2007, 327, 261-269.
[61] W. P. Shan, F. D. Liu, H. He, X. Y. Shi, C. B. Zhang, Chem. Commun., 2011, 47, 8046-8048.
[62] X. Y. Fan, F. M, Qiu, H. S. Yang, W. Tian, T. F. Hou, X. B. Zhang, Catal. Commun., 2011, 12, 1298-1301.
[63] B. Thirupathi, P. G. Smirniotis, J. Catal., 2012, 288, 74-83.
[64] D. Fang, J. L. Xie, H. Yang, F. He, Z. B. Fu, H. Hu, Chem. Eng. J., 2015, 271, 23-30.
[65] F. D. Liu, H. He, Y. Ding, C. B. Zhang, Appl. Catal. B, 2009, 93, 194-204.
[66] H. J. Albering, in:J. O. Besenhard ed., Handbook of Battery Materi-als, McGraw-Hill, New York, 1999, 85-112.
[67] M. M. Thackeray, Progr. Solid State Chem., 1997, 25, 1-71.
[68] Y. Chabre, J. Pannetier, Progr. Solid State Chem., 1995, 23, 1-130.

Effects of surface physicochemical properties on NH₃-SCR activity of MnO₂ catalysts with different crystal structures

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

[1]	Hai Wang, Qingsong Luo, Liang Wang, Yu Hui, Yucai Qin, Lijuan Song, Feng-Shou Xiao. Product selectivity controlled by manganese oxide crystals in catalytic ammoxidation [J]. Chinese Journal of Catalysis, 2021, 42(12): 2164-2172.
[2]	Yingdong Chen, Shujiao Yang, Hongfei Liu, Wei Zhang, Rui Cao. An unusual network of α-MnO₂ nanowires with structure-induced hydrophilicity and conductivity for improved electrocatalysis [J]. Chinese Journal of Catalysis, 2021, 42(10): 1724-1731.
[3]	Panpan Wang, Jiahao Duan, Jie Wang, Fuming Mei, Peng Liu. Elucidating structure-performance correlations in gas-phase selective ethanol oxidation and CO oxidation over metal-doped γ-MnO₂ [J]. Chinese Journal of Catalysis, 2020, 41(8): 1298-1310.
[4]	Quanming Ren, Shengpeng Mo, Jie Fan, Zhentao Feng, Mingyuan Zhang, Peirong Chen, Jiajian Gao, Mingli Fu, Limin Chen, Junliang Wu, Daiqi Ye. Enhancing catalytic toluene oxidation over MnO₂@Co₃O₄ by constructing a coupled interface [J]. Chinese Journal of Catalysis, 2020, 41(12): 1873-1883.
[5]	Xiaona Liu, Yi Cao, Nana Yan, Chao Ma, Lei Cao, Peng Guo, Peng Tian, Zhongmin Liu. Cu-SAPO-17: A novel catalyst for selective catalytic reduction of NO_x [J]. Chinese Journal of Catalysis, 2020, 41(11): 1715-1722.
[6]	Xiaole Weng, Yu Long, Wanglong Wang, Min Shao, Zhongbiao Wu. Structural effect and reaction mechanism of MnO₂ catalysts in the catalytic oxidation of chlorinated aromatics [J]. Chinese Journal of Catalysis, 2019, 40(5): 638-646.
[7]	Shujun Ming, Lei Pang, Chi Fan, Wen Guo, Yahao Dong, Peng Liu, Zhen Chen, Tao Li. Chemical deactivation of Cu-SAPO-18 deNO_x catalyst caused by basic inorganic contaminants in diesel exhaust [J]. Chinese Journal of Catalysis, 2019, 40(4): 590-599.
[8]	Chuanmin Chen, Yue Cao, Songtao Liu, Jianmeng Chen, Wenbo Jia. Review on the latest developments in modified vanadium-titanium-based SCR catalysts [J]. Chinese Journal of Catalysis, 2018, 39(8): 1347-1365.
[9]	Jun Yang, Yupeng Chang, Weili Dai, Guangjun Wu, Naijia Guan, Landong Li. Bimetallic Cr-In/H-SSZ-13 for selective catalytic reduction of nitric oxide by methane [J]. Chinese Journal of Catalysis, 2018, 39(5): 1004-1011.
[10]	Zhongyi Sheng, Dingren Ma, Danqing Yu, Xiang Xiao, Bingjie Huang, Liu Yang, Sheng Wang. Synthesis of novel MnO_x@TiO₂ core-shell nanorod catalyst for low-temperature NH₃-selective catalytic reduction of NO_x with enhanced SO₂ tolerance [J]. Chinese Journal of Catalysis, 2018, 39(4): 821-830.
[11]	Yarong Fang, Yanbing Guo. Copper-based non-precious metal heterogeneous catalysts for environmental remediation [J]. Chinese Journal of Catalysis, 2018, 39(4): 566-582.
[12]	Xiaoxia Dai, Weiyu Jiang, Wanglong Wang, Xiaole Weng, Yuan Shang, Yehui Xue, Zhongbiao Wu. Supercritical water syntheses of transition metal-doped CeO₂nano-catalysts for selective catalytic reduction of NO by CO: An in situ diffuse reflectance Fourier transform infrared spectroscopy study [J]. Chinese Journal of Catalysis, 2018, 39(4): 728-735.
[13]	Yexuan Wen, Shuang Cao, Xiaoqi Fei, Haiqiang Wang, Zhongbiao Wu. One-step synthesized SO₄^2--TiO₂ with exposed (001) facets and its application in selective catalytic reduction of NO by NH₃ [J]. Chinese Journal of Catalysis, 2018, 39(4): 771-778.
[14]	Bingyang Bai, Qi Qiao, Yanping Li, Yue Peng, Junhua Li. Effect of pore size in mesoporous MnO₂ prepared by KIT-6 aged at different temperatures on ethanol catalytic oxidation [J]. Chinese Journal of Catalysis, 2018, 39(4): 630-638.
[15]	Lei Chen, Ding Weng, Jiadao Wang, Duan Weng, Li Cao. Low-temperature activity and mechanism of WO₃-modified CeO₂-TiO₂ catalyst under NH₃-NO/NO₂ SCR conditions [J]. Chinese Journal of Catalysis, 2018, 39(11): 1804-1813.