Flower-Like Co-Ni/C Bimetallic Catalysts for the Selective Hydrogenation of o-Chloronitrobenzene

doi:10.1016/S1872-2067(11)60451-8

Abstract

Abstract: Three dimensional flower-like Co-Ni/C bimetallic catalysts composed of interlaced carbon flakes with highly dispersed metal nanoparticles were synthesized by a facile hydrothermal/solvothermal process followed by a heat treatment in flowing N₂. The sizes of the metal nanoparticles were from 26 to 4 nm, which became smaller as the Co/Ni molar ratio increased. The catalytic activities for the selective hydrogenation of o-chloronitrobenzene to o-chloroaniline were tested. The conversion of o-chloronitrobenzene over the bimetallic Co-Ni/C catalysts was increased by up to 200% compared with that over a mono-metallic Co/C catalyst, which was due to a synergistic interaction between the Co and Ni species. Hydrogen temperature-programmed desorption results showed that new active sites were formed in the Co₅₀Ni₅₀/C catalyst due to the formation of a Co-Ni alloy, which gave the improved activity of the Co₅₀Ni₅₀/C catalyst.

Key words: cobalt, nickel, carbon nanomaterials, bimetallic catalyst, synergistic effect, o-chloronitrobenzene, hydrogenation

JIE Ya-Ling, XIAO 南, LING Zheng, LIU Yue, YU Chang, QIU Jie-Shan. Flower-Like Co-Ni/C Bimetallic Catalysts for the Selective Hydrogenation of o-Chloronitrobenzene[J]. Chinese Journal of Catalysis, 2012, 33(12): 1883-1888.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60451-8

https://www.cjcatal.com/EN/Y2012/V33/I12/1883

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