Mesoporous WO3 Supported Pt Catalyst for Hydrogenolysis of Glycerol to 1,3-Propanediol

doi:10.1016/S1872-2067(11)60425-7

Abstract

Abstract: Mesoporous tungsten trioxide (m-WO₃) was prepared using an evaporation-induced self-assembly method and was used as the support of Pt for hydrogenolysis of glycerol to produce 1,3-propanediol. In comparison with commercial WO₃, the m-WO₃ presents a much larger surface area and better reduciblity, which make the Pt particles highly dispersed on the support. At a reaction condition of 180 ^oC, 5.5 MPa H₂, and reaction time of 12 h, the Pt/m-WO₃ catalyst afforded 18.0% conversion of glycerol and 39.2% selectivity for 1,3-propanediol, both of which are much higher than those on commercial Pt/WO₃ catalyst.

Key words: mesoporous tungsten trioxide, platinum, glycerol, hydrogenolysis, 1,3-propanediol

LIU Long-Jie, ZHANG Yan-Hua, WANG Ai-Qin, ZHANG Tao. Mesoporous WO₃ Supported Pt Catalyst for Hydrogenolysis of Glycerol to 1,3-Propanediol[J]. Chinese Journal of Catalysis, 2012, 33(8): 1257-1261.

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Mesoporous WO₃ Supported Pt Catalyst for Hydrogenolysis of Glycerol to 1,3-Propanediol

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